The invention provides an aromatic amine compound and an organic light-emitting device thereof, and relates to the technical field of organic photoelectric materials. An aromatic amine main body structure is connected with three substituted or non-substituted 3,5-diphenylbenzene group to obtain the aromatic amine compound, the aromatic amine compound has good hole transport ability, and is high inreflectivity, good in film-forming property and good in thermal stability, synthesis is simple and is easy to operate, the aromatic amine compound can be applied to the organic light-emitting deviceand serves as a hole transport layer and/or a covering layer, the problems that the organic light-emitting device is severe in light loss and low in light emitting efficiency, heat of the device is accumulated, the efficiency of the device is severe in roll-off, and the service life is short are solved, and the organic light-emitting device has the advantages of high light-emitting efficiency andlong service life.