423 results about "Low smoke zero halogen" patented technology

The invention provides a tear-resistant, wear-resistant, low-smoke and non-dripping sheath material as well as a preparation method and application thereof. The tear-resistant wear-resistant low-smoke non-dripping sheath material is prepared from the following components in parts by weight: 25 to 35 parts of metallocene linear low-density polyethylene, 10 to 15 parts of ethylene-vinyl acetate copolymer, 6 to 8 parts of compatilizer, 50 to 60 parts of aluminum hydroxide, 10 to 15 parts of magnesium hydroxide, 3 to 4 parts of microencapsulated red phosphorus, 5 to 8 parts of lithium oxide synergist, 4 to 6 parts of silicone master batch, 0.3 to 0.7 part of carbon black master batch and 1.5 to 2.5 parts of coupling agent. The tear-resistant wear-resistant low-smoke non-dripping sheath material provided by the invention has the characteristics of being halogen-free, flame-retardant, tear-resistant and wear-resistant, and a low-smoke halogen-free flame-retardant power cable prepared from the sheath material has the characteristics of high smoke light transmittance during combustion, no dripping and cracking resistance.

The invention provides a low-smoke halogen-free flame-retardant cable material and a preparation method thereof, and belongs to the field of cable materials. The low-smoke halogen-free flame-retardant cable material is prepared from the following chemical components: 32 to 40 parts of nitrile rubber, 22 to 27 parts of natural rubber, 8 to 12 parts of benzoxazole-siloxane copolymer containing phosphate dynamic bonds, 13 to 15 parts of core-shell-sheath three-stage structure flame retardant, 4 to 6 parts of hexaphenoxy cyclotriphosphazene modified carbon nanotubes, 2 to 3 parts of europium-doped mesoporous cerium dioxide and 3 to 4 parts of nano zinc oxide. The composite material is prepared from the following components in parts by weight: 3 to 4 parts of carbon nanotube grafted montmorillonite hybrid, 2 to 3 parts of lubricant, 0.8 to 1.2 parts of cross-linking agent, 0.3 to 0.4 part of accelerant, 0.4 to 0.6 part of dicumyl peroxide and 0.1 to 0.2 part of antioxidant. Unification of high flame retardance, low smoke, excellent mechanical property and processability of the cable material is realized.

The invention discloses a high-temperature-resistant flame-retardant carbon fiber cable and an intelligent preparation method thereof, and relates to the technical field of power cables, and the cable is composed of a composite bearing core, a first / second electrical isolation belt, a stranded conductor, an annular composite bearing layer, a high-temperature-resistant main insulator and a low-smoke halogen-free outer sheath. The force bearing core is formed by bundling carbon fiber micro rods, elastic reset layers are arranged between the micro rods, micro-particle friction layers are formed on the outer surfaces of the micro rods, and a stable friction-rebound interface is constructed. A fire-resistant barrier, a phase change microcapsule filling layer and a fiber bragg grating can be arranged, and fire resistance, thermal peak suppression and on-line monitoring are considered. And closed-loop control of pultrusion, surface activation, coating and on-line thickness measurement / friction test is carried out in the manufacturing process. The cable can be operated at 200 DEG C for a long time and at 250 DEG C for a short time, the residual elongation is less than or equal to 0.10%, and light weight, high strength, high temperature resistance, low smoke and flame retardance are realized.

The invention discloses a crosslinked polyethylene low-smoke halogen-free flame-retardant power cable which comprises the following hierarchical structures: a conductor layer; an insulating layer; a shielding layer; the shielding layer takes polyethylene as a matrix and comprises the following components in parts by weight: 70-78 parts of matrix, 20-25 parts of carbon black and 2-5 parts of nano montmorillonite modified lignin, the thickness of the shielding layer is 0.8-1.2 mm, the shielding layer and the insulating layer are molded through a co-extrusion process, and the interface gap is less than or equal to 0.1 mm. The nano montmorillonite modified lignin is adopted as a core flame retardant, the addition amount is reduced by 10%-15% compared with that of a traditional halogen-free flame retardant, by taking a 120 mm civil cable as an example, 18 parts of modified lignin replace 25 parts of a traditional flame retardant with the same flame retardant effect, the raw material cost is reduced by 8%-12%, lignin is derived from agricultural and forestry wastes, dependence on a petroleum-based material is reduced, and the environment-friendly flame-retardant cable material is suitable for industrial production. The gradient cooling process shortens the cooling time by 20%-30% compared with the traditional single-section cold water cooling process, and meanwhile, the pre-crosslinking process reduces the subsequent forming internal stress and reduces the rejection rate.

