187 results about "Photopolymer" patented technology

The invention discloses a thiophene monomer, a holographic recording medium, a preparation method and a related device, the structural general formula of the thiophene monomer is shown in the specification, the refractive index of the monomer is larger than 1.8 and smaller than 1.9, the diffraction efficiency can be remarkably improved, the thiophene monomer is applied to preparation of a photopolymer type holographic recording medium, and the photopolymer type holographic recording medium with the sensitivity larger than 100 cm / mJ can be obtained. According to the holographic recording medium, the diffraction efficiency of the recording grating is larger than 95%, the refractive index modulation degree is larger than 0.1, and the shrinkage rate is lower than 1%, and further, the holographic recording medium can be used for preparing a volume holographic grating, a holographic optical element and an optical device.

The invention discloses a (methyl) acrylate monomer, a holographic recording medium, a preparation method and a related device.The structural formula of the (methyl) acrylate monomer is as shown in G1-G19. The preparation method is easy to operate and high in synthesis yield, and further, the holographic recording medium can be applied to holographic recording. According to the photopolymer holographic recording medium, the (methyl) acrylate monomer with the structure is introduced into the photopolymer holographic recording medium, so that the holographic recording medium with high sensitivity, high diffraction efficiency and no yellowing is obtained, and the invention further provides a preparation method of the holographic recording medium. The invention also provides a volume holographic grating, a holographic optical element and an optical device comprising the holographic recording medium.

The invention discloses a thianthrene monomer, a holographic recording medium, a preparation method and a related device, the structural formula of the thianthrene monomer is shown as G1-G6, the refractive index of the thianthrene monomer is larger than 1.7 and smaller than 1.8, the diffraction efficiency can be remarkably improved, and further, the holographic recording medium can be applied to holographic recording. The thianthrene monomer with the structure is introduced into the photopolymer type holographic recording medium, so that the holographic recording medium with high sensitivity, high diffraction efficiency and high refractive index is obtained, and the invention further provides a preparation method of the holographic recording medium. The invention also provides a volume holographic grating, a holographic optical element and an optical device comprising the holographic recording medium.

The invention discloses a (methyl) acrylate monomer, a holographic recording medium, a preparation method and a related device.The structural formula of the (methyl) acrylate monomer is as shown in G1-G5. The preparation method is easy to operate and high in synthesis yield, and further, the holographic recording medium can be applied to holographic recording. The (methyl) acrylate monomer with the structure is introduced into the photopolymer type holographic recording medium, reverse migration of a short polymer chain can be effectively inhibited, and therefore the holographic recording medium with high sensitivity and high diffraction efficiency is obtained, and the invention further provides a preparation method of the holographic recording medium. The invention also provides a volume holographic grating, a holographic optical element and an optical device comprising the holographic recording medium.

The invention discloses a dendritic (methyl) acrylate monomer, a holographic recording medium, a preparation method and a related device. Wherein the structural formula of the dendritic (methyl) acrylate monomer is shown as G1-G12, the preparation method of the dendritic (methyl) acrylate monomer is simple and easy to operate, and further, the dendritic (methyl) acrylate monomer with the structure is introduced into the photopolymer type holographic recording medium, so that the photopolymer type holographic recording medium is prepared. The invention further provides a preparation method of the holographic recording medium, a volume holographic grating containing the holographic recording medium, a holographic optical element containing the holographic recording medium and an optical device containing the holographic recording medium.

The invention discloses a 4, 4 '-bis (omega-alkenyl thioether) diphenyl sulfide monomer and a preparation method, the structural general formula of the 4, 4'-bis (omega-alkenyl thioether) diphenyl sulfide monomer is shown in the specification, n represents the number of methylene and is a positive integer, n = 1-10, the refractive index of a polymer obtained after the monomer and 4 '4-dimercapto diphenyl sulfide are polymerized is larger than 1.65 and smaller than 1.8, diffraction efficiency is remarkably improved, the preparation method is easy to operate, and the preparation method is suitable for industrial production. The invention further provides a photopolymer type holographic recording medium containing the monomer and a preparation method of the photopolymer type holographic recording medium, the sensitivity of the holographic recording medium is larger than 100 cm / mJ, the diffraction efficiency of a recording grating is larger than 95%, the refractive index modulation degree is larger than 0.1, the shrinkage rate is lower than 1%, and the preparation method is simple, controllable and suitable for industrial production. The invention also provides a volume holographic grating containing the holographic recording medium, a holographic optical element and an optical device.

