4925 results about "3D printing" patented technology

The invention belongs to the technical field of aerogel materials, and particularly relates to antistatic aerogel for 3D printing as well as a preparation method and application of the antistatic aerogel. The preparation method comprises the following steps: (1) dispersing inorganic nanoparticles modified by a silane coupling agent containing epoxy groups and an aniline monomer in an acidic solvent to obtain a monomer mixed solution; (2) stirring and dissolving polyamide in the monomer mixed solution; (3) initiating a reaction to obtain a polyaniline modified polyamide solution; and (4) freeze-drying to obtain the antistatic aerogel for 3D printing. By controlling synthesis conditions, a core-shell structure of acid-doped polyaniline coated inorganic nanoparticles is formed, and a good conductive path is formed in polyamide with a small addition amount of polyaniline. The antistatic aerogel for 3D printing can be applied to technologies such as photocuring molding and fused deposition of polyurethane resin in a 3D printing technology, and the antistatic property and the mechanical property of a 3D printed product are improved.

The invention belongs to the technical field of aerogel materials, and particularly relates to high-performance antistatic aerogel for 3D printing as well as a preparation method and application thereof. According to the invention, inorganic hollow nanoparticles are selected as a nucleating modifier for in-situ polymerization of aniline monomers in a polyamide solution, so that polyaniline-coated inorganic hollow nanoparticles are uniformly dispersed in polyamide, and the aerogel composite material with polyamide as a continuous phase and polyaniline-coated inorganic hollow nanoparticles as a conductive and reinforced phase is formed. The use of the hollow inorganic nanoparticles avoids the problem that the solid inorganic nanoparticles lose the characteristics of the inorganic nanoparticles due to high specific gravity and high surface energy, and easy agglomeration or adsorption with other substances in the preparation process of the solid inorganic nanoparticles. The inorganic hollow nanoparticles are adopted as a nucleating modifier, so that the problems of agglomeration of solid nanoparticles and dispersion in a polyamide matrix are well solved.

The invention discloses a 3D printing path planning method based on electric arc additive anisotropy and a stress field, and the method comprises the steps: constructing a CAD three-dimensional model of a part, and obtaining the stress field of the part through finite element simulation; determining a slice plane; mapping the stress field to a slice plane to form a force flow line; according to the obtained force flow line, rotation transformation regeneration is carried out according to the anisotropy of the used electric arc additive, and a reference trajectory considering the anisotropy of the material is obtained; under the principle of alternate arc starting and extinguishing, the corresponding printing sequence in the layers and between the layers is further planned, and the reference trajectory lines are connected end to end to be planned into a continuous path; and generating a code file, and printing according to the printing sequence. The comprehensive mechanical property of a printed piece is improved.

The invention relates to the technical field of 3D printing error compensation and precision control, and particularly discloses a printing comprehensive precision measurement method for 3D printing equipment, which comprises the following steps: designing a standard test piece containing various typical geometrical characteristics, and combining non-contact three-dimensional optical scanning and contact probe measurement means to measure the printing comprehensive precision of the 3D printing equipment. Spatial distribution data of printing errors are obtained in a controlled environment, a three-dimensional error field model with direction and amplitude information is constructed through point cloud registration and feature comparison, and based on error distribution features, the local resolution is dynamically adjusted by adopting a multi-level self-adaptive grid division strategy, so that a three-dimensional error field model with direction and amplitude information is constructed. A local error compensation model is established by combining tightly-supported radial basis function interpolation and a linear fitting method, a boundary consistency matching algorithm is introduced to realize multi-level model fusion, a unified global error compensation field is formed, an error offset vector field is embedded into a slicing process, point-by-point dynamic correction of a nozzle path is realized by using a trilinear interpolation algorithm, and the nozzle path is dynamically corrected. And the forming precision and the surface quality of the key structure are improved.

