The invention relates to a Tb coordination polymer luminescent material based on two rigid ligands and a preparation method of the Tb coordination polymer luminescent material. The chemical formula ofthe luminescent material is {[Tb(Tfpa)3 Tfba(phen)3.3H2O]}n, wherein n is greater than 1, Tfpa is 3,4,5,6-tetrafluoro-1,2-phthalic acid, Tfba is 2,3,4,5-tetrafluoro-benzoic acid, and phen is 1,10-phenanthroline. The material can be excited by near ultraviolet light and can emit green fluorescence. The polymer luminescent material prepared by the preparation method provided by the invention is better in crystallinity, free of toxicity or pollution, high in thermal stability, good in luminescent property, low in raw material cost, simple in preparation process equipment and suitable for industrial production, and can meet the requirements of rare earth fluorescent powder, fluorescent lamps with three primary colors, display in public places and lighting application fields.