The invention discloses a metallic/ceramic composite armor and preparation method with ordered supporting structure of metallic materials as a framework and alumina ceramic materials as a core, and comprises the following steps: (1) a ceramic core plate with well-ordered pore canals is prepared and comprises working procedures such as forming, first sintering, hole machining and final sintering; (2) the ceramic core plate is sintered and metallized, all the surfaces of the finally sintered ceramic core plate is coated with Mo-Mn metal pastes, after being dried, the finally sintered ceramic core plate is metallized and sintered by being put under a protective atmosphere; (3) the metal is poured or vacuum heating treatment is made, the metal material is heated into a molten state, then poured into a die in which the ceramic core plate is arranged to have a thermostatic treatment, and finally cooled slowly to knock out. The invention can overcome weak binding of articulated connection and plane connection between the metal and the ceramic, etc., and realize high-strength binding between metallic/ceramic interfaces, moreover, the prepared metallic/ceramic composite armor with the sandwiches which can pass mutually is provided with the performance of light weight, high strength and impact resistance, thereby being suitable for a bulletproof composite armor plate and an armored panel on tanks and armored vehicles, etc.