123 results about "Photocathode" patented technology

This invention discloses an energy storage type TiO2 / CN X The photoanode of WO3 composite material and its preparation method include the following steps: preparing WO3 nanorods by hydrothermal method; adding WO3 nanorods and anionic surfactant to water, sonicating, adding pyrrole, stirring, and then adding an initiator solution dropwise under ice bath conditions, stirring, and obtaining WO3 / PPy composite after reaction; adding WO3 / PPy composite and anionic surfactant to an alcohol solution, sonicating and stirring, adding tetrabutyl titanate, glacial acetic acid and acetone, and then adding an aqueous alcohol solution dropwise, transferring to a hydrothermal reactor for reaction, obtaining precursor TiO2 / PPy / WO3 composite after hydrothermal reaction; loading the precursor TiO2 / PPy / WO3 composite onto a conductive substrate. TiO2 / CN X / WO3's excellent sustained photocathode protection performance can be attributed to the highly conductive CN X In synergy with WO3, a narrow-bandgap semiconductor with energy storage properties, TiO2 nanoparticles with stable photoelectrochemical properties serve as the main material, ensuring the stability of the photoelectric performance of ternary materials.

The application discloses a micro-nano grating and photocathode collaborative design method. The method breaks the traditional isolated design, and considers the micro-nano grating and the photocathode as an organic whole, and takes the spectral response or integral quantum efficiency of the system as a whole as a target function. Specifically, the method comprises the following steps: establishing a system structure model and clearly defining an optimization target and process constraints; establishing a complex refractive index-wavelength correlation model of the photocathode to accurately obtain a complex refractive index distribution; determining a set of parameters to be optimized and setting initial values; calculating the system electric field distribution under the current parameters based on an electromagnetic simulation model; combining the electric field distribution and the photoelectric emission mechanism to calculate the spectral response of the system in the target waveband; and using a parameter optimization algorithm to iteratively search the parameter space, and outputting an optimal parameter combination. The application fully considers the electromagnetic and photoelectric coupling between the two and the actual process constraints, has the advantages of high design accuracy, strong pertinence, good implementability and the like, and can significantly improve the detection sensitivity of a weak light detection device.

An embodiment of the present disclosure provides a pulse electron microscope device including: a pulse generator configured to emit a laser pulse; a first beam splitter configured to split the laser pulse into a first laser pulse and a second laser pulse; a second beam splitter configured to split the second laser pulse and to reflect a second-1 laser pulse; an interval controller configured to control a time interval between the first laser pulse and the second-1 laser pulse by controlling an optical path length of the first laser pulse; a column part including a photocathode, the photocathode configured to convert the first laser pulse into a first electron pulse and convert the second-1 laser pulse into a second electron pulse; and an inspection module configured to inspect electrical defects in the sample by detecting a change in potential occurring on a surface of the sample.

The present application relates to the field of dehumidification, in particular to a photoelectrochemical auxiliary dehumidification device driven by shadow effect, the upper layer is super-hygroscopic hydrogel, the middle layer is photoelectrochemical cell, and the lower layer is shadow effect device; in the photoelectrochemical auxiliary dehumidification system provided by the present application, the moisture absorbed by the hydrogel is rapidly decomposed by the photoelectrochemical cell with enhanced voltage generated by the shadow effect device. The absorption of atmospheric moisture by the hydrogel and the voltage generated by the light contrast difference of the shadow effect device caused by the transparent photoanode of the photoelectrochemical cell from the upper layer and the light-tight photocathode result in continuous dehumidification of the closed space under zero energy input, the relative humidity in the room can be maintained below 70% without additional energy input, and a certain stable current is generated, which improves the efficiency of the dehumidification system and reduces energy consumption, and has wide application prospect.

Disclosed is an electron microscope system including a light generator including a modulator that modulates excitation light based on a control signal, an electron gun including a photocathode that generates an emission current as the modulated excitation light is radiated on the photocathode, wherein an amount of the generated emission current depends on the modulated excitation light, a sensor circuit that senses the emission current as the emission current is generated, and a control unit that generates the control signal based on an amount of a reference current and an amount of the sensed emission current.

