High temperature resistant soft low-smoke no-halogen flame-proof polyolefine cable material

A polyolefin cable material, high temperature resistance technology, applied in the direction of insulating cables, cables, circuits, etc., can solve the problems of poor heat resistance, achieve the effect of reduced softness, excellent physical and mechanical properties, and increased softness

Active Publication Date: 2009-04-01
中广核三角洲(江苏)塑化有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The invention provides a high-temperature-resistant soft low-smoke halogen-free flame-retardant polyolefin cable material, aiming t

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063]Example 1: A high-temperature-resistant soft low-smoke halogen-free flame-retardant polyolefin cable material

[0064] 1. Raw material formula

[0065] components parts by weight Ethylene-vinyl acetate copolymer (vinyl acetate in copolymer raw material monomer

Ester weight content is 35%, Shore A hardness is less than 75) 38 Propylene-Ethylene Copolymer 38 Maleic anhydride grafted ethylene-butene copolymer, Shore A hardness less than 80 24 Aluminum hydroxide 70 magnesium hydroxide 30 Magnesium stearate 1 Tetrakis[β-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate]pentaerythritol ester 1.5 Vinyltris(β-methoxyethoxy)silane (A-172) 1.5

[0066] 2. Preparation process

[0067] First, mix ethylene-vinyl acetate copolymer, propylene-ethylene copolymer, maleic anhydride grafted ethylene-propylene copolymer, magnesium hydroxide, aluminum hydroxide, magnesium stearate and antioxidant in a high-speed mixer Finally,...

Embodiment 2

[0071] Example 2: A high-temperature-resistant soft low-smoke halogen-free flame-retardant polyolefin cable material

[0072] 1. Raw material formula

[0073] Ethylene-vinyl acetate copolymer (vinyl acetate in copolymer raw material monomer

The weight content is 40%, the Shore A hardness is less than 75) 60 Propylene-Ethylene Copolymer 25 Maleic anhydride grafted ethylene-propylene copolymer, Shore A hardness less than 80 12 Aluminum hydroxide 45 magnesium hydroxide 60 Zinc stearate 0.7 1,1,3 Tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane 0.5 γ-(Methacryloyloxy)propyltrimethoxysilane (KH-570) 2.5

[0074] 2. Preparation process

[0075] Same as embodiment one.

[0076] 3. Material properties

[0077] High-temperature-resistant soft low-smoke halogen-free flame-retardant polyolefin cable compound prepared according to the above formula and process:

[0078] Tensile strength 7.9MPa, elongation at break 310%, Shore...

Embodiment 3

[0079] Example 3: A high-temperature-resistant soft low-smoke halogen-free flame-retardant polyolefin cable material

[0080] 1. Raw material formula

[0081] Ethylene-vinyl acetate copolymer (weight of vinyl acetate in copolymer raw material monomer

Alcohol content is 50%, Shore A hardness is less than 75) 45 Propylene-Ethylene Copolymer 43 Maleic anhydride grafted ethylene-vinyl acetate copolymer, Shore A hardness less than 80 34 Aluminum hydroxide 85 magnesium hydroxide 25 stearic acid 2.4 Stearyl Propionate (Antioxidant 1076) 2.5 γ-Aminopropyltriethoxysilane (KH-550) 0.7

[0082] 2. Preparation process

[0083] Same as embodiment one.

[0084] 3. Material properties

[0085] High-temperature-resistant soft low-smoke halogen-free flame-retardant polyolefin cable compound prepared according to the above formula and process:

[0086] Tensile strength 8.3MPa, elongation at break 290%, Shore A hardness 83, limiting ...

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Abstract

The invention discloses a high temperature resistant flexible low-smoke zero-halogen flame-retardant polyolefin compound. The material formula thereof consists of the following materials: an ethylene-vinyl acetate copolymer, a propylene-ethylene copolymer, an interfacial compatilizer, a flame retardant, an antioxidant silane coupling agent and a lubricant, wherein, the Shore A hardness of the ethylene-vinyl acetate copolymer is less than 75, the weight content of the vinyl acetate in the raw material monomer is 30 percent to 70 percent, the Shore A hardness of the propylene-ethylene copolymer is less than 90, and the Shore A hardness of the interfacial compatilizer is less than 80. The invention can meet the high temperature resistant conditions of an aging test (135 DEG C 168h), and has the advantage of low cost.

Description

technical field [0001] The invention relates to a plastic used for wires and cables, in particular to a high-temperature-resistant soft low-smoke halogen-free flame-retardant polyolefin cable material. Background technique [0002] At present, soft low-smoke halogen-free flame-retardant polyolefin cable materials have been widely used in flexible cables, household appliances wires and cables and other products as a substitute for soft polyvinyl chloride (PVC) cable materials. Most of the soft low-smoke halogen-free flame-retardant polyolefin cable materials on the market use soft ethylene-octene copolymer and ethylene-vinyl acetate as the main resin substrates, and the addition of inorganic flame retardants is mostly about 50%. The heat temperature is limited to 70°C and 90°C, and under the aging conditions of the 105°C heat resistance grade (105°C 168h), melting deformation will occur due to the low melting point of the base material. In addition, compared with conventiona...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08L31/04C08L23/16C08L51/06C08K13/02H01B7/295H01B3/22
Inventor 齐兴国单永东
Owner 中广核三角洲(江苏)塑化有限公司
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