The invention provides an intelligent image processing method and device for UV curing 3D ink-jet printing and a storage medium, and the method comprises the steps: carrying out the contour feature extraction of a slice image, and intelligently recognizing a supporting region based on the interlayer contour change and geometric features; printing data corresponding to the color ink layer, the white ink layer, the gloss oil layer, the shaping layer and the supporting layer are generated according to the contour features, the shrinkage judgment result and the overhanging area recognition result, the printing data serve as spot color channels and are combined with CMYK channels of the color ink layer, halftone processing is carried out on the data of the channels, and the color ink layer is obtained. And finally, generating and outputting a TIF format image file comprising at least eight channels, wherein the TIF format image file is used for driving the UV curing 3D ink-jet printer, the equipment and the storage medium storage and is used for realizing the intelligent image processing method during execution. According to the method, the printing precision and the material utilization rate are improved, and the problems of support generation, color management and quality control in multi-material 3D printing are effectively solved.

The invention discloses a photocuring 3D printing mechanism method for multi-material cooperative spraying, and relates to the field of cooperative control, and the photocuring 3D printing mechanism method comprises the following steps: layering a model, generating a material distribution map, and labeling a functional area and a transition area; a multi-nozzle array is used for accurately positioning and spraying according to the atlas; a gradual change path is planned in the transition area, and gradient change of material components is achieved through cooperative spraying; a partition curing strategy is adopted, ultraviolet light full curing and visible light semi-curing are adopted, and leveling is promoted in combination with micro-vibration; spraying a penetrating agent between layers to form a mechanical interlocking enhanced interface; based on visual online defect detection, printing parameters are fed back and adjusted in real time through a CNN model. The device and the method have the advantages that accurate mixing of multiple materials is realized through cooperative spraying of the multiple piezoelectric sprayers and gradual change path planning, and real-time defect detection and correction can be realized by matching with differentiated photocuring, high-frequency micro-vibration leveling and interlayer penetrating agent interlocking, so that high-precision multi-material functional component forming is efficiently completed.

A silicon carbide source material structure for use in a sublimation system for growing crystalline silicon carbide is provided. The silicon carbide source material structure includes a composite shaped solid. The composite shaped solid may be made by casting, extrusion, 3D printing, graphite conversion, or other suitable process.

The invention discloses a photo-thermal composite hydrogel patch and a preparation method and application thereof.The hydrogel patch is of a three-dimensional latticed porous structure formed by taking methylacryloyl gelatin (GelMA) and methylacryloyl hyaluronic acid (HAMA) as matrixes, loading niobium carbide nano-particles (Nb2CNPs) and vinipofen (VP) and conducting 3D printing or casting molding, the hydrogel patch is named as VP-Nb2C-coated GelMA / HAMA (VNGH) hydrogel patch for short. The VNGH has good photo-thermal antibacterial property, oxidation resistance and reepithelization promoting function, can significantly improve the quality of mouse diabetic wound healing, and provides a new thought and strategy for realizing scar-free healing of diabetic wounds.

The invention discloses a method for preparing spherical metal fine powder by using coarse / waste powder through ultrasonic atomization, which comprises the following steps of: (1) collecting coarse / waste powder raw materials for ultrasonic atomization powder preparation, (2) conveying the coarse / waste powder to an electric arc melting area through argon gas flow, and carrying out melting and ultrasonic atomization powder preparation processing; (3) in the powder preparation process, the powder is continuously collected by using argon circulating airflow, so that the continuity of the powder preparation process is ensured; and (4) finally screening the prepared powder in particle size ranges to obtain high-quality spherical fine powder in different particle size ranges. According to the method, the recycling and reusing problems of 3D printing splashing waste powder and coarse powder in the traditional gas atomization powder manufacturing process are solved, and the powder pollution risk is remarkably reduced; according to the ultrasonic atomization re-powdering technology, the high-quality spherical metal fine powder needed by additive manufacturing can be efficiently prepared, powder waste discharge and environmental burden are reduced, the obtained powder can be directly used as a high-quality raw material for additive manufacturing, and green and sustainable development of the metal additive manufacturing industry is promoted.