The invention discloses a dithiocarbamate monomer, a holographic recording medium, a preparation method and a related device, the structural general formula of the monomer is as shown in G1 and G2, R1 represents any one of hydrogen, halogen and C1-C4 alkyl, R3 represents any one of hydrogen, halogen and C1-C4 alkyl, A1 represents C1-C4 alkyl, A2 represents hydrogen or methyl, n is a positive integer, and n = 1-10. The dithiocarbamate monomer provided by the invention has high refractive index, and the holographic recording medium with high sensitivity, high diffraction efficiency and high refractive index modulation degree can be obtained by applying the dithiocarbamate monomer to preparation of the photopolymer holographic recording medium; holographic recording media can be used to prepare volume holographic gratings, holographic optical elements, and optical devices.

The invention provides a photopolymer system, a grating device containing a chirp structure and a preparation method of the grating device. Visible light and ultraviolet light dual initiators and azobenzene polymerizable acrylate monomers are introduced into the photopolymer system; by utilizing the characteristics that an acrylate group can be used as a writing monomer to participate in a copolymerization process and an azobenzene group can be subjected to continuous photoisomerization during holographic exposure, a visible light photoinitiator and an ultraviolet light initiator driving system are reacted and cross-linked in sequence; a chirp structure is induced to be generated in the formed volume holographic grating while the photopolymer system records interference fringes, so that grating period change caused by material shrinkage is effectively compensated, the angle response bandwidth of the grating is remarkably widened, the requirement for refractive index modulation of the photopolymer system is reduced, and the optical grating has a wide application prospect. According to the invention, the selection range of the photopolymer system is widened, the overall aging resistance of the material system is improved, and the service life of the grating device is prolonged.

The invention relates to an optical monomer and a preparation method and application thereof, the structural general formula of the optical monomer is shown as G1, G2, G3, G4, G5, G6, G7 and G8, R1 is selected from one of the formulas, and R2 is hydrogen or methyl; n is a positive integer selected from 1-10. The optical monomer provided by the invention contains a plurality of aromatic rings with high molar refractive index and low molar volume, and also contains sulfur atoms with relatively high molar refractive index, so that the whole molecule of the whole monomer is extremely high in refractive index; the polymer also has a phenyl dithiocarbamate structure, and has good compatibility with film-forming resin with carbamate when being used for a photopolymer holographic recording medium. The monomer structure provided by the invention has a plurality of branched chains, the overall molecular weight is small, and the molecules are not easy to agglomerate.

The invention discloses an optical monomer, a holographic recording medium, a preparation method and a related device, the structural general formula of the optical monomer is as shown in G1-G6, the monomer is high in refractive index, the preparation method is simple, and further, the optical monomer with the structure is introduced into the photopolymer type holographic recording medium, so that the photopolymer type holographic recording medium is prepared. The invention further provides a preparation method of the holographic recording medium, a volume holographic grating containing the holographic recording medium, a holographic optical element containing the holographic recording medium and an optical device containing the holographic recording medium.

The invention discloses an unsaturated phenyl ether monomer, a holographic recording medium, a preparation method and a related device, the structural general formula of the monomer is as shown in G1 and G2, R1 represents any one of R2, A1 and A2 independently represent any one of hydrogen and phenyl, A3 represents hydrogen or methyl, A4 represents C1-C4 alkyl or phenyl, n is a positive integer and n = 1-5. The unsaturated phenyl ether monomer provided by the invention has high refractive index and is in a liquid state, and the holographic recording medium with high sensitivity, high diffraction efficiency and high refractive index modulation degree can be obtained by applying the unsaturated phenyl ether monomer to preparation of the photopolymer type holographic recording medium.