The invention relates to the technical field of cable materials, in particular to a low-smoke halogen-free flame-retardant polyolefin cable material and a preparation process thereof. The low-smoke halogen-free flame-retardant polyolefin cable material is obtained by uniformly mixing the ethylene-vinyl acetate copolymer, the polyethylene, the compatilizer, the halogen-free flame retardant, the fuming inhibitor, the carbon black, the lubricant and the antioxidant and carrying out extrusion granulation. The low-smoke halogen-free flame-retardant polyolefin cable material comprises the following components in parts by weight: 60-80 parts of an ethylene-vinyl acetate copolymer, 20-40 parts of polyethylene, 10-20 parts of a compatilizer, 50-60 parts of a halogen-free flame retardant, 15-30 parts of a fuming inhibitor, 5-10 parts of carbon black, 1-3 parts of a lubricant and 1-2 parts of an antioxidant. The low-smoke halogen-free flame-retardant polyolefin cable material prepared by the invention has excellent mechanical properties, flame retardance and aging resistance.

The invention relates to the technical field of polyolefin cable materials, in particular to a photovoltaic weather-resistant anti-cracking low-smoke halogen-free flame-retardant polyolefin cable material and a preparation method thereof.The photovoltaic weather-resistant anti-cracking low-smoke halogen-free flame-retardant polyolefin cable material is prepared from, by weight, 90-150 parts of polyolefin resin, 1-3 parts of antioxidant, 2-5 parts of ultraviolet light absorber, 30-70 parts of composite flame retardant, 10-25 parts of carbon black and 3-5 parts of cross-linking agent; the composite flame retardant comprises a core material, a first shell material and a second shell material, the core material comprises a halloysite nanotube adsorbed with a flame retardant, the first shell material comprises epoxy resin, and the second shell material comprises maleic anhydride grafted polyethylene. According to the polyolefin cable material provided by the invention, the purpose of efficient flame retardance can be achieved by adding the halloysite nanotubes and the flame retardant system, the interfacial compatibility between the flame retardant and the matrix resin can be improved by adding the maleic anhydride grafted polyethylene, and the flame retardance of the polyolefin cable material can be improved by combining the added halloysite nanotubes and epoxy resin. The purpose of improving weather resistance, stress resistance and crack resistance of matrix resin is achieved.

The invention relates to the technical field of polymer insulating materials, in particular to a flexible low-smoke halogen-free polypropylene insulating material and a preparation method thereof. The invention discloses an ultra-soft low-smoke halogen-free polypropylene insulating material, which comprises the following components in parts by weight: 50-80 parts of block co-polypropylene; 10 to 40 parts of organic silicon rubber; 0.06 to 0.24 part of a bis-2, 5 vulcanizing agent; the material further comprises an antioxidant, a compatilizer, a flame retardant, a flame retardant synergist, a lubricant and the like. The insulation material provided by the invention is good in flexibility and convenient to install and lay under the condition of ensuring that the polypropylene cable material meets flame-retardant energy absorption and electrical insulation properties. The preparation method of the insulating material adopts a dynamic vulcanization technology, and the organic silicon rubber is distributed in the polypropylene material in a'sea-island 'or'sea-sea' structure, so that the hardness of the matrix resin is reduced on the premise of ensuring the mechanical property of the material. Meanwhile, a surface modification mode of the flame retardant is optimized, so that the hardness of the material is further reduced. And the odor emission of the material in the production and use processes can be effectively reduced, so that the material is more environment-friendly.

