347 results about "Photopolymer" patented technology

The invention discloses a photopolymer type holographic recording medium and a preparation method and application thereof.The photopolymer type holographic recording medium comprises a writing monomer, film-forming resin, a photosensitive initiation combination agent and a catalyst, the writing monomer comprises nanoparticles and a polymerizable monomer, and the film-forming resin is prepared from the nanoparticles and the polymerizable monomer; the refractive index of the polymerizable monomer is smaller than that of the nanoparticles, and the difference between the refractive index of the nanoparticles and the refractive index of the polymerizable monomer is larger than 0.5. The film-forming resin includes a polyol compound and an isocyanate-based compound. The catalyst is used for catalyzing a polyol compound and an isocyanate compound to react to form a film. The photosensitive initiation combination agent is used for sensing light and inducing polymerization of the polymerizable monomer. According to the photopolymer type holographic recording medium disclosed by the invention, after exposure, the polymerizable monomers located in the bright area and the nanoparticles extruded to the dark area have relatively large refractive index difference, so that the refractive index modulation degree of the recording grating can be improved; the film-forming resin provides effective support for the nanoparticles, and the nanoparticles are not agglomerated.

The invention discloses a photopolymer type holographic recording medium and a substrate processing method, and the method comprises the steps: providing a substrate which comprises a glass substrate or a resin substrate; providing a mixed solution of the photopolymer type holographic recording medium; performing hydroxylation treatment on the surface of the substrate to generate hydroxyl groups on the surface of the substrate; uniformly distributing the mixed solution of the photopolymer type holographic recording medium on the surface of a substrate, and baking, so that the compound with a plurality of isocyanate reactive functional groups and the polyisocyanate group compound in the photopolymer type holographic recording medium react to generate film-forming resin; the hydroxyl group on the surface of the substrate participates in the reaction, and the film-forming resin is connected to the substrate in a covalent bond manner. In this way, the adhesion between the photopolymer layer and the substrate can be improved without increasing the complexity of subsequent process operations.

The invention discloses a thiophene monomer, a holographic recording medium, a preparation method and a related device, the structural general formula of the thiophene monomer is shown in the specification, the refractive index of the monomer is larger than 1.8 and smaller than 1.9, the diffraction efficiency can be remarkably improved, the thiophene monomer is applied to preparation of a photopolymer type holographic recording medium, and the photopolymer type holographic recording medium with the sensitivity larger than 100 cm / mJ can be obtained. According to the holographic recording medium, the diffraction efficiency of the recording grating is larger than 95%, the refractive index modulation degree is larger than 0.1, and the shrinkage rate is lower than 1%, and further, the holographic recording medium can be used for preparing a volume holographic grating, a holographic optical element and an optical device.

The invention discloses a (methyl) acrylate monomer, a holographic recording medium, a preparation method and a related device.The structural formula of the (methyl) acrylate monomer is as shown in G1-G19. The preparation method is easy to operate and high in synthesis yield, and further, the holographic recording medium can be applied to holographic recording. According to the photopolymer holographic recording medium, the (methyl) acrylate monomer with the structure is introduced into the photopolymer holographic recording medium, so that the holographic recording medium with high sensitivity, high diffraction efficiency and no yellowing is obtained, and the invention further provides a preparation method of the holographic recording medium. The invention also provides a volume holographic grating, a holographic optical element and an optical device comprising the holographic recording medium.

The invention discloses a thianthrene monomer, a holographic recording medium, a preparation method and a related device, the structural formula of the thianthrene monomer is shown as G1-G6, the refractive index of the thianthrene monomer is larger than 1.7 and smaller than 1.8, the diffraction efficiency can be remarkably improved, and further, the holographic recording medium can be applied to holographic recording. The thianthrene monomer with the structure is introduced into the photopolymer type holographic recording medium, so that the holographic recording medium with high sensitivity, high diffraction efficiency and high refractive index is obtained, and the invention further provides a preparation method of the holographic recording medium. The invention also provides a volume holographic grating, a holographic optical element and an optical device comprising the holographic recording medium.

The invention discloses a (methyl) acrylate monomer, a holographic recording medium, a preparation method and a related device.The structural formula of the (methyl) acrylate monomer is as shown in G1-G5. The preparation method is easy to operate and high in synthesis yield, and further, the holographic recording medium can be applied to holographic recording. The (methyl) acrylate monomer with the structure is introduced into the photopolymer type holographic recording medium, reverse migration of a short polymer chain can be effectively inhibited, and therefore the holographic recording medium with high sensitivity and high diffraction efficiency is obtained, and the invention further provides a preparation method of the holographic recording medium. The invention also provides a volume holographic grating, a holographic optical element and an optical device comprising the holographic recording medium.