The application belongs to the technical field of photon imaging detection, and particularly relates to a photon counting imaging detection system based on a mixed anode. The system comprises a vacuum sealed tube detector composed of a window coated with a photocathode, a microchannel plate stack and a mixed anode, and a signal processing circuit. The photocathode is used for converting photons incident through the window into photoelectrons. The microchannel plate stack is used for converting the photoelectrons into electron clouds. The mixed anode comprises a strip anode and a delay line anode arranged orthogonally, and the mixed anode transmits the collected charge short pulses of each channel to the signal processing circuit. The signal processing circuit calculates the two-dimensional coordinates of the photons based on the collected charge short pulses of each channel, and then transmits the two-dimensional coordinates of the photons to a terminal for imaging display. The application provides a photon counting imaging detection system based on a cross strip-delay line mixed anode, and solves the problem that the existing position sensitive anode detector cannot simultaneously have high spatial resolution and high temporal resolution.

The application provides an X-ray communication device and method based on a laser-driven matrix photocathode. The device is applied to the technical field of X-ray tubes and comprises a laser control circuit, a matrix transmission photocathode array, a collimating microchannel plate, a matrix transmission anode target array, a vacuum tube shell and a beryllium window. The method comprises: generating a dynamic pattern, loading data information to be input into an optical signal; and exciting photoelectron emission with spatial resolution characteristics at a corresponding photocathode pixel area; each channel cluster is aligned with a single photocathode pixel at the front end; after the electrons enter the microchannel, continuous secondary electron emission occurs under the action of the electric field on the inner wall of the channel, and an avalanche effect is generated; and through mechanisms such as bremsstrahlung radiation, a bundle of microfocus X-rays is generated at each target point. In this way, the technical problems of the X-ray source in the prior art, such as the limitation in spatial coding capability, response speed, integration degree and communication dimension, can be solved.

The invention discloses a vacuum and solid integrated lightweight digital solar blind ultraviolet device, which comprises a glass input window, an ultraviolet photocathode, a microchannel plate, a digital readout circuit chip and a ceramic tube shell, the ultraviolet photocathode is attached to the front surface of the glass input window; the ultraviolet photocathode, the micro-channel plate and the digital readout circuit chip are arranged in a vacuum chamber of the ceramic tube shell; the micro-channel plate is positioned right below the ultraviolet photocathode; the digital readout circuit chip is located right below the micro-channel plate, and the device adopts a proximity packaging structure. The device is a high-resolution, integrated and lightweight vacuum digital solar blind device, does not need coupling, is integrated, realizes image digital output, is convenient to use and signal transmission, and is safe and reliable to use.

The application discloses a molybdenum monatomic anchored gamma-Fe2O3 photoelectric cathode catalyst, a preparation method of an electrode thereof and application of the catalyst to photoelectrocatalytic degradation of pollutants in water bodies. The molybdenum monatomic anchored gamma-Fe2O3 photoelectric cathode catalyst comprises a gamma-Fe2O3 carrier and molybdenum atoms anchored on the surface of the gamma-Fe2O3 carrier in the form of monatomic atoms, wherein the molybdenum atoms are anchored by replacing part of iron sites in the gamma-Fe2O3 crystal lattice. The preparation method comprises the following steps: mixing and impregnating a molybdenum precursor solution with gamma-Fe2O3, and evaporating dry; and performing twice calcination on the obtained solid to obtain the molybdenum monatomic anchored gamma-Fe2O3 photoelectric cathode catalyst; in the twice calcination, the first time calcination is performed at 250-350 DEG C in an oxygen-containing atmosphere, and the second time calcination is performed at 450-550 DEG C in an inert atmosphere.

The invention provides an X-ray communication device and method based on a laser driving matrix type photocathode. The device is applied to the technical field of X-ray tubes and comprises a laser control circuit, a matrix transmission type photocathode array, a collimation type structure micro-channel plate, a matrix transmission type anode target array, a vacuum tube shell and a beryllium window. The method comprises the following steps: generating a dynamic pattern, and loading data information to be input into an optical signal; photoelectron emission with spatial resolution characteristics is excited in a corresponding photocathode pixel area; each channel cluster is aligned with a single photocathode pixel at the front end; after the electrons enter the micro-channel, continuous secondary electron emission occurs under the action of an electric field on the inner wall of the channel, and an avalanche effect is generated; a beam of micro-focus X-rays is generated at each target spot through mechanisms such as tough-induced radiation. In this way, the technical problem that in the prior art, an X-ray source is limited in space coding capacity, response speed, integration degree and communication dimension can be solved.