The present invention proposes a B1-class halogen-free, low-smoke, flame-retardant special cable and its preparation method. The cable comprises: a cable core formed by wrapping a control core and a power core, a flame-retardant filling rope, a wrapping layer, a flame-retardant tape layer, a total shielding layer, a ceramic fireproof layer, and an outer sheath. The present invention uses a cross-linked polyethylene sheath to form an outer layer of protection, a ceramic fireproof layer to form an intermediate shell flame-retardant insulation layer, and a flame-retardant tape layer combined with expandable graphite as an inner layer of buffer insulation, thereby achieving multiple flame-retardant insulation for the cable core, inhibiting the release of burning drips and toxic smoke with corrosion, and meeting and exceeding the B1-class flame-retardant requirements. By using low-smoke, halogen-free materials, the release of toxic gases can be reduced during combustion. At the same time, a double-layer hardness flame-retardant filling rope is twisted in the core to make the cable more round as a whole, and to allow the flame-retardant material to be fully filled into the cable core, achieving a better flame-retardant effect, and having certain buffering, compression resistance, torsional resistance, and fatigue resistance effects, thereby improving the mechanical properties of the cable.

The invention discloses a high-performance ship cable and a preparation process thereof, relates to the technical field of cables, and aims to solve the problem that an existing cable is insufficient in environmental adaptability, safety, electromagnetic compatibility and the like, the cable comprises a conductor, an insulating layer, a longitudinal waterproof structure, a shielding layer and a sheath layer from inside to outside, the conductor is of a multi-strand soft copper wire stranded structure, and the copper content of the multi-strand soft copper wire stranded structure is larger than or equal to 99.95%; the DC resistance at 20 DEG C is less than or equal to 0.01724 omega mm / m; the insulating layer is made of cross-linked polyethylene or polytetrafluoroethylene and can resist 1.5 times of rated voltage for 1 minute without breakdown; the longitudinal waterproof structure comprises a water-blocking tape and water-blocking paste; the shielding layer is of a double-layer structure, and the shielding effectiveness is larger than or equal to 60 dB The sheath layer is made of a low-smoke halogen-free flame-retardant material and contains an antioxidant and an ultraviolet light absorber, the preparation process comprises six steps of conductor preparation, insulating layer forming and the like, parameters are accurately controlled, the cable can work at the temperature of-40 DEG C to 85 DEG C, is salt-fog-resistant, waterproof and flame-retardant, is adaptive to the complex environment of ships and warships, and the operation reliability and safety are improved.

The invention discloses a low-smoke halogen-free self-crosslinking cable material for a photovoltaic cable and a preparation method of the low-smoke halogen-free self-crosslinking cable material. The low-smoke halogen-free self-crosslinking cable material for the photovoltaic cable is prepared from the following components in parts by weight: 40 to 50 parts of ethylene-vinyl acetate copolymer, 20 to 30 parts of polyolefin elastomer resin, 10 to 15 parts of linear low-density polyethylene, 3 to 5 parts of modified montmorillonite, 3 to 5 parts of magnesium hydroxide, 5 to 10 parts of vinyl siloxane, 0.5 to 2 parts of initiator, 1 to 2 parts of antioxidant, 1 to 2 parts of ultraviolet light absorber, 0.1 to 5 parts of compatilizer, 0.5 to 3 parts of lubricant and 0.1 to 1 part of antioxidant. And 0.3 part of a catalyst. According to the cable material provided by the invention, through collaborative design of a modified montmorillonite / magnesium hydroxide flame-retardant system, a silane self-crosslinking technology and an anti-aging functional aid, triple breakthrough of flame-retardant high efficiency, weather-resistant long-term effect and environmental protection safety is realized.

The invention discloses a drippage-free polypropylene-based low-smoke halogen-free flame-retardant cable material and a preparation method thereof, and belongs to the field of flame retardance of high polymer materials. The invention aims to solve the problems of low flame-retardant efficiency and poor mechanical and physical properties of the existing polypropylene-based low-smoke halogen-free cable material. The composite material is prepared from the following components in parts by weight: 0-100 parts of thermoplastic polypropylene, 10-50 parts of maleic anhydride grafted polypropylene, 0-80 parts of aluminum hydroxide, 0-30 parts of expanded graphite, 0-30 parts of elastomer and 0.1-3 parts of antioxidant. According to the polypropylene-based low-smoke halogen-free flame-retardant cable material, LOI can be not lower than 31.5%, vertical combustion can reach V-0 level under the UL-94 standard, drippings are not generated during combustion, and the polypropylene-based low-smoke halogen-free flame-retardant cable material is environmentally friendly, low in smoke and even free of smoke in the flame-retardant process and has excellent mechanical performance.

