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346 results about "Ethyl carbamate" patented technology

Ethyl carbamate (also called urethane) is an organic compound with the formula CH₃CH₂OC(O)NH₂. It is an ester of carbamic acid. It is a white solid. Despite its name, it is not a component of polyurethanes. Because it is a carcinogen, it is little used, but has been detected in alcoholic beverages.

Preparing method and application of pit mud for improving flavor of baijiu in new pit

The invention belongs to the field of wine brewing and particularly relates to a preparing method and application of pit mud for improving the flavor of baijiu in a new pit. The preparing method comprises the steps of preparation, and primary fermentation and secondary fermentation of raw materials. According to the preparing method, microorganisms in yellow-water-aged pit mud diluent are used for mass propagation in primary pit mud, starter microorganisms are properly added, and thus comprehensive composite pit mud function bacteria are obtained and replace a single strain to serve as a microorganism species source. Meanwhile, yellow-water-aged pit mud diluent is used for long-time soaking, a small amount of foreshot and after-run are supplemented, and thus certain organic acid and alcohol are increased, so that the original ecology of aged pit mud is simulated, and thus microorganism fermentation is better promoted. Black peat is further added to serve as humus and replace urea added by other factories as a nutrition source, and thus ethyl carbamate is avoided. On the aspect of pit mud aging, the prepared pit mud and the aged pit mud are mixed at the bottom of the pit, fermented mass fermentation is carried out for multiple turns to promote aging of the new pit mud, the circle is short, and higher practicability is achieved.
Owner:CHENGDU SHUZHIYUAN WINE

Wine yeast capable of low-yielding hydrogen sulfide and ethyl carbamate as well as screening method and application of wine yeast

The invention particularly relates to wine yeast capable of low-yielding hydrogen sulfide and ethyl carbamate as well as a screening method and application of the wine yeast. A strain of the wine yeast is classified and named as saccharomyces cerevisiae CECLFN524 and is preserved in China General Microbiological Culture Collection Center on November 5th, 2010, and the preservation number is CGMCC NO. 4299. The strain is separated and screened in a natural fermentation process of small seedless white grapes of Xinjiang Loulan wine plant of China. The screening method comprises the steps of: after separating and purifying the strain by virtue of a WL culture medium, feeding the strain into fermentation liquid, respectively carrying out primary screening and secondary screening on a strain capable of low-yielding hydrogen sulfide by virtue of a lead acetate test paper development method and a hydrogen sulfide detection tube method, simultaneously detecting the contents of hydrogen sulfide and ethyl carbamate in the fermentation liquid, and finally screening to obtain saccharomyces cerevisiae capable of low-yielding hydrogen sulfide and ethyl carbamate. The strain can be applied to the wine-making industries.
Owner:NORTHWEST A & F UNIV

Brewing method for restraining generation of ethyl carbamate in conventional yellow rice wine

The invention discloses a brewing method for restraining the generation of ethyl carbamate in conventional yellow rice wine. The brewing method comprises the steps of soaking rice, steaming the rice, spraying water, putting the obtained product into a jar and making a nest; adding wine yeast and water, fermenting and carrying out post treatment, wherein in the process of putting the obtained product into the jar and making the nest, Chinese yeast is added; and adding urase into fermented liquid after the obtained product is put into the jar and the nest is made for 5-10 days. According to the method disclosed by the invention, the urase is added into the conventional yellow rice wine fermentation stage, so that the enzymatic reaction and the fermentation process are cooperatively performed, and no additional enzymolysis technology is required, therefore, the operation is easy, and yellow rice wine is suitable for large-scale production; the urase has high efficiency in urea degradation, is persistent in activity, can effectively inhibit the generation of ethyl carbamate in the process of brewing, and can effectively reduce the accumulation of ethyl carbamate in the storage of the yellow rice wine; the urase is easy to obtain and easy to use and the dosage of the urase can be easily controlled; ammonia and carbon dioxide are generated through the decomposition of the urase, so that the urase is safe and non-toxic; and the residual activity is lost in the process of wine boiling, so that the flavor of the yellow rice wine is not affected.
Owner:ZHEJIANG UNIV

Screening method of grape wine yeast with low-yield ethyl carbamate and application thereof

The invention discloses a screening method of grape wine yeast with low-yield ethyl carbamate and application of grape wine yeast in the production of grape wine. The screening method comprises the following steps of: screening out a bacterial strain with the low-yield ethyl carbamate from active dried yeast and mutant strains by adopting a structural analogue of arginine, i.e., canavanine resistance flat plate, wherein the activity dried yeast can be separated from nature or can be purchased in market, and the mutant strains are obtained through the mutagenesis of chemical mutagen. The method is designed by a yeast amino acid metabolism theory and is simple and convenient; and a target bacterial strain can be obtained through rapid separation. According to the screening method, the obtained resistance bacterial strain B1 can be numbered as F15-1-15 bacterial strain (CGMCC (China General Microbiological Culture Collection Center) NO. 4727) and is applied to the brewing of the grape wine in a small-sized fermented container; and on the basis of excellent brewing performance of the grape wine, the bacterial strain has the advantages of being capable of effectively and obviously reducing the content of the ethyl carbamate in the production of the grape wine and having the potential of industrial production and application.
Owner:TIANJIN UNIVERSITY OF SCIENCE AND TECHNOLOGY