The invention belongs to the technical field of photoelectrocatalysis, and particularly relates to a preparation method of a double-confinement hollow photocathode and application of the double-confinement hollow photocathode in synthesis of ammonia from nitrate wastewater through photoelectric reduction. According to the method, based on an ion exchange and in-situ growth strategy, a FeMnO3 / CuFe2O4 / Ti hollow cube integrated photocathode is constructed, hydroxyl functionalized ionic liquid (OH-ILs) is further introduced through vacuum impregnation, and an ILs (at) FeMnO3 / CuFe2O4 / Ti nanoreactor with a dual confinement effect is formed. Under ultraviolet-visible-near infrared (UV-Vis-NIR) illumination, the photocathode can remarkably promote separation of photo-induced electron-hole pairs, the charge transfer efficiency is improved, and high-selectivity and high-efficiency ammonia synthesis is achieved. Experiments show that the photocathode can almost completely convert nitrate in high-concentration nitrate wastewater (50mM) within 2.5 hours, so that the effluent reaches the drinking water standard of the World Health Organization (WHO). In a flowing electrolytic tank, the ammonia yield reaches 20.51 mg h <-1 > cm <-2 >, the Faraday efficiency reaches up to 97.75%, and excellent catalytic performance is shown.

The invention discloses a carbon nanotube / cadmium selenide quantum dot heterojunction photoelectric catalyst as well as a preparation method and application thereof. The method comprises the following steps: activating single-wall and / or multi-wall carbon nanotubes by aqua regia at room temperature, dispersing the single-wall and / or multi-wall carbon nanotubes in an aqueous solution containing CdCl2. 5H2O, adding a Na2SeSO3 selenium source and 3-mercaptopropionic acid, and reacting at 110-150 DEG C, so that CdSe quantum dots with the particle size of 1-5 nm are subjected to in-situ nucleation growth on the surfaces and / or the interiors of the carbon nanotubes and form a heterojunction interface. The obtained catalyst and Nafion are prepared into ink drops, the ink drops are coated on conductive glass to construct a photocathode, in an H-type electrolytic tank with a light path, a high-purity CO2 saturated bicarbonate aqueous solution is used as an electrolyte, Ag / AgCl is used as a reference electrode, and under irradiation of an LED light source with the maximum wavelength being 450 nm and bias voltage ranging from-0.1 V (vs. RHE) to-1.0 V (vs. RHE), CO is generated through water-phase photoelectrocatalysis CO2 reduction. The photoelectrocatalyst has the characteristics of simple synthesis method and excellent photoelectrocatalytic reduction effect of carbon dioxide.

There is disclosed a gated power supply for a night vision system includes an input terminal to receive source power, and output terminal to electrically couple to a photocathode, a first voltage source to source a positive or neutral voltage to the photocathode, a second voltage source to source a large negative voltage to the photocathode, and a switching circuit to switch between the first voltage source and the second voltage source on a duty cycle, wherein the switching circuit comprises an optical switch.

The invention discloses a synchrotron radiation hard X-ray electron coupling nanoscale high spatial resolution detection method. The method comprises the following steps: 1) selecting synchrotron radiation hard X-rays as a light source; selecting a matched light source energy interval according to the material and thickness of the sample; 2) according to the selected synchrotron radiation hard X-ray energy, selecting a point spread function with high quantum efficiency, a small point spread function and a narrow emission electron spectrum, and calculating a corresponding photocathode material and thickness; 3) detecting the sample by using the light source and the photocathode determined in the above step to obtain a synchrotron radiation hard X-ray transmission image carrying sample structure information, and incidence the synchrotron radiation hard X-ray transmission image on the photocathode; the photocathode emits electrons under the action of incident photons, converts an X-ray transmission signal into an electronic signal, inputs the electronic signal into the electronic imaging system for focusing, amplifying and imaging, and inputs the electronic signal into the imaging recording system; and 4) obtaining a detection result of the sample according to the image recorded by the imaging recording system.