The invention discloses an industrial low-smoke halogen-free fireproof low-voltage cable, and relates to the technical field of low-voltage cables, an upper welding strip plate is fixedly mounted in the middle of the top end of an upper arc-shaped fitting block, and auxiliary stable supporting blocks are symmetrically mounted at the two ends of the top of the upper welding strip plate; arc-shaped anti-collision guide blocks are fixedly installed at the positions, located on the two sides of the auxiliary stable supporting block, of the two ends of the upper welding strip plate, a lower welding strip plate is fixedly installed in the middle of the bottom end of the lower arc-shaped attaching block, and trapezoidal limiting frames are symmetrically and fixedly installed at the bottom end of the lower welding strip plate. The labor intensity of carrying the cable is reduced, the placing stability of the laid cable is improved, the problems that the cable rolls and inclines to influence normal wiring or the cable rolls down from a high place to cause safety problems are solved, and after the cable slides down, a pulling pressure is generated at a wiring position to easily cause short circuit to cause a fire hazard; the cable placement stability is improved, and the cable use safety can be effectively improved.

The invention relates to the technical field of high polymer materials, and particularly discloses a B1-grade low-smoke halogen-free flame-retardant polyethylene cable material and an extrusion molding process thereof. The invention discloses a B1-grade low-smoke halogen-free flame-retardant polyethylene cable material. The cable material is prepared from the following raw material components in parts by weight: 50 to 70 parts of linear low-density polyethylene, 50 to 70 parts of ethylene-vinyl acetate copolymer, 40 to 60 parts of nanoscale magnesium hydroxide, 5 to 8 parts of microencapsulated red phosphorus, 10 to 15 parts of intumescent flame retardant, 3 to 5 parts of zinc borate and 2 to 4 parts of carbon nanotubes. According to the cable material, the ethylene-vinyl acetate copolymer can improve the dispersing performance of the inorganic filler, the composite flame retardant composed of the nanoscale magnesium hydroxide, the microencapsulated red phosphorus and the intumescent flame retardant is utilized, and the synergistic effect of the zinc borate and the carbon nanotubes is matched, so that the obtained cable material has better flame retardance, and the release of smoke is less.

The invention relates to the technical field of power cables, and discloses a high-flexibility high-temperature-resistant fireproof cable which comprises a conductor, an insulating layer, a shielding layer, an inner sheath layer, a fireproof layer and an outer sheath layer which are sequentially arranged from inside to outside, the conductor is formed by twisting multiple strands of fine copper wires, the surface of each fine copper wire is plated with a layer of tin, the insulating layer is made of a silicon rubber material, and the shielding layer is made of a silicon rubber material. A nanoscale magnesium hydroxide flame retardant and a high-temperature-resistant additive are added into the silicone rubber material; the shielding layer is a copper wire braided shielding layer; the inner sheath layer is made of a polyurethane material; the fireproof layer comprises a ceramic silicone rubber layer and a mica tape wrapping layer which are arranged in sequence; according to the scheme, the conductor is stranded by multiple strands of fine copper wires, and the diameter, the stranding pitch and the tension are optimized, so that the cable keeps excellent flexibility in frequent bending and moving environments, and the conductor is prevented from being broken. The tin coating improves the oxidation resistance and the welding performance, and ensures the long-term stability of electrical connection.

The invention relates to the technical field of cables, in particular to a multi-layer co-extrusion cable based on a low-smoke halogen-free flame-retardant composite layer and a preparation method of the multi-layer co-extrusion cable based on the low-smoke halogen-free flame-retardant composite layer, and the multi-layer co-extrusion cable structurally comprises a conductor layer, a double-layer insulating layer, a reinforced buffer layer and a composite sheath layer from inside to outside in sequence; wherein the double-layer insulating layer comprises an inner layer and an outer layer; the inner layer takes an ethylene-octylene copolymer as a core layer and takes a norbornene dianhydride grafted polyether ester elastomer as a shell layer, so that the material is endowed with high elasticity and impact resistance, and the cracking of the insulating layer is inhibited; the modified nano montmorillonite is dispersed into a nano lamellar barrier, so that heat diffusion is delayed, and low smoke and zero halogen are realized; the outer layer is composed of an ethylene-methyl acrylate matrix and di-tert-butyl phosphinic acid aluminum salt, the di-tert-butyl phosphinic acid aluminum salt is decomposed at high temperature to generate aluminum phosphate, a carbon layer is formed to isolate oxygen heat, and phosphorus-containing free radicals capture active free radicals to interrupt flame propagation.

