Organic electroluminescence device
An electroluminescent device, organic technology, applied in the direction of electro-solid devices, electrical components, light-emitting materials, etc., can solve the problems that plague the OLED industry, and achieve the effects of being difficult to crystallize, easy to form films, and reducing coplanarity.
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Embodiment 1
[0097] [Example 1] Synthesis of Compound A-2
[0098]
[0099] Step1: Add 1,1':3',1"terphenyl-5'-amine (2.45g, 10mmol), 5'-bromo-1,1':3',1"terphenyl-5'-amine (3.09g , 10mmol), Pd 2 (dba) 3 (0.21g, 0.25mmol), P(t-Bu) 3 (0.18g, 0.84mmol), NaOt-Bu (2.8g, 25mmol), 100mL of toluene solution, reacted at 100°C for 24h, extracted the organic phase with diethyl ether and water after the reaction, and washed the organic layer with MgSO 4 Dry, concentrate the organic matter, go through column chromatography and recrystallize to obtain intermediate A-2-1 (3.88g, 82%).
[0100] Step2: Add intermediate A-2-1 (4.74g, 10mmol), p-bromoiodobenzene (2.83g, 10mmol), Pd to the reactor 2 (dba) 3 (0.21g, 0.25mmol), P(t-Bu) 3 (0.18g, 0.84mmol), NaOt-Bu (2.8g, 25mmol), 100mL of toluene solution, reacted at 100°C for 24h, extracted the organic phase with diethyl ether and water after the reaction, and washed the organic layer with MgSO 4 Drying, concentration of organic matter, column chromat...
Embodiment 2
[0102] [Example 2] Synthesis of Compound A-14
[0103] Compound A-14 (6.50 g, 78%) was obtained according to the synthesis method of compound A-2.
[0104]
Embodiment 3
[0105] [Example 3] Synthesis of Compound A-24
[0106] Compound A-24 (6.98 g, 79%) was obtained according to the synthesis method of compound A-2.
[0107]
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