The invention discloses a laser speed measuring device. According to the laser speed measurement device, a photoelectric cathode is connected with a micro-channel plate through a vacuum bonding technology, and the photoelectric cathode is used for converting a laser signal into a photoelectronic signal and transmitting the photoelectronic signal to the micro-channel plate; the micro-channel plate is connected with the fluorescent screen through a vacuum bonding technology, and the micro-channel plate is used for carrying out electron multiplication processing on the photoelectron signals and transmitting enhanced electronic signals to the fluorescent screen; the fluorescent screen is connected with the nano optical fiber taper coupling structure through a vacuum bonding technology, and the fluorescent screen is used for sending a visible light signal to the nano optical fiber taper coupling structure; the nano optical fiber taper coupling structure is connected with the CCD chip, and the nano optical fiber taper coupling structure is used for transmitting the visible light signal to the CCD chip; the CCD chip is used for receiving the visible light signal, converting the visible light signal into a digital signal and transmitting the digital signal to the control module so as to determine speed data of the laser signal according to the digital signal. According to the invention, the transmission efficiency of the laser signal is improved, and the determination precision of the speed data of the laser signal is improved.

Disclosed is an imaging apparatus comprising: a segmented scintillator structure; and a photocathode structure optically coupled to the segmented scintillator structure, for conversion of high-energy particles with an arbitrary spatial distribution to a corresponding distribution of photoelectrons, emitted with a spread in energy ranging from 100 meV to 1 meV. Also disclosed is an imaging apparatus comprising: a segmented scintillator structure, and a photocathode structure optically coupled to the segmented scintillator structure, for conversion of high-energy particles with an arbitrary spatial distribution to a corresponding distribution of photoelectrons, emitted with an angular spread ranging from 10 degrees to 0.1 degrees. Also disclosed is a pressureless filling of capillary tubes and nano-molds using electroosmosis effect.

This invention discloses a miniaturized high-repetition-rate pulsed photocathode electron gun, comprising a laser, a shaping optical path, and a photocathode electron gun arranged sequentially. The photocathode electron gun includes a front electrode and a quaternary electronic lens group. The laser serves as the light source for the shaping optical path, which precisely and stably transmits the laser beam to the photocathode surface. The cathode of the front electrode of the photocathode electron gun generates photoelectrons, and the front electrode controls the intensity of the emitted electron beam. The quaternary electronic lens group of the photocathode electron gun adjusts the uniformity of the emitted electron beam. This invention achieves high-quality electron beams while possessing advantages such as compact structure and miniaturization.

This invention belongs to the field of photoelectrochemical detection, specifically relating to a method for fabricating a photo-assisted all-solid-state zinc-air battery self-powered sensor based on a signal reversal strategy and its application in detecting theophylline. Using CuInS2 as the photocathode, CdS is loaded onto the photocathode using a split aptamer technique. Polished zinc foil is used as the anode, and PVA gel polymer is used as the solid electrolyte to construct a photo-assisted all-solid-state zinc-air battery self-powered sensor based on a signal reversal strategy. This invention achieves signal reversal by incorporating split aptamer technology, thereby significantly improving the detection sensitivity for antioxidants. The constructed photo-assisted all-solid-state zinc-air battery self-powered sensor based on a signal reversal strategy also has a wide detection range, low detection limit, and low detection cost.

This invention discloses a MIL-100(Fe)-CdS-sodium alginate composite film for long-term photocathode protection in seawater environments and its preparation method, belonging to the field of photocathode protection technology. The method includes the following steps: cleaning conductive glass; growing a MIL-100(Fe) thin film on the conductive glass using a hydrothermal method; growing a MIL-100(Fe)-CdS composite film on the surface of the MIL-100(Fe) thin film using a dip-coating method; and growing sodium alginate (SA) hydrogel on the surface of the MIL-100(Fe)-CdS using an in-situ drop-coating method. This invention utilizes the heterojunction of MIL-100(Fe) and CdS, and uses a loaded sodium alginate hydrogel as a protective layer, solving the problem of severe photoelectric conversion efficiency degradation in existing photoanodes during long-term seawater immersion. After coupling with a metal, the current generated under illumination causes cathodic polarization of the metal, and the hydrogel layer delays the loss of active materials. The synergistic effect of these two factors results in long-term stable photochemical cathodic protection performance in seawater environments.

The invention belongs to the technical field of biosensors, and discloses a photoelectrochemical immunosensor based on a dendritic peptide tetramer as well as a preparation method and application of the photoelectrochemical immunosensor. The dendritic peptide tetramer is adopted to construct the photoelectrochemical immunosensor for the first time, and the method comprises the following steps: preparing an HsGDY / Cu2O photocathode, and sequentially anchoring an antibody probe and the dendritic peptide tetramer on the surface of the photocathode. Through specific binding of a target object and the antibody probe, a significant steric hindrance effect is generated on an electrode interface, interface charge transfer is hindered, photocurrent signal change is caused, and detection of the target object staphylococcus aureus enterotoxin A is realized. The photoelectrochemical immunosensor provided by the invention is simple, convenient and efficient in preparation process, has excellent food matrix biological pollution resistance, can effectively inhibit non-specific adsorption so as to significantly improve the sensitivity, specificity and accuracy of detection, is suitable for the field of food safety detection, and is suitable for market popularization and application.