The invention relates to the technical field of high-performance polypropylene, and discloses a low-smoke halogen-free flame-retardant polypropylene material as well as a preparation method and application thereof in automobile wires and cables. The low-smoke halogen-free flame-retardant polypropylene material disclosed by the invention is prepared from the following components in parts by weight: 70 to 80 parts of polypropylene resin, 20 to 30 parts of microencapsulated ammonium polyphosphate and 0.15 to 0.35 part of antioxidant. The capsule wall of the microencapsulated ammonium polyphosphate contains polypropylene molecular chains and has good dispersity in polypropylene resin, the capsule wall of the microcapsule contains a large number of nitrogen-containing heterocyclic rings and can be used as a nitrogen flame retardant to play a synergistic flame-retardant role with ammonium polyphosphate, the flame-retardant and smoke-suppression performance of polypropylene is improved, and the flame-retardant and smoke-suppression performance of polypropylene is improved. Microencapsulated ammonium polyphosphate has good compatibility with polypropylene resin, the influence on the mechanical property of polypropylene is small, meanwhile, after being coated with the microcapsules, ammonium polyphosphate is not prone to absorbing moisture, and the polypropylene material is not prone to absorbing moisture and has high tensile strength.

The invention provides a high-shielding-property flame-retardant fire-resistant control cable and a preparation method thereof. The cable sequentially comprises a conductor core wire, a fire-resistant insulating layer, a composite shielding layer and a flame-retardant fire-resistant sheath layer from inside to outside, the invention discloses a preparation method of a traditional Chinese medicine. The flame-retardant fireproof sheath layer is prepared from the following raw materials: 35 to 45 parts of low-smoke halogen-free flame-retardant polyolefin, 15 to 20 parts of ethylene-vinyl acetate copolymer, 8 to 12 parts of polyolefin elastomer, 6 to 10 parts of magnetic montmorillonite-based hybrid electromagnetic shielding filler, 7 to 11 parts of core-shell type ceramic flame-retardant microcapsule, 1.0 to 1.5 parts of silane coupling agent, 2 to 4 parts of basalt fiber and 0.4 to 0.7 part of cross-linking agent. 0.6 to 1.0 part of lubricant, 0.7 to 1.1 parts of stabilizer and 0.3 to 0.6 part of antioxidant. The high-shielding flame-retardant fire-resistant control cable provided by the invention has excellent electromagnetic shielding, flame-retardant and fire-resistant properties, outstanding mechanical strength, good processing fluidity, effective inhibition of thermal degradation and oxidative degradation in high-temperature processing and use processes, and good heat resistance, dimensional stability and use stability.

The invention relates to a cable sheath material, and particularly discloses a weather-proof low-smoke halogen-free flame-retardant polyolefin cable sheath material and a preparation method thereof. The cable sheath material is prepared from 30 to 45 parts of low-density polyethylene, 10 to 30 parts of high-impact homo-polypropylene, 15 to 30 parts of graft modified flexibilizer, 30 to 50 parts of main flame retardant, 1 to 5 parts of coupling agent, 10 to 30 parts of phosphorus-nitrogen synergistic flame retardant, 4 to 10 parts of efficient smoke suppressant, 0.2 to 0.8 part of hindered phenol main antioxidant, 0.4 to 1.2 parts of thioester auxiliary antioxidant, 0.4 to 1.0 part of hindered amine light stabilizer, 0.5 to 1.5 parts of ultraviolet light absorber and 2.5 to 2.5 parts of weather resistance enhancer. 5.0 parts of a lubricant, 0.5 to 2.0 parts of a lubricant, and 0.1 to 0.8 part of an anti-copper agent. The mechanical property, the electrical insulation property and the weather resistance of the sheath material are effectively improved, an efficient synergistic flame retardant effect can be obtained, the flame retardant property is excellent, and a finished product can obtain excellent weather resistance, low-smoke zero-halogen property, flame retardant property, mechanical property, electrical insulation property and the like.