According to the photopolymer system based on the fluorine-containing liquid crystal, the grating device and the preparation method of the grating device, the mixed liquid crystal containing the nematic liquid crystal and the fluorine-containing liquid crystal at the same time is adopted in the photopolymer system, and therefore the polarity and dielectric anisotropy of the mixed liquid crystal material are improved; the overall electro-optical performance, uniformity and stability of the photopolymer system are improved, so that a grating device prepared based on the photopolymer system has good optical characteristics of low haze while having relatively high diffraction efficiency. Specifically, fluorine-containing biphenyl liquid crystals, fluorine-containing alkyne liquid crystals and fluorine-containing difluoromethoxy liquid crystals of which the carbon atoms of flexible side chains are 2-5, and nematic liquid crystals of which the delta epsilon is not less than 10 are selected to jointly form mixed liquid crystals; and the balance and optimization between the diffraction efficiency and haze performance of the photopolymer system and the grating device prepared from the photopolymer system are realized.

The invention discloses a dendritic (methyl) acrylate monomer, a holographic recording medium, a preparation method and a related device. Wherein the structural formula of the dendritic (methyl) acrylate monomer is shown as G1-G12, the preparation method of the dendritic (methyl) acrylate monomer is simple and easy to operate, and further, the dendritic (methyl) acrylate monomer with the structure is introduced into the photopolymer type holographic recording medium, so that the photopolymer type holographic recording medium is prepared. The invention further provides a preparation method of the holographic recording medium, a volume holographic grating containing the holographic recording medium, a holographic optical element containing the holographic recording medium and an optical device containing the holographic recording medium.

The invention discloses a 4, 4 '-bis (omega-alkenyl thioether) diphenyl sulfide monomer and a preparation method, the structural general formula of the 4, 4'-bis (omega-alkenyl thioether) diphenyl sulfide monomer is shown in the specification, n represents the number of methylene and is a positive integer, n = 1-10, the refractive index of a polymer obtained after the monomer and 4 '4-dimercapto diphenyl sulfide are polymerized is larger than 1.65 and smaller than 1.8, diffraction efficiency is remarkably improved, the preparation method is easy to operate, and the preparation method is suitable for industrial production. The invention further provides a photopolymer type holographic recording medium containing the monomer and a preparation method of the photopolymer type holographic recording medium, the sensitivity of the holographic recording medium is larger than 100 cm / mJ, the diffraction efficiency of a recording grating is larger than 95%, the refractive index modulation degree is larger than 0.1, the shrinkage rate is lower than 1%, and the preparation method is simple, controllable and suitable for industrial production. The invention also provides a volume holographic grating containing the holographic recording medium, a holographic optical element and an optical device.

The invention provides wear-resistant fluorescent waterborne polyurethane and a preparation method thereof, and relates to the technical field of novel fluorescent polymer materials. The wear-resistant fluorescent waterborne polyurethane is prepared from the following raw materials in parts by weight: 5 to 15 parts of perylene bisimide modified monomer, 20 to 45 parts of oligomer polyol, 35 to 45 parts of isocyanate, 2 to 7 parts of hydrophilic monomer, 5 to 10 parts of chain extender, 2 to 5 parts of neutralizer and 0.01 to 0.1 part of catalyst, wherein the perylene bisimide modified monomer takes perylene bisimide as a center, the nitrogen end of the perylene bisimide is grafted with a cage type polysilsesquioxane group, and the bay position of the perylene bisimide is modified with a triethylene glycol group. The wear-resistant fluorescent waterborne polyurethane disclosed by the invention has high solid-state fluorescent quantum yield and excellent physical and mechanical properties.

The invention discloses a dithiocarbamate monomer, a holographic recording medium, a preparation method and a related device, the structural general formula of the monomer is as shown in G1 and G2, R1 represents any one of hydrogen, halogen and C1-C4 alkyl, R3 represents any one of hydrogen, halogen and C1-C4 alkyl, A1 represents C1-C4 alkyl, A2 represents hydrogen or methyl, n is a positive integer, and n = 1-10. The dithiocarbamate monomer provided by the invention has high refractive index, and the holographic recording medium with high sensitivity, high diffraction efficiency and high refractive index modulation degree can be obtained by applying the dithiocarbamate monomer to preparation of the photopolymer holographic recording medium; holographic recording media can be used to prepare volume holographic gratings, holographic optical elements, and optical devices.

