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37results about How to "Reduce coplanarity" patented technology

Imidazole tri-acylhydrazone compound, application of compound as organic light-emitting material as well as preparation method of compound

The invention discloses an imidazole tri-acylhydrazone compound shown in formula I, an application of the compound as an organic light-emitting material as well as a preparation method of the compound. Four functional structure units, namely, an imidazole group, an acylhydrazone group, a diarylethene group and a naphthyl group, are effectively combined in one molecule, and a novel multi-functional-group imidazole tri-acylhydrazone organic light-emitting molecule is formed. The preparation method of the light-emitting material comprises steps as follows: (1) preparation of an intermediate, namely, imidazole trimethyl tricarboxylate; (2) preparation of an intermediate, namely, imidazole trimethyl hydrazide; (3) preparation of a target product, the imidazole tri-acylhydrazone. The preparation method is simple and comprises few synthesis steps, raw materials are easy to obtain, the cost is low, and purification and industrialization are easy. The imidazole tri-acylhydrazone compound is stable in structure and easy to store and shows stronger fluorescence emission under solution and solid states. The light-emitting material is good in stability and can be applied to fields of light-emitting devices, fluorescence sensing and the like.
Owner:INST OF ANALYSIS GUANGDONG ACAD OF SCI (CHINA NAT ANALYTICAL

Fluorophenyl pyrimidine solid green emission organic light-emitting material and preparation method thereof

The invention discloses a fluorophenyl pyrimidine solid green emission organic light-emitting material and a preparation method thereof. The novel fluorophenyl pyrimidine solid green emission organic light-emitting material is formed by binding two types of functional structural units of propyl substituted cycloketone and isopropyl methylsulfonyl amino-fluorophenyl pyrimidine through poly-ketene bridge bonds. The fluorophenyl pyrimidine solid green emission organic light-emitting material can embody solid broadband green emission characteristics when in a solid state. The preparation method of the fluorophenyl pyrimidine solid green emission organic light-emitting material is simple in operation and convenient to synthesize; the obtained fluorophenyl pyrimidine solid green emission organic light-emitting material is high in stability and practicality and can be applied to fields such as luminescent devices, laser dyes, anti-counterfeit technology, fluorescence sensing and biomedical analysis. The fluorophenyl pyrimidine solid green emission organic light-emitting material expands the study and application field of fluorophenyl pyrimidine compounds. As shown in the chemical formula, X is C or N.
Owner:INST OF ANALYSIS GUANGDONG ACAD OF SCI (CHINA NAT ANALYTICAL

An imidazole triacylhydrazone compound, its application as an organic luminescent material and its preparation method

The invention discloses an imidazole tri-acylhydrazone compound shown in formula I, an application of the compound as an organic light-emitting material as well as a preparation method of the compound. Four functional structure units, namely, an imidazole group, an acylhydrazone group, a diarylethene group and a naphthyl group, are effectively combined in one molecule, and a novel multi-functional-group imidazole tri-acylhydrazone organic light-emitting molecule is formed. The preparation method of the light-emitting material comprises steps as follows: (1) preparation of an intermediate, namely, imidazole trimethyl tricarboxylate; (2) preparation of an intermediate, namely, imidazole trimethyl hydrazide; (3) preparation of a target product, the imidazole tri-acylhydrazone. The preparation method is simple and comprises few synthesis steps, raw materials are easy to obtain, the cost is low, and purification and industrialization are easy. The imidazole tri-acylhydrazone compound is stable in structure and easy to store and shows stronger fluorescence emission under solution and solid states. The light-emitting material is good in stability and can be applied to fields of light-emitting devices, fluorescence sensing and the like.
Owner:INSTITUTE OF ANALYSIS GUANGDONG ACADEMY OF SCIENCES (CHINA NATIONAL ANALYTICAL CENTER GUANGZHOU)

A kind of fluorophenylpyrimidine solid-state green light-emitting organic luminescent material and preparation method thereof

The invention discloses a fluorophenyl pyrimidine solid green emission organic light-emitting material and a preparation method thereof. The novel fluorophenyl pyrimidine solid green emission organic light-emitting material is formed by binding two types of functional structural units of propyl substituted cycloketone and isopropyl methylsulfonyl amino-fluorophenyl pyrimidine through poly-ketene bridge bonds. The fluorophenyl pyrimidine solid green emission organic light-emitting material can embody solid broadband green emission characteristics when in a solid state. The preparation method of the fluorophenyl pyrimidine solid green emission organic light-emitting material is simple in operation and convenient to synthesize; the obtained fluorophenyl pyrimidine solid green emission organic light-emitting material is high in stability and practicality and can be applied to fields such as luminescent devices, laser dyes, anti-counterfeit technology, fluorescence sensing and biomedical analysis. The fluorophenyl pyrimidine solid green emission organic light-emitting material expands the study and application field of fluorophenyl pyrimidine compounds. As shown in the chemical formula, X is C or N.
Owner:INSTITUTE OF ANALYSIS GUANGDONG ACADEMY OF SCIENCES (CHINA NATIONAL ANALYTICAL CENTER GUANGZHOU)
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