The invention discloses a method for preparing a light-transmitting gradient multicolor zirconium oxide material through photocuring, which comprises the following steps: preparing modified aluminum oxide which is formed by attaching a strontium element and a chromium element to the surface of aluminum oxide; preparing bottom-layer slurry, middle-layer slurry and upper-layer slurry from the zirconium-aluminum powder; the bottom layer slurry comprises zirconium aluminum powder and a coloring agent; the middle layer slurry comprises zirconium-aluminum powder, a light-transmitting auxiliary agent and a coloring agent; the upper-layer slurry comprises zirconium-aluminum powder, a light-transmitting auxiliary agent and a coloring agent; preparing a bottom layer green body by using the bottom layer slurry through 3D printing by using the photocuring slurry, preparing a middle layer green body on the surface of the bottom layer green body by using the middle layer slurry, and preparing an upper layer green body on the surface of the middle layer green body by using the upper layer slurry, so as to obtain a zirconium oxide material green body; the light-transmitting gradient multicolor zirconia material with gradient light transmission and gradient color is directly prepared through 3D printing, the color of the light-transmitting gradient multicolor zirconia material is closer to that of real teeth, and the strength and toughness are not reduced.

The invention belongs to the technical field of high polymer materials, and particularly relates to bio-based light-cured polyurethane acrylate resin as well as a preparation method and application thereof. The preparation method of the bio-based light-cured polyurethane acrylate resin comprises the following steps: (1) mixing a catalyst, a first polymerization inhibitor, first hydroxyl acrylate and itaconic acid, stirring and reacting at 90-120 DEG C for 6-9 hours to obtain a reaction product, then adding epoxidized soybean oil, and stirring at 90-120 DEG C for 3-5 hours to obtain a prepolymer; and (2) cooling the prepolymer obtained in the step (1) to room temperature, dropwise adding second acrylic hydroxyl ester and diisocyanate, and then stirring and reacting at 30-60 DEG C for 1.5-4 hours until an NCO infrared peak value disappears, thereby obtaining the polyurethane acrylate. The resin is high in bio-based content, moderate in viscosity, good in flexibility, high in hardness, strong in adhesive force, high in glossiness, small in smell and good in storage stability, and is suitable for being applied to preparation of UV curing coatings, UV curing printing ink, UV curing adhesives, 3D printing materials and nail polish glue.

The invention relates to precipitation-hardening stainless steel and a preparation method and application thereof. The stainless steel comprises the following chemical components: 0.05%-0.25% of C, 0-0.15% of Si, 0.2%-0.5% of Mn, 9%-18% of Cr, 0.2%-5% of Ni, 0.5%-5% of Mo, 0-0.5% of V, 5%-13% of Co and the balance of Fe and inevitable impurities. During preparation, alloy raw materials are forged or rolled after being smelted and cast, or prepared into spherical alloy powder through an atomization method / rotating electrode method and then subjected to 3D printing, a formed component is prepared, and then the product is obtained through aftertreatment. By controlling the proportion of alloy elements and cooperating with an optimized post-treatment process, the dispersion degree and strengthening effect of second-phase precipitation are improved, impact toughness is improved, 3D printing cracking is avoided, excellent comprehensive mechanical properties, especially high-temperature strength, are obtained, the fatigue cracking risk is reduced, the service life is prolonged, and the production cost is reduced. And the corrosion resistance of polishing, machining and complex environments is improved, and the mold can be used in the field of molds.

The invention relates to the technical field of 3D printing, and discloses a fiber reinforced composite material 3D printer and a printing method, current deposition tows are heated / cooled under the action of a preset interlayer pressing force through an interlayer pressing device, interlayer fusion can be promoted, the interlayer bonding strength can be improved, the heat history in the wire cooling process can be eliminated, and the 3D printing quality of the fiber reinforced composite material is improved. The crystallization behavior, the grain size and the grain distribution of a polymer in a printing wire material are controlled, and the microscopic uniformity of a composite material printing product is improved. The side face and the upper surface of the current deposition tow are subjected to hot-pressing shaping through the inter-channel pressing device, meanwhile, secondary hot-pressing is conducted on the adjacent printing layer deposition tow, resin of the current deposition tow and resin of the adjacent printing layer deposition tow can be melted and flow, so that the inter-channel gap between the adjacent printing layers is filled, and the printing effect is improved. And the inter-track bonding strength is improved.

