The present application relates to a capillary array and a preparation method and application therefor. The capillary array includes: a capillary region, including a plurality of capillaries of a first glass, which are disposed in an axis-parallel manner, wherein a low
refractive index layer is disposed on an inner wall of each of the capillaries, and a
refractive index of each low
refractive index layer is less than a refractive index of a liquid
scintillator; a light
absorption layer of a second
glass material is disposed between any two adjacent capillaries; a
softening point of the first glass is T1, a
softening point of second glass is T2, and a value of T1 minus T2 is in a range from 30°C to 50°C; and a
thermal expansion coefficient of the first glass is α1; and an edge covering region, disposed on an outer side of the capillary region and making contact with an outer side face of the capillary region, wherein a material of the edge covering region is a third glass, a
softening point of the third glass is T3, and a value of T2 minus T3 is in a range from 50°C to 100°C; and a
thermal expansion coefficient of the third glass is α3, and a value of α1 minus α3 is in a range from 2×10-7 / °C to 10×10-7 / °C. The technical problem to be solved by the present application is how to prepare a capillary array that enables a liquid
scintillator fiber optical panel made of the capillary array to have a
high spatial resolution, high aperture uniformity, a
high numerical aperture, high
coupling efficiency, and a simple preparation process.