Siliconstabilizers for flame retardant polyurethane- resp. polyioscyanurate rigid foams

ActiveCN101096425AFoaming agentAntioxidant
The invention relates to a process for producing rigid polyurethane or polyisocyanurate foams by reacting an isocyanate with a polyol in the presence of urethane and / or isocyanurate catalysts, water, optionally further blowing agents, optionally flame retardants and optionally further additives (e.g. fillers, emulsifiers, purely organic stabilizers and surfactants, viscosity reducers, dyes, antioxidants, UV stabilizers, antistatics) using foam stabilizers of the general formula (I) R-Si(CH3)2-O-[-Si(CH3)2-O-]n-[-Si(CH3)R- O-]m-Si(CH3)2-R, where R=-(CH2)x-O-(CH2-CHR'-O )y- R''. -27- Claims: 1. A process for producing rigid polyurethane or polyisocyanurate foams by reacting an isocyanate with a polyol in the presence of foam stabilizers, urethane and / or isocyanurate catalysts, water, optionally further blowing agents, optionally flame retardants and optionally further additives, wherein one or more compounds of the general formula (I) R-Si(CH3)2-O-[-Si(CH3)2-O-]n-Si(CH3)R1-O-]m Si(CH3)2-R2 where the substituents and indices have the following meanings: R, R1, R2 are identical or different and are each -(CH2)x-O-(CH2-CHR'-O) y-R'', R' = H, -CH3, -CH2CH3, phenyl, R'' = H, alkyl, acyl, n+m+2 = 10 to 45, m = 0 to 4, x = 3 to 10, y = 1 to 19, are used as foam stabilizers. 2. The process for producing rigid polyurethane or polyisocyanurate foams as claimed in claim 1, wherein at least 50% of the radicals R' are H. -28- 3. The process for producing rigid polyurethane or polyisocyanurate foams as claimed in claim 1 and / or 2, wherein R'' = H. 4. The process for producing rigid polyurethane or polyisocyanurate foams as claimed in at least one of claims 1 to 3, wherein m = 0 to 2. 5. The process for producing rigid polyurethane or polyisocyanurate foams - as claimed in at least one of claims 1 to 4, wherein n+m+2 = 10 to 40. 6. The process for producing rigid polyurethane or polyisocyanurate foams as claimed in at least one of claims 1 to 5.
Owner:EVONIK OPERATIONS GMBH

Preparation method and application of natural material composite system immobilized bifunctional enzyme used for wine

Belonging to the technical field of enzyme preparations and wine brewing additives, the invention relates to a preparation method and application of a natural material composite system immobilized bifunctional enzyme used for wine. The preparation method includes: subjecting the free bifunctional enzyme that is extracted from Providencia sp. JNB815 and has the activity of degrading urea and ethyl carbamate (EC) to chitosan adsorption, gelatin embedding and genipin crosslinking, thus obtaining the immobilized bifunctional enzyme. When the immobilized enzyme takes urea as the substrate, the optimum temperature is 40DEG C, and the optimum pH is 4.0; when EC is adopted as the substrate, the optimum temperature is 60DEG C, and the optimum pH is 4.5. The storage half-life periods of two enzyme activity are 54d and 45d respectively. The invention also relates to application of the immobilized bifunctional enzyme, which can reach a urea removal rate of 93.03% and an EC removal rate of 56.60%. According to the invention, the process conditions of original fermented wine cannot be changed, the wine flavor is not changed, and the immobilized bifunctional enzyme can be reused, and has more advantages in the application of removing trace urea and EC from yellow wine.
Owner:JIANGNAN UNIV

Preparation method of nanosheet magnesium oxide catalyst and method for preparing diethyl carbonate by adopting catalyst

The invention discloses a preparation method of nanosheet magnesium oxide catalyst and a method for preparing diethyl carbonate by adopting the catalyst. The preparation method of the magnesium oxide catalyst comprises the following steps: (1) mixing 0.1 to 2 mol/L magnesium salt aqueous solution and 0.1 to 12 mol/L metal salt aqueous solution precipitating agent, wherein the precipitation temperature is 20 to 80 DEG C, the pH value in the precipitation process is 9 to 12, and precipitating insoluble metal salt mixture; (2) after the precipitation is ended, continuously stirring for 0.1 to 3 hours at the temperature of 40 to 80 DEG C; (3) then hydrothermally aging for 10 to 20 hours, filtering and washing precipitates to be neutral, and drying the precipitates at the temperature of 100 to 120 DEG C for 6 to 24 hours; (4) then roasting the precipitates for 0.2 to 6 hours, and obtaining white magnesium oxide powder. The average thickness of nanosheet magnesium oxide is 20nm to 50nm, and the specific surface area is 200 to 500 m<2>/g. The catalyst is used for preparing diethyl carbonate by virtue of alcoholysis of ethyl carbamate and ethanol, the product yield is 80 percent or more, and the selectivity is 99 percent.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI
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