The invention provides a thermal barrier coating with an interface three-dimensional bionic structure and a preparation method and application of the thermal barrier coating, and belongs to the technical field of thermal barrier coatings. By means of 3D printing, preparation of a complex, special and arrangement-distribution-controllable three-dimensional texture component with a complex geometrical shape and an internal structure can be achieved, and therefore the coating interface residual stress, the contact area and the pinning effect are improved; 3D printing can avoid internal oxidation of the bonding layer, and meanwhile it is ensured that the structure of the multi-level interface is uniform and stable; and then the ceramic layer is prepared by combining the spraying technology, preparation of the interface three-dimensional bionic structure thermal barrier coating is achieved, interface mechanical engagement of the bonding layer and the ceramic layer can be increased through the structure, an interlocking mechanism is achieved, the coating interface structure and residual stress are improved, and therefore the service life of the coating is greatly prolonged, and the bonding strength of the coating is greatly improved.

The invention relates to a rock rough interface nonlinear seepage visualization test device and method. The device is characterized in that a fissure surface digitalization module generates a digitalized fissure model by obtaining natural rock sample fissure three-dimensional point cloud data through noise reduction, feature extraction and parametric modeling; the crack test piece preparation module is used for preparing a photosensitive resin crack test piece by adopting photocuring 3D printing based on the digital crack model, and then carrying out surface silicon dioxide nanoparticle spraying treatment to obtain the crack test piece; the multi-field flow field acquisition module is used for acquiring flow field information of the crack test piece by applying a microscopic flow field visualization measurement technology; and the seepage modeling analysis module identifies a seepage interface and extracts a dominant flow path based on the flow field information, and fits a nonlinear seepage curve in combination with a Forchhe immer equation to finally obtain a three-dimensional correlation model representing fracture seepage characteristics. The device can accurately reproduce the physical characteristics and seepage environment of the natural rough fracture, and effectively capture the nonlinear seepage rule under the multi-field coupling condition.

Systems and a method for regulating a multi-part 3D printing order transfer between at least one requesting unit and a plurality of supplying units. Access to a nesting module is received. A quote module is defined for providing a price quote for a printing order based on material cost and on production cost. At least a portion of the production cost is calculated based on required build portion and on selected printing job type. For each supplying unit, it is received data on supplier auto-quote profile. Aata on a multi-part order of N parts requested by the requesting unit. For each relevant supplying unit and by using said two modules customized in via the auto-quote profiles, it is calculated a supplier quote to the nestable part subset, by applying the customized quote module—with the identified build portion size and with the type of the identified jobs as module input parameters. Supplying units are identified and the 3D printing order transfer is regulated by matching a selected set of supplying units to the requesting unit.

The invention discloses a niobium-titanium-tungsten alloy based on 3D printing, a gradient material of the niobium-titanium-tungsten alloy and a preparation method of the niobium-titanium-tungsten alloy. Mixed powder is used as a raw material, and short-process and low-cost preparation of the niobium-titanium-tungsten alloy can be achieved through multiple additive manufacturing methods. By utilizing the ratio of the pre-alloyed powder with different impurity contents, the performance of the niobium-titanium-tungsten alloy can be effectively regulated and controlled through various additive manufacturing methods; a niobium-titanium alloy coating is cladded on the surface of the niobium-titanium-tungsten alloy to form a gradient material, and the corrosion resistance of the niobium-titanium-tungsten alloy can be improved on the premise that the performance of a niobium-titanium-tungsten matrix is not obviously changed.