The invention discloses an elastic composite shielding cable for a ship and a preparation process thereof, and aims to solve the problems of poor environmental adaptability, low shielding effectiveness, insufficient elasticity and unstable process of an existing ship cable. The cable sequentially comprises a conductor layer, an insulating layer, a composite shielding layer and a sheath layer from inside to outside, wherein the conductor layer is formed by twisting a plurality of strands of superfine tinned oxygen-free annealed copper wires, and two 1500D aromatic polyamide fiber elastic cores are arranged in the center of the conductor layer; the insulating layer is made of ethylene propylene rubber or thermoplastic elastomer, and the dielectric constant is not more than 3.0; the composite shielding layer is of a double-layer structure of aluminum-plastic composite tape wrapping and tinned copper wire weaving, and the shielding effectiveness of the X wave band is larger than or equal to 30 dB. The sheath layer is of a chloroprene rubber or polyurethane double-layer structure, tests such as C5-M-grade salt mist are carried out, the preparation process comprises the steps of conductor twisting, insulation extrusion, composite shielding forming and the like, various parameters are accurately controlled, the bending radius of the cable is smaller than or equal to 6D, and the cable is stable in performance after being repeatedly bent for 1000 times, low in smoke, halogen-free, flame-retardant, adaptive to severe environments of ships, stable in process and high in reliability. And reliable operation of ship equipment can be ensured.

The invention relates to the technical field of materials, and discloses a high-flame-retardancy low-smoke halogen-free cable sheath material and a preparation method thereof.The cable sheath material is prepared by taking a polyvinyl base material as a main raw material and taking a flexibilizer, a flame retardant and the like as auxiliary materials through mixing and extrusion processes; wherein the flame retardant is prepared by cross-linking galactomannan by using a triazine derivative containing a phosphorus flame-retardant element in the structure as a cross-linking agent, the galactomannan can be used as a carbon source, a triazine ring can be used as a nitrogen source, and the phosphorus flame retardant can be used as an acid source, so that a three-element integrated intumescent flame-retardant system can be formed, and the flame-retardant effect is good when combustion occurs. An expanded carbon layer can be rapidly formed on the surface of the sheath material, the expanded carbon layer can effectively isolate oxygen, heat and a fire source, then the flame retardant property of the sheath material is effectively improved, the aerogel structure has rich pores, smoke formed by combustion can be effectively absorbed, and the flame retardant property of the sheath material is improved. Therefore, low-smoke halogen-free modification of polyethylene is realized.

The invention discloses a high-speed extruded low-smoke halogen-free flame-retardant polyolefin material for a remote optical cable and a preparation method thereof. The polyolefin material is prepared from the following raw materials in parts by weight: 15 to 30 parts of ethylene-vinyl acetate copolymer, 5 to 8 parts of SEBS flame-retardant master batch, 8 to 11 parts of low-density polyethylene, 5 to 8 parts of maleic anhydride grafted polyethylene, 5 to 10 parts of magnesium hydroxide, 1 to 3 parts of synergistic flame retardant, 30 to 45 parts of calcium carbonate, 0.1 to 0.5 part of antioxidant and 1 to 2 parts of lubricant, the synergistic flame retardant is a shape memory microencapsulated flame retardant, and a core material of the synergistic flame retardant is a flame-retardant compound containing red phosphorus and ammonium molybdate. The polyolefin material disclosed by the invention has excellent flame retardant property, good mechanical property and flexibility and excellent chemical resistance and weather resistance, and can meet the requirements of a high-speed extrusion process.

The invention discloses a production method of a high-structural-strength insulating steel tape armored multi-core power cable. The power cable comprises a conductor unit and an insulating layer from inside to outside, wherein the conductor unit is formed by twisting and pressing a conductor with a copper base material, the conductor unit is wrapped outside the conductor, the overlapping rate of the conductor unit is larger than or equal to 50%, and the insulating layer is formed by semi-conductive ceramic silicone rubber and / or crosslinked polyethylene. The double-layer wrapping tape is composed of ceramic silicone rubber filling strips and assists the insulating core wires to be twisted into a cable and is of a filling structure; an inner sheath made of a ceramic silicone rubber material; the composite armor layer is composed of an inner-layer galvanized steel band and an outer-layer stainless steel band; the buffer layer is composed of an aramid fiber woven mesh or a ceramic fiber belt; and the outer sheath is composed of ceramic silicone rubber or a low-smoke halogen-free flame-retardant material of which the oxygen index is greater than or equal to 40. The cable is high in structural strength, good in temperature resistance and high in impact resistance, high-temperature mechanical locking is achieved through tension-controlled double-layer reverse wrapping, and the performance of the cable is greatly improved.