The invention provides a photopolymer system, a grating device containing a chirp structure and a preparation method of the grating device. Visible light and ultraviolet light dual initiators and azobenzene polymerizable acrylate monomers are introduced into the photopolymer system; by utilizing the characteristics that an acrylate group can be used as a writing monomer to participate in a copolymerization process and an azobenzene group can be subjected to continuous photoisomerization during holographic exposure, a visible light photoinitiator and an ultraviolet light initiator driving system are reacted and cross-linked in sequence; a chirp structure is induced to be generated in the formed volume holographic grating while the photopolymer system records interference fringes, so that grating period change caused by material shrinkage is effectively compensated, the angle response bandwidth of the grating is remarkably widened, the requirement for refractive index modulation of the photopolymer system is reduced, and the optical grating has a wide application prospect. According to the invention, the selection range of the photopolymer system is widened, the overall aging resistance of the material system is improved, and the service life of the grating device is prolonged.

The invention discloses an acrylate monomer and a preparation method thereof, a photopolymer composition and a volume holographic grating and a preparation method thereof, the acrylate monomer provided by the invention is simple in structure and rich in expandable structure, so that the synthesis steps are simple and convenient, the cost is reduced, a relatively high refractive index of the monomer is realized on the basis of introduction of more sulfur atoms into the monomer, and the volume holographic grating has a good application prospect. In the subsequent photopolymerization process, the difference between the refractive index of the generated polymer and the refractive index of the common matrix is larger, so that the preparation of the holographic grating with high-refractive-index modulation degree can be realized.

The present invention concerns a bottom-up type photo-curing three-dimensional printing process, comprising the following steps:forming a support (11, 33, 41) on an extraction plate (12, 34), by the photo-curing of successive layers of a photopolymer material, the imprint of at least a portion of the object (10, 30, 40) to be formed being formed on said support (11, 33, 41);completing the curing of the photopolymer material of said support (11, 33, 41);forming the object (10, 30, 40) to be printed on said support (11, 33, 41), by the photo-curing of a photopolymer material; anddetaching the obtained object (10, 30, 40) from said support (11, 33, 41).

Provided are dual cure resin compositions useful for additive manufacturing that include an elastomer-producing light polymerizable monomer and / or prepolymer; a monomer and / or prepolymer that is solidified by exposure to heat, microwave irradiation, and / or moisture; a photoinitiator; optionally, one or more additional light polymerizable monomers and / or prepolymers; and optionally, a thiol crosslinker. Methods of forming a polymer and / or three-dimensional object with the resin, and polymers and / or three-dimensional objects produced are also described.

The invention relates to an optical monomer and a preparation method and application thereof, the structural general formula of the optical monomer is shown as G1, G2, G3, G4, G5, G6, G7 and G8, R1 is selected from one of the formulas, and R2 is hydrogen or methyl; n is a positive integer selected from 1-10. The optical monomer provided by the invention contains a plurality of aromatic rings with high molar refractive index and low molar volume, and also contains sulfur atoms with relatively high molar refractive index, so that the whole molecule of the whole monomer is extremely high in refractive index; the polymer also has a phenyl dithiocarbamate structure, and has good compatibility with film-forming resin with carbamate when being used for a photopolymer holographic recording medium. The monomer structure provided by the invention has a plurality of branched chains, the overall molecular weight is small, and the molecules are not easy to agglomerate.

A three-dimensional optical device (100) for coupling light from a single-core input fiber into a plurality of separate fiber cores of a multicore output fiber is disclosed. The optical device is formed in a photopolymer material and comprises an input waveguide (110), a plurality of output waveguides (130a-d), and a non-planar multimode interference section (120) for splitting light of a first mode (210) at a first end face (221) of the MMI section into a plurality of second modes (230a-d) at a second end face (222) of the MMI section. The plurality of second modes comprises a central mode (230a) and a plurality of peripheral modes (230b-d). Each output waveguide has a proximal end (131) separately connected to the second end face of the MMI section. A mode field diameter associated with the input waveguide and output waveguides is smaller at the proximal end than at the distal end. A distance between adjacent output waveguides is smaller at the proximal ends.