This invention discloses a photocurable pixel arrangement structure, a photocurable module, and a printing device. By setting multiple sub-pixels with different wavelength ranges and arranging them in a special array, the differences in beam angle and curing effect of multiple sub-pixels with different wavelength ranges are balanced, and the light coverage range of various sub-pixels is better matched.

This invention provides a photosensitive conductive resin composition and its application. The photosensitive conductive resin composition comprises, by weight, the following components: 20-60 parts of a photosensitive polymer, 10-20 parts of an epoxy resin, 5-20 parts of an acrylate monomer, 0.5-5 parts of a photoinitiator, 20-60 parts of a conductive carbon filler, and 1-10 parts of an additive; the volume resistivity of the conductive carbon filler is ≤0.5 Ω·m. Through the screening and synergistic compounding of specific components, the photosensitive conductive film prepared from this resin composition exhibits excellent conductivity and peel strength, high photosensitivity resolution, and excellent developability, thus meeting the application requirements of photosensitive conductive films.

A holographic photopolymer material, a holographic photosensitive film, a holographic optical element, and a display device, wherein the holographic photopolymer material includes a polymer matrix, photopolymerizable monomers, and a photosensitizer. An index of refraction of the photopolymerizable monomer is greater than an index of refraction of the polymer matrix. A molecular structure of the polymer matrix includes a linear structure, and branch chains of the polymer matrix include activation groups; and / or the molecular structure of the polymer matrix includes a crosslinked structure.

Holographic photopolymer materials, holographic photosensitive films, holographic optical elements, and display devices are provided. The holographic photopolymer material comprises a polymer matrix, a photopolymerizable monomer, and a photosensitizer. The refractive index of the photopolymerizable monomer is greater than that of the polymer matrix. The molecular structure of the polymer matrix includes a linear structure, the branched chains of the polymer matrix include activating groups, and / or the molecular structure of the polymer matrix includes a crosslinked structure. Because polymer matrices with a crosslinked molecular structure have a high glass transition temperature, holographic photopolymer materials have good heat resistance. Because holographic photopolymer materials with a linear molecular structure include activating groups that can form crosslinked structures, optical elements made from holographic photopolymer materials can have crosslinked structures, i.e., optical elements can have good heat resistance. Holographic photopolymer materials have good heat resistance, or optical elements made from holographic photopolymer materials can have good heat resistance.

A three-dimensional printing system is provided that includes a tank, a textured substrate connected to the tank, and at least one electrode. The tank contains a liquid photopolymer resin and a lubricant. The textured substrate is configured to allow light to pass through into the liquid photopolymer resin. The at least one electrode is configured to control a flow of the lubricant on the textured substrate.

A method for manufacturing a deflection member is disclosed. The method may include the steps of providing an additive manufacturing apparatus that includes at least two radiation sources and photopolymer resin, providing a reinforcing member, contacting a surface of the reinforcing member with the photopolymer resin, and directing radiation from the radiation source(s) towards a surface(s) of the reinforcing member to at least partially cure photopolymer resin in contact with the surface of the reinforcing member.

This invention relates to the technical field of photopolymer additive manufacturing, and specifically to a control system and method for continuous photopolymerization of multi-material composites. The system includes a control unit, a projection unit, and a composite molding execution unit. Since the composite molding execution unit is positioned above the projection unit, the Z-axis lifting module is perpendicular to the projection unit, and the X-axis translation module is connected to the Z-axis lifting module. This achieves physical isolation between the dual independent optomechanics and the material tank, continuous molding of functionally graded materials through dynamic parameters and multi-mode scheduling, and cross-tank collaborative control and interface strengthening treatment. The control method for continuous photopolymerization of multi-material composites of this invention, by achieving continuous printing of two materials through time-driven cross-tank collaborative control, improves the interfacial bonding strength of heterogeneous materials and increases printing speed, thereby solving the problems of poor multi-material compatibility, low switching efficiency, and low interfacial bonding strength.

This adhesive sheet (10) contains a base polymer. The base polymer is a photopolymer comprising a polymerizable component of a reactive surfactant. The adhesive sheet (10) has an adhesive force (Fn1) of 1.4 N / 10 mm or more in a prescribed initial peeling test, and an adhesive force (Fw1) of 1.2 N / 10 mm or less in a prescribed first water peeling test.