The invention discloses a flame-retardant, low-smoke and halogen-free environment-friendly high-voltage power cable, which relates to the technical field of high-voltage power cables and comprises a central conductor, the central conductor is externally coated with an internal insulation protection layer, and the outer side of the central conductor is sequentially coated with an insulation shielding layer, a waterproof silica gel isolation layer and an outer rubber protection layer. The outer side of the outer rubber protection layer is coated with a flexible deformation silica gel layer, the flame erosion and spreading process is intercepted through active falling of the flame-retardant rubber clamping pieces, heat is taken away in the falling process of the flame-retardant rubber clamping pieces, and a local fire insulation belt is formed; and meanwhile, in the subsequent maintenance process of the cable, corresponding fusing separation adhesive tapes and flame-retardant rubber cards need to be replaced to complete repair, so that the overall fireproof performance of the cable is improved, and the cable is protected in different degrees in different degrees of fire environments by utilizing a strategy of coping with fire disasters through layer-by-layer separation, so that the service life of the cable is prolonged, and the service life of the cable is prolonged. And the maintenance cost of the cable is effectively reduced.

The invention relates to the technical field of cable materials, and particularly discloses a low-smoke halogen-free flame-retardant cable material and a preparation method thereof. The low-smoke halogen-free flame-retardant cable material is prepared from 100 parts of polyolefin blended resin, 10 to 20 parts of polyphenyl ether, 3 to 8 parts of glycidyl methacrylate grafted POE, 1 to 3 parts of hyperbranched polyesteramide, 50 to 80 parts of a flame retardant, 5 to 15 parts of silicone powder, 0.5 to 1.5 parts of an antioxidant and 0.05 to 0.2 part of an organic zirconium compound. The preparation method comprises the following steps: uniformly mixing the raw materials to obtain a mixture; and adding the mixture into a twin-screw extruder, carrying out melt extrusion by the twin-screw extruder, cooling, granulating, and drying to obtain the low-smoke halogen-free flame-retardant cable material. The mechanical property and temperature resistance of the low-smoke halogen-free flame-retardant cable material can be improved.

The invention relates to the technical field of cable materials, and discloses a slurry-resistant silane cross-linked low-smoke halogen-free flame-retardant polyolefin sheath material and a preparation method, the slurry-resistant silane cross-linked low-smoke halogen-free flame-retardant polyolefin sheath material comprises a master batch, a material A, a material B and various materials, a halogen-free flame retardant compound system is adopted, aluminum hydroxide and magnesium hydroxide have a synergistic effect, and the slurry-resistant low-smoke halogen-free flame-retardant polyolefin sheath material is prepared through a silane coupling agent graft modification and dynamic vulcanization process. The flame retardant property, slurry resistance, mechanical property, electrical insulation property and thermal stability are comprehensively improved. The sheath material disclosed by the invention shows excellent durability and comprehensive performance under the conditions of long-term contact with drilling fluid, high temperature, high humidity and extreme weather, overcomes the problems of insufficient flame retardance, poor chemical resistance and poor thermal stability in the prior art, and meets the requirement of environmental protection at the same time. The sheath material not only meets the high-grade requirement on the flame retardant grade, but also has excellent processability and mechanical properties, and is suitable for multi-scene application of cable sheaths under complex working conditions.

The invention discloses a double-layer synergistic low-smoke halogen-free flexible cable which comprises a cable conductor, a low-smoke halogen-free polyolefin insulating layer, a shielding layer and a TPU sheath layer which are sequentially coated from inside to outside, the shore A hardness of the low-smoke halogen-free polyolefin insulating layer is 60-70, and the shore A hardness of the TPU sheath layer is 80-90; the double-layer synergistic low-smoke halogen-free flexible cable realizes the full-structure low-smoke halogen-free characteristic based on the coordination of the insulating layer and the sheath layer, has better flexibility, wear resistance and weather resistance, and can be stably used for a long time under severe conditions such as frequent bending, friction or long-term exposure.