The invention discloses a copper-molybdenum alloy component and a manufacturing method thereof, and belongs to the technical field of alloy manufacturing. Mo powder is sequentially subjected to vacuum drying treatment, oxidation-reduction treatment and coating treatment, so that the Mo powder has good flowability and powder laying uniformity; under the preset 3D printing condition, the porous Mo framework which is stably formed and complex in structure can be obtained, the problems that an existing rolling composite method is complex in technological process, strict in technological requirement and the like are solved, and the method is suitable for manufacturing parts with small sizes or complex shapes; the porous Mo framework is subjected to vacuum thermocuring and Cu infiltration treatment, and the obtained copper-molybdenum alloy component is excellent in compactness, high-temperature stability, interface bonding strength, heat conduction, electrical conductivity and the like. The problems that a copper-molybdenum alloy obtained in the prior art is poor in wettability and low in density and uniformity, and the mass content of copper is lower than 30%, so that the heat conductivity, the electric conductivity, the air tightness and other performance are low are solved.

The invention relates to the technical field of lithium batteries, in particular to a preparation method of a high-temperature-resistant lithium battery cell. The invention discloses a preparation method of a high-temperature-resistant lithium battery cell, which is characterized in that through full-chain synergy of modification of positive and negative electrode materials, electrolyte optimization and structural design, a positive electrode adopts nickel cobalt lithium aluminate with a core-shell structure, and a metal organic framework coordination layer, polyaniline-polyacrylic acid multilayer coating and foam aluminum foil 3D printing coating are combined. The negative electrode takes silicon-carbon core-shell particles as a substrate, and breaks through the expansion bottleneck of a silicon-based negative electrode through metal organic framework confinement coating, polyaniline-polyacrylic acid cross-linked network modification and foam copper foil functionalization. The electrolyte adopts a film-forming additive and lithium difluorophosphate to form a stable SEI film, and internal resistance increase at high temperature is inhibited. The aramid fiber coating diaphragm and the aluminum alloy shell are matched, so that the thermal stability of the battery cell is remarkably improved, the battery cell can stably work in a wide temperature range environment, high energy density and long cycle life are comprehensively realized, and key support is provided for a long-endurance and high-safety battery.

The invention relates to the technical field of flexible sensors, in particular to a gradient hierarchical porous structure flexible piezoresistive sensor and a preparation method thereof. The sensor is of a laminated structure and comprises an upper flexible packaging protection layer, a lower flexible packaging protection layer, a conductive fabric electrode and a middle piezoresistive sensing layer, and a limiting frame is arranged on the periphery of the sensor. The sensing layer is prepared by adopting a 3D printing ink direct writing technology, and adopted printing slurry takes silicone rubber as a matrix and is uniformly mixed with expanded conductive microspheres and conductive filler. The printing wires are stacked in order to form a macroscopic gradient porous network structure; after the expanded microspheres are subjected to in-situ foaming, micro closed pores are formed in the material, and a rough microstructure is constructed on the surface of the wire material, so that hierarchical multi-scale regulation and control of a conductive network are realized cooperatively, contact sites are increased remarkably, and the sensitivity of the sensor is further improved effectively. The flexible piezoresistive sensor prepared by the invention has the advantages of high sensitivity, wide pressure detection range and high linearity, and has the commercial values of simple preparation process, high repeatability, lower cost and the like.

The embodiment of the invention provides a 3D printing process parameter generation method and device, equipment, a medium and a product. The method comprises the steps that a 3D printing request is received, and the 3D printing request comprises a target three-dimensional model and geometric data of the target three-dimensional model; according to the geometric data, the target three-dimensional model is subjected to layering processing, layering parameters are obtained, and the layering parameters comprise the position of each layer and the thickness of each layer; performing hierarchical calculation on the target three-dimensional model according to the geometric data and the hierarchical parameters to obtain a curved surface normal vector corresponding to a contact point on the surface of the target three-dimensional model; according to the curved surface normal vector, determining a printed piece attitude angle; and according to the attitude angle of the printed piece, the geometric data and the layering parameters, generating process parameters. According to the scheme, the matched process parameters are adaptively set at different curvature positions of the target three-dimensional model through layering processing, so that the accuracy of 3D printing is improved.