The invention discloses a photopolymer type holographic recording medium and a preparation method and application thereof, the photopolymer type holographic recording medium comprises a writing monomer, and the writing monomer comprises epoxy resin and a polymerizable monomer, the polymerizable monomer is selected from an alkenyl naphthalene compound, an alkenyl anthracene compound, an alkenyl benzene compound, an acrylic acid compound, a methacrylic acid compound, an acrylate compound, a methacrylate compound, N-vinyl pyrrole, N-vinyl carbazole, N-vinyl imidazole, N-vinyl indole and N-vinyl pyrrolidone; the carbazole is at least one of trans-N-3-alkyne butenyl carbazole. According to the epoxy resin disclosed by the invention, the volume shrinkage of the polymerizable monomer after polymerization can be effectively reduced, the cationic polymerization of the epoxy resin can be accelerated while the polymerizable monomer forms free radical polymerization, and the photopolymer type holographic recording medium disclosed by the invention is high in light sensitivity, stable in holographic performance and high in volume holographic grating diffraction efficiency.

The invention discloses an optical monomer, a holographic recording medium, a preparation method and a related device, the structural general formula of the optical monomer is as shown in G1-G6, the monomer is high in refractive index, the preparation method is simple, and further, the optical monomer with the structure is introduced into the photopolymer type holographic recording medium, so that the photopolymer type holographic recording medium is prepared. The invention further provides a preparation method of the holographic recording medium, a volume holographic grating containing the holographic recording medium, a holographic optical element containing the holographic recording medium and an optical device containing the holographic recording medium.

The invention discloses a near-infrared photosensitive initiation system, a photopolymer type holographic recording medium, a holographic optical element and display equipment, and the photopolymer type holographic recording medium comprises film-forming resin, a writing monomer, the near-infrared photosensitive initiation system, a chain transfer agent, a catalyst and an additive, the film-forming resin comprises a compound with a plurality of isocyanate reactive functional groups and a polyisocyanate group compound, and the near-infrared light-sensitive initiation system comprises a near-infrared light-sensitive dye and a co-initiator. In this way, monomer polymerization can be efficiently initiated, the material cost is low, and the holographic recording performance of the photopolymer is effectively improved.

The invention discloses an unsaturated phenyl ether monomer, a holographic recording medium, a preparation method and a related device, the structural general formula of the monomer is as shown in G1 and G2, R1 represents any one of R2, A1 and A2 independently represent any one of hydrogen and phenyl, A3 represents hydrogen or methyl, A4 represents C1-C4 alkyl or phenyl, n is a positive integer and n = 1-5. The unsaturated phenyl ether monomer provided by the invention has high refractive index and is in a liquid state, and the holographic recording medium with high sensitivity, high diffraction efficiency and high refractive index modulation degree can be obtained by applying the unsaturated phenyl ether monomer to preparation of the photopolymer type holographic recording medium.

The present disclosure relates to a holographic grating which includes a holographic photopolymer, and to an augmented reality / virtual reality apparatus including the same. The holographic grating may include at least one nanoparticle, a light portion, a dark portion, and a holographic photopolymer. The holographic photopolymer may also include a polymer matrix, a writing monomer, and a dye system. The holographic photopolymer may be dispersed throughout the light portion and the dark portion of the holographic grating. In some forms, the light portion may include a first concentration of the nanoparticles and / or the dark portion may include a second concentration of the nanoparticles. The first concentration of the nanoparticles may be greater than the second concentration of the nanoparticles.

This invention discloses a photocurable pixel arrangement structure, a photocurable module, and a printing device. By setting multiple sub-pixels with different wavelength ranges and arranging them in a special array, the differences in beam angle and curing effect of multiple sub-pixels with different wavelength ranges are balanced, and the light coverage range of various sub-pixels is better matched.

The present invention discloses a method for recording and displaying photopolymers based on a computer-generated holographic bin algorithm. S1: After a beam of light emitted by a femtosecond pulse laser is expanded and collimated, the pulse laser is focused on a photopolymer material through an objective lens, causing the refractive index of the photopolymer to change. The position of the photopolymer is controlled by controlling a translation stage to achieve three-dimensional recording of two pieces of material. S2: The complex amplitude distribution of the object is calculated through the computer-generated holographic bin algorithm and the two pieces of material are encoded. The exposure time and other parameters are controlled by a computer, and the femtosecond laser is used to write the calculated and encoded phase information diagram on the photopolymer. S3: After recording, the second beam splitter and the objective lens in front of the recording position are removed, and a plane wave is used to simultaneously irradiate the two pieces of engraved photopolymer and combine the beams to obtain a reproduced image of the three-dimensional object. The recording and display of the three-dimensional object can be achieved.