The invention relates to the technical field of photocuring 3D printing support generation, in particular to a photocuring 3D printing support generation method based on suspension angle self-adaption, which comprises the following steps of: layering a model and extracting a normal vector and a curvature of a triangular patch; dynamically calculating a critical suspension angle by combining equipment parameters, material characteristics and temperature; identifying a suspension area and marking a risk level; constructing a support density mapping function to generate an initial support point; optimizing a support network topology through gradient descent; and corrected support parameters are fed back based on historical collapse data. According to the invention, adaptive generation and closed-loop optimization of the supporting structure can be realized, and the printing success rate and the supporting efficiency are improved.

The disclosure relates to a benzopyrylium dye of the formula (I),in which R200, R201, R202, R203, R204, R205, R206, R207 and R208 independently of one another are each hydrogen, C1 to C16 alkyl, C4 to C7 cycloalkyl, C7 to C16 aralkyl, C6 to C10 (het)aryl, hydroxyl, C1 to C6 alkoxy, or dialkylamino, the dialkylamino being selected from the group consisting of diethylamino, dimethylamino, diisopropylamino, a six-membered saturated ring attached via the N of the amino group, which may additionally contain an N or O and may be substituted by nonionic arbitrary radicals, or a combination of at least two thereof, and / or R200 with R201 or R201 with R202 or R202 with R203 and / or R205 with R206 and / or R206 with R207 each independently of one another form a —CH═CH—CH═CH— bridge, and A is a —CH2— or a —CH2—CH2— bridge, where the anion Ann− has a molecular weight of ≥200 g / mol and does not contain a halogen atom.

The invention discloses a photopolymer material, application thereof and a volume holographic grating, and relates to the technical field of polymer photosensitive materials. The photopolymer material comprises the following raw materials: a binder, an active monomer, a photoinitiator, a photosensitizer, a hydrogen donor and a sensitizer, the molar ratio of the active monomer to the photoinitiator is (8-12): 1; the molar ratio of the photosensitizer to the photoinitiator is 1: (15-25); the active monomer comprises a high-refractive-index monomer with the refractive index of 1.55-1.72 and a low-refractive-index monomer with the refractive index of 1.44-1.50, and the molar ratio of the high-refractive-index monomer to the low-refractive-index monomer is (0.7-1.3): 1. The photopolymer material meeting holographic recording can be prepared, and the prepared material is good in heat resistance, rapid in film forming, short in oxygen isolation exposure response time (as long as several seconds), high in refractive index modulation degree, high in sensitivity, high in diffraction efficiency, good in mechanical property and high in transmittance and can be prepared in a large area.

A pane with thermal stabilization of at least one hologram element, includes at least one glass pane with an outer surface and an interior-side surface, at least one hologram element arranged on the outer surface or the interior-side surface of the at least one glass pane, wherein the at least one hologram element includes a photopolymer, and at least two temperature stabilization elements, wherein the at least two temperature stabilization elements are configured to stabilize the temperature of the at least one hologram element to a target temperature.

The invention provides high-precision photocuring 3D printing equipment for printing a polyurethane elastomer material, and belongs to the technical field of 3D printing equipment, the high-precision photocuring 3D printing equipment comprises an upper-layer plate, a printing mechanism, an inclination mechanism and a recoverable execution mechanism are mounted on the upper-layer plate, and a pressing mechanism is mounted on the recoverable execution mechanism; the printing mechanism comprises a container, a deoxidation mold, a photocuring substrate and a forming assembly, the container, the deoxidation mold, the photocuring substrate and the forming assembly are all installed on the upper layer plate, the deoxidation mold is installed on the photocuring substrate and located below the container, and the inclination mechanism comprises a vertical rod, a driving rod and an inclination mechanism body; the recoverable executing mechanism comprises a conveying pipe, a surrounding frame, a material groove, a collecting assembly and a lifting assembly, the material groove is located below the photocuring base plate and connected with the conveying pipe through the collecting assembly, the conveying pipe communicates with the container, and the collecting assembly is connected with the driving rod through the lifting assembly; the pressing mechanism comprises a pressing head and a supporting assembly, and the supporting assembly is installed on the photocuring substrate.