The invention discloses a preparation method of niobium-tungsten alloy spherical powder and a 3D printing method of the niobium-tungsten alloy spherical powder, and belongs to the technical field of refractory metal material preparation.The preparation method comprises the steps that niobium, tungsten, molybdenum and zirconium refractory metal raw materials are smelted to obtain cast ingots with uniform components, and hydride powder is formed after hydrotreating and mechanical crushing; spherical powder is prepared by adopting a plasma spheroidizing technology, then dehydrogenation is performed for 1-3 hours at the temperature of 450-750 DEG C, magnesium powder is added, treatment is performed for 2-5 hours in an inert atmosphere at the temperature of 800-1100 DEG C, and finally the low-oxygen niobium-tungsten alloy spherical powder with the oxygen content lower than 120 ppm is obtained. Compared with a traditional process, the spheroidizing treatment is innovatively carried out before the dehydrogenation and oxygen reduction process, the deoxidation efficiency is improved through the relatively small specific surface area of spherical powder, and oxygen content control is achieved in combination with magnesium powder heat treatment. The problems of high oxygen content and low powder yield in a traditional process are solved, and material support is provided for high-performance niobium-tungsten alloy components in the fields of aerospace, nuclear power and the like.

The invention belongs to the technical field of aerogel, and particularly relates to nylon aerogel for 3D printing as well as a preparation method and application of the nylon aerogel. The preparation method of the aerogel comprises the following steps: (1) adding an aniline monomer and ice micropowder into pre-cooled deionized water to obtain a monomer mixed solution; (2) dropwise adding an initiator into the monomer mixed solution in batches under the stirring condition of not less than 400rpm, and reacting to obtain curved polyaniline; (3) preparing a nylon mixed solution containing curved polyaniline; and (4) freeze-drying to obtain the nylon aerogel for 3D printing. According to the preparation method, an ice crystal template method and a freeze drying method are combined, so that the microstructure of the polyaniline-containing nylon aerogel is adjusted, and the nylon-based aerogel conductive polymer material is prepared. The conductive aerogel material can greatly improve the elongation at break and the conductivity of a polyurethane material, and has a wide application prospect.

The invention discloses a deformation compensation method for a 3D printing model of an oral implanting guide plate, and belongs to the technical field of computer-aided design and manufacturing. The method comprises the steps that original three-dimensional model data of the oral implanting guide plate is obtained; performing dynamic hierarchical stress accumulation analysis on the original three-dimensional model data, and generating a dynamic stress evolution field for describing the internal stress distribution and change of the model in the virtual printing process; based on the dynamic stress evolution field, generating an adaptive compensation transformation matrix for correcting geometric deformation; and performing compensation transformation on the original three-dimensional model data by using the self-adaptive compensation transformation matrix to generate high-fidelity compensation model data. A self-adaptive compensation transformation matrix is generated through dynamic hierarchical stress accumulation analysis to preprocess three-dimensional model data, complex deformation in the printing process can be accurately predicted and compensated, and therefore the forming precision of a printed piece is remarkably improved.

The utility model discloses a 3D (three-dimensional) printing integrated manufacturing device, which is characterized in that a printing switching driving mechanism is used for switching a material attached in a material containing groove in a working state through a printing switching driving mechanism to form a forming curing layer through photocuring, so that different surface models of an integrated carrying platform can be constructed, namely, different working surfaces of 3D components can be subjected to 3D printing. And integrated and one-time printing construction is realized.

The invention relates to a salt-scale-resistant anoxic TiO2 ceramic photo-thermal evaporation material with a vertical pore structure and a preparation method of the salt-scale-resistant anoxic TiO2 ceramic photo-thermal evaporation material. The salt-scale-resistant anoxic TiO2 ceramic photo-thermal evaporation material with the vertical pore channel structure is rutile phase anoxic TiO2 with a non-stoichiometric ratio, the chemical composition is TiO2-x, and x is more than 0 and less than 2; the photo-thermal evaporation material has a three-dimensional macroscopic porous structure formed by a direct-writing 3D printing technology, and an included angle between a pore channel in the three-dimensional macroscopic porous structure and a normal of an evaporation surface is 90 degrees.