The invention discloses a halogen-free low-smoke flame-retardant polyolefin cable which comprises a composite cable core, a first flame-retardant wrapping tape layer, an inner sheath, a second flame-retardant wrapping tape layer, a waterproof layer, a metal sheath layer and an outer sheath which are sequentially arranged from inside to outside. The outer sheath is made of a ceramic polyolefin material which is extruded and covered on the metal sheath layer. According to the low-smoke halogen-free cable, the ceramic polyolefin outer sheath is introduced into the cable structure, so that the problems of sheath softening, insulating layer stripping, structure collapse and the like of a traditional low-smoke halogen-free cable during high-temperature combustion are effectively solved. The ceramic polyolefin material can be converted into a compact ceramic layer under the action of flame to form a firm heat insulation barrier, so that the integral structure of the cable is kept complete, flame spreading and conductor short circuit are prevented, and the fire resistance and continuous power supply performance are remarkably improved.

The invention discloses a low-smoke halogen-free flame-retardant cable, and belongs to the technical field of cables, the low-smoke halogen-free flame-retardant cable sequentially comprises a conductor layer, an insulating layer, an inner sheath, a flame-retardant isolation sleeve and an outer sheath from inside to outside, a spiral bulge is arranged between the flame-retardant isolation sleeve and the outer sheath to form a spiral air duct, the inner sheath comprises a flame-retardant sheath, a thermal expansion strip, a heat conduction rib and a flame-retardant strip, the thermal expansion strip forms a heat dissipation flow channel and can be thermally expanded to form a fireproof barrier, a flowable flame retardant is arranged in the flame-retardant strip, the outer sheath is provided with a stress release suite, the stress release suite comprises a fixing sleeve, a temperature sensing ring and an isolating ring and can release stress and achieve high-temperature early warning, and a release cylinder is arranged outside the flame-retardant isolating sleeve and can be matched with the flame-retardant strip to release the flowable flame retardant when a fire occurs. The cable has the dynamic self-adaptive flame-retardant capability, gives consideration to heat dissipation and stress release, is low-smoke and halogen-free, is high in safety, and is suitable for various scenes.

The invention relates to the technical field of organic polymer materials, and particularly discloses a low-smoke halogen-free flame-retardant material and a preparation method thereof. The low-smoke halogen-free flame-retardant material is prepared from the following raw materials in parts by weight: polyolefin, an ethylene-butyl acrylate copolymer, polyurethane, dicumyl peroxide, melamine polyphosphate, a reinforced wear-resistant filler, a double-layer shell structure microcapsule, a compatilizer and an antioxidant, the reinforced wear-resistant filler is silicon carbide micro powder of which the surface is plated with a metal oxide; the microcapsule with the double-layer shell structure comprises a core material, an inner shell layer and an outer shell layer from inside to outside, the core material is molybdenum disulfide nanoparticles, the inner shell layer is a copolymer of polyester polyol and isocyanate, and the outer shell layer is poly N-isopropylacrylamide. The low-smoke halogen-free flame-retardant material disclosed by the invention can be applied to many fields such as electronic appliances, electric wires and cables, rail transit and buildings, and has the advantages of high flame retardance, less combustion smoke and high wear resistance.

The environment-friendly nuclear power high-voltage power cable comprises a cable body, and the cable body comprises a conductor, a semi-conductive shielding layer, an insulating layer, a filling layer, a belting layer, a waterproof layer, an armor layer and an outer protective layer from inside to outside in sequence; the semi-conductive shielding layer is made of a low-smoke halogen-free cross-linked polyolefin semi-conductive material; the insulating layer is made of a radiation-resistant low-smoke halogen-free cross-linked polyolefin composite material; the filling layer is a low-smoke halogen-free polypropylene filling rope; the belting layer is made of a low-smoke halogen-free polypropylene and water-based butyl rubber composite material; the semi-conductive shielding layer tightly wraps the outer side of the conductor, the semi-conductive shielding layer is made of a low-smoke halogen-free cross-linked polyolefin semi-conductive material, is used for uniformizing an electric field on the surface of the conductive wire core and preventing point discharge, and is firmly bonded with the adjacent insulating layer, and the insulating layer is made of a radiation-resistant low-smoke halogen-free cross-linked polyolefin composite material, so that the radiation-resistant low-smoke halogen-free cross-linked polyolefin semi-conductive material has good radiation resistance. And the arrangement of the filling layer, the belting layer and the outer sheath layer improves the comprehensive performance of the cable body and meets the halogen-free, low-smoke, low-toxicity and environment-friendly requirements of the cable.