Adhesive compositions disclosed herein can be applied to substrates using flexo-printing (via, e.g., photopolymer plate); cured to a hardened, tack-free state; and readily be rendered tacky on application of heat and pressure to accurately transfer foil to the substrates. An example adhesive composition includes a monomer component, an oligomer / resin component including one or more oligomers and one or more inert thermoplastic resins that are soluble in the monomers, and, where required, one or more free radical polymerization initiators.

A scenario-adaptable color-changing ink and a corresponding solar glass product are provided. The ink includes 7-30 parts by weight of photopolymer, 8-20 parts by weight of photoactive monomer, 1-5 parts by weight of photosensitizer, 30-55 parts by weight of weather-resistant resin, 1-10 parts by weight of curing agent, and 1-15 parts by weight of pearlescent pigment. The pearlescent pigment is at least one interference pearlescent pigments with weather-resistance, which has no color. Each sheet of the pearlescent pigment can be considered as a miniature prism which can break the white composite light into colorful monochromatic light, thus allow the coating of the printing ink to present a beautiful pearl luster and metallic luster. The pattern color which is visible by human is a result of overlaps and interferes of lights that the incident light is multiply reflected and refracted by the sheets of transparent pearlescent pigment.

The invention discloses a method for applying photoswitch fluorescent polymers to dynamic fluorescent falsification prevention, which comprises the following steps: taking methyl acrylate, 1, 6-hexanediol diacrylate, a photoinitiator 819, a green fluorescent dye BDPMA and one of three photochromic spiropyrans SPMA, SPAMA and SPBMA as raw materials, and preparing three photoswitch fluorescent polymers P1, P2 and P3 in a photopolymerization manner. The P1, P2 and P3 are irradiated by ultraviolet light and placed in room-temperature darkness, red fluorescence generated by the P1, P2 and P3 can be gradually and spontaneously converted into green fluorescence, due to the structural difference of the three spiropyrans, the fluorescence discoloration rates of the three polymers show obvious difference, and a new dynamic fluorescent anti-counterfeit label is constructed by utilizing the difference. The photoswitch fluorescent polymer obtained by the invention has the advantages of simple preparation method, stable structure and good machinability, is suitable for amplification synthesis and practical application, and has wide application prospects in the fields of optical anti-counterfeiting and information encryption.

This invention provides a photosensitive conductive resin composition and its application. The photosensitive conductive resin composition comprises, by weight, the following components: 20-60 parts of a photosensitive polymer, 10-20 parts of an epoxy resin, 5-20 parts of an acrylate monomer, 0.5-5 parts of a photoinitiator, 20-60 parts of a conductive carbon filler, and 1-10 parts of an additive; the volume resistivity of the conductive carbon filler is ≤0.5 Ω·m. Through the screening and synergistic compounding of specific components, the photosensitive conductive film prepared from this resin composition exhibits excellent conductivity and peel strength, high photosensitivity resolution, and excellent developability, thus meeting the application requirements of photosensitive conductive films.

A holographic photopolymer material, a holographic photosensitive film, a holographic optical element, and a display device, wherein the holographic photopolymer material includes a polymer matrix, photopolymerizable monomers, and a photosensitizer. An index of refraction of the photopolymerizable monomer is greater than an index of refraction of the polymer matrix. A molecular structure of the polymer matrix includes a linear structure, and branch chains of the polymer matrix include activation groups; and / or the molecular structure of the polymer matrix includes a crosslinked structure.

The invention relates to a device for continuously replicating holograms, comprising: a coating module arranged to coat a liquid photopolymer onto a first carrier film; a lamination module arranged to apply a second carrier film onto the first carrier film coated with the photopolymer in order to obtain a photopolymer composite comprising a liquid photopolymer layer between the two carrier films; an exposure module, the exposure module having a light source and a master element comprising a master hologram to be replicated, the master element being mounted so as to be axially rotatable, and the exposure module being arranged such that a photopolymer composite is in optical contact with the master element, simultaneously exposing the master hologram onto the region of the photopolymer composite by the light source to obtain a duplicated hologram; and a securing module arranged to cure the replicated hologram in the photopolymer composite.