This invention provides a multifunctional gradient composite filament for 3D printing, its preparation method, and its applications, relating to the field of additive manufacturing materials technology. The filament's cross-section includes at least two structurally or functionally distinguishable regions, each region composed of a thermoplastic polymer with different chemical properties, or a thermoplastic polymer matrix with the same chemical properties but different functional modifications. These at least two regions are arranged in an ordered spatial pattern on the filament's cross-section using a multi-component co-extrusion technique, enabling pre-design and integration of properties. This invention overcomes the inherent limitations of traditional single-material filaments, achieving multifunctionality and performance designability of a single filament. It significantly improves the interlayer bonding performance of multi-component 3D printing and the comprehensive mechanical properties of the printed composite material. Furthermore, it allows for the production of components with both functional gradients and high mechanical properties in a single printhead operation, making it suitable for mass production.

The invention belongs to the technical field of 3D printing, and particularly relates to a deviation real-time monitoring system for a 3D duplicating printing forming process, which comprises a three-dimensional reference feature extraction module, a printing interlayer deviation sensing module, a real-time feedback regulation and control module, a duplicating stability hidden danger output module and a user control management terminal, a high-precision reference model is constructed through a three-dimensional reference feature extraction module, a printing interlayer deviation sensing module comprehensively calculates and accurately captures interlayer deviation, a real-time feedback regulation and control module dynamically adjusts equipment and environment parameters according to a deviation value, and a stability hidden danger output module studies and judges potential risks and performs early warning. The duplicating printing performance evaluation module controls the product percent of pass and the equipment running state from the overall level, real-time monitoring, precise regulation and control and hidden danger pre-judgment of 3D duplicating printing deviation are achieved, the product reject ratio is remarkably reduced, the manual intervention cost is reduced, meanwhile, centralized management and control by a user are facilitated, and the intelligence and reliability of 3D duplicating printing are comprehensively improved.

The invention particularly relates to a UV-cured epoxy resin material for 3D printing and a preparation method of the UV-cured epoxy resin material. The epoxy resin material is prepared from the following raw materials in parts by weight: 60 to 65 parts of epoxy acrylate resin, 30 to 35 parts of epoxy resin, 2 to 5 parts of ANFs / graphene / MoS2 composite lubricant, 4 to 6 parts of flexibilizer, 3 to 5 parts of repairing agent, 3 to 5 parts of spiro orthoester, 1 to 3 parts of initiator, 0.6 to 1.5 parts of tetrahydrofuran acrylate and 0.1 to 1 part of rheology modifier. The UV-cured epoxy resin material for 3D printing obtained by the scheme has good toughness, impact resistance and wear resistance, and has good self-recovery capability and high long-term reliability under a heating condition for conditions such as slight scratches and cracks in 3D printing application.

The application relates to a modified separation membrane in the technical field of membrane materials, a preparation method and application thereof. The modified separation membrane comprises a base film and a nanostructure layer on the upper surface of the base film and the membrane hole surface close to one side of the upper surface of the base film; wherein the pore size of the base film is 120-400 mu m; the nanostructure layer is composed of microparticles with a size of 100-1000 nm; the preparation method comprises 3D printing of the separation membrane; and the upper surface of the separation membrane and the membrane hole surface close to one side of the upper surface of the separation membrane are subjected to plasma treatment. The modified separation membrane preparation method combines the 3D printing technology and the membrane separation technology, improves the traditional membrane preparation process, finds a more optimal membrane replacement process, and the modification method is free of chemical agents, has the advantages of being more convenient and fast to operate, high in separation efficiency, low in processing cost, green and pollution-free, and the like, and has important significance in the aspects of membrane separation technology improvement and application of oily wastewater treatment.