The present application relates to a liquid crystal elastomer microstructure preparation method based on photopolymerization phase separation, the method comprising S1, for a first liquid crystal cell with a specified thickness, filling a mixture of photopolymer monomers and liquid crystals between the first substrate and the second substrate of the first liquid crystal cell, the first substrate being a substrate without an alignment layer, and the second substrate being coated with an alignment layer; S2, covering a gray-tone mask on the first surface of the first substrate of the first liquid crystal cell; the first surface of the first substrate being the surface away from the mixture; S3, performing ultraviolet exposure on the gray-tone mask to separate the photopolymer monomers and the liquid crystals, and obtaining a composite structure; S4, based on a pre-configured liquid crystal elastomer prepolymer, processing the composite structure according to a preset liquid crystal elastomer microstructure preparation strategy, and obtaining a liquid crystal elastomer microstructure. The liquid crystal elastomer microstructure film prepared by the method has a thickness ranging from several microns to tens of microns, good alignment, and simple manufacturing process, low cost and high precision.

The present invention relates to a method for producing a substrate coated with a photopolymer film, wherein the photopolymer film is suitable in a partial region of its total surface to form a holographic optical element (HOE). The product of the process can be used in laminated glass for building glazing or in vehicle windows.

The application discloses a kind of material-saving type light-cured printer and printing method, including rack, the liquid tank is installed in the bottom layer of rack, platform is placed horizontally in liquid tank, a plurality of holes are arranged on platform, platform is connected with screw lifting system, realize the up-and-down movement of platform;The remaining three sides except the side where screw lifting system is located are all connected with protection plate through telescopic device on the inside of liquid tank, air bag is placed between the side wall of liquid tank and protection plate;A group of guide rails are installed in the middle layer of rack, scraper is installed between two guide rails, scraper has telescopic tool bit, scraper is above liquid tank, scraper moves back and forth along guide rail, and liquid level in liquid tank is scraped flat;Laser is installed in the top layer of rack.In the scheme, when platform is lowered to the lowest end, liquid level is lifted by inflation, then printing is continued, liquid photopolymer around printing model can be fully utilized, the utilization rate of liquid photopolymer is improved, and it is also applicable to printing model with larger height.

The present disclosure relates to a photopolymer composition, a hologram recording medium, a method of preparing the same, and an optical element including the same. The photopolymer composition can provide a hologram recording medium and an optical element including the same, which exhibit excellent optical recording characteristics such as diffraction efficiency while ensuring colorless and transparent optical characteristics and excellent thermal stability.

This invention provides a photopolymer composition, a holographic film, and a volume holographic grating. The photopolymer composition of this invention comprises a polymer matrix, a photopolymerizable monomer, and a photoinitiator; the polymer matrix comprises linear polyurethane, and the photopolymerizable monomer comprises a compound represented by Formula I. By using linear polyurethane as the polyurethane matrix and a compound represented by Formula I as the photopolymerizable monomer, the photopolymer composition of this invention possesses high refractive index modulation capability and low viscosity, enabling the formation of a holographic film with uniform material distribution, thereby achieving high diffraction efficiency in the volume holographic grating.

A method for producing and recycling a crosslinked photopolymer is disclosed. The method includes mixing reactive thiols, multifunctional alkenes, and a photoinitiator to create a homogeneous mixture that is crosslinked through exposure to light. The method also includes decrosslinking the crosslinked photopolymer through base-catalyzed thiol-disulfide exchange reactions by mixing the crosslinked photopolymer with a reactive thiol, a base catalyst, and a solvent to create a decrosslinked material including recycled thiol oligomers which are reactive. The method further includes removing the base catalyst and the solvent and recrosslinking the recycled thiol oligomers by mixing stoichiometric amounts of the recycled thiol oligomers and a reactive alkene such that a molar ratio between thiol end groups and ene end groups is maintained at 1:1. The method includes adding a photoinitiator and mixing to create a homogeneous mixture, and recrosslinking the homogeneous mixture through exposure to light. The recrosslinked photopolymer includes dynamic disulfide bonds.