The present invention discloses a chiral heteroleptic nine-coordinate
rare earth complex and its preparation method and application, belonging to the field of organic luminescent materials. This chiral
rare earth complex consists of three anionic
coumarin-derived
diketone ligands (Coum) ‑ The chiral bis-
oxazoline-derived enantiomerically pure ligands 1R,2R-2,6-bis(4-phenyl-2-
oxazoline-2-yl)
pyridine (1R,2R-Ph-PyBox) or 1S,2S-2,6-bis(4-phenyl-2-
oxazoline-2-yl)
pyridine (1S,2S-Ph-PyBox) were self-assembled with
rare earth ions in
alcohol solution. Thanks to the combination of the excellent photophysical properties of the Coum ligand and the strong
chiral induction ability of the chiral Chiral-Ph-PyBox ligand, the two Tb 3+ The enantiomers [Tb(Coum)3(1R,2R‑Ph‑PyBox)](2)and[Tb(Coum)3(1S,2S‑Ph‑PyBox)](5) not only achieve bright and
high color purity characteristic
green emission (Φ PL =74%), and also obtained a strong
excited state CPL activity (|g lum |=0.097‑0.103) and significantly enhanced antenna ligand center absorption behavior (ε 320nm =47820-47940M ‑1 cm ‑1 ). Complexes 2 and 5 have magnetic dipoles 5 D4→ 7 The
circular polarization brightness at the F5 transition position (B CPL ) can be as high as 1132.7-1205.8M ‑1 cm ‑1 .