The invention discloses a hybrid photomultiplier coaxial output structure based on a microstrip line. The hybrid photomultiplier coaxial output structure comprises a semiconductor detector, a bonding wire, the microstrip line, a ground electrode, a lead pin, a medium, an outer conductor base and a detector lead pin. The semiconductor detector is used for receiving the photoelectrons converted by the photoelectric cathode and generating a current signal; the bonding wire is used for electrically connecting the semiconductor detector and the microstrip structure; the microstrip line and the ground electrode adopt gold-plated kovar alloy parts to form an in-tube microstrip structure; the guide pin and the detector guide pin are kovar alloy guide pins and form an inner conductor with a coaxial structure; the outer conductor base is a kovar alloy disc and forms an outer conductor with a coaxial structure; the medium is glass or ceramic. According to the coaxial output structure, a vacuum tube is of a 50-ohm microstrip structure, the exterior of the vacuum tube is of a 50-ohm SMA coaxial structure, and a complete 50-ohm coaxial line is formed by connecting a microstrip line and a guide pin together. The structure provided by the invention has the advantages of high transmission speed, small signal reflection and oscillation and the like, and is more beneficial to detection of ultrafast optical pulse signals.

The application discloses a self-supporting thin film photocathode design method for improving the dynamic range of a transmission grating spectrometer, and the photocathode is designed by using a self-supporting thin film and an equal-width photocathode slit, so that the difference in photoelectron density in the high-energy area and the low-energy area of a diffraction spectrum is reduced, the dynamic range of the time-resolved transmission grating spectrometer is improved, and the time resolution of the spectrometer along the length direction of the photocathode is kept unchanged. Compared with a conventional equal-width photocathode and a flat-response photocathode, the self-supporting thin film photocathode can reduce the difference in photoelectron density in the high-energy area and the low-energy area of the diffraction spectrum on the photocathode, and improve the dynamic range of the spectrometer. Compared with a width-second-gradual photocathode, the self-supporting thin film photocathode can keep the time resolution of the time-resolved transmission grating spectrometer along the length direction of the photocathode unchanged, and solve the problem that the quantitative spectral analysis is difficult due to the change of the time resolution of the width-second-gradual photocathode along the length direction of the photocathode.

The present application relates to the technical field of spectral imaging detection, and particularly relates to a cross-bar anode photon counting imaging detector splicing system and a splicing method, which respectively cover ultraviolet, visible and near-infrared bands, each detector unit comprises a vacuum sealed tube composed of a glass window coated with a photocathode, a cylindrical micro-channel plate stack, a resistance anode and a cross-bar anode, and a position reading circuit, wherein the curvature radius of the cylindrical MCP stack is matched with the focal plane curvature radius of the Rowland circle spectrometer to improve the spectral resolution. Four detector units are connected in one-to-one correspondence to form a long strip electrode array in the direction perpendicular to the spectral imaging direction, and the position reading circuit is used for processing charge pulses to determine the electron cloud centroid position. The curvature radius of the cross-bar anode single-photon imaging detector unit can be matched with the curvature radius of the cylindrical focal plane of the Rowland circle spectrometer, the spectral resolution of the spectrometer is improved, and continuous imaging of a wide spectral band of 115 nm to 900 nm is realized.

The application relates to a manganese-cadmium-sulfur / crystalline silicon composite water photolysis photocathode and a preparation method and application thereof. The method is as follows: manganese-cadmium-sulfur nanoparticles with a specific component ratio are synthesized through a hydrothermal method, then a drop-coating process is adopted, and drop-coating process parameters are controlled, so that a manganese-cadmium-sulfur / silicon heterojunction photocathode is successfully constructed on crystalline silicon with a pn junction structure and a surface pyramid light-trapping microstructure. The photocathode has excellent photocatalytic activity and water photolysis efficiency, and has good catalytic stability.

An electron beam device has a semiconductor ultraviolet light source (SULS), a photocathode attached to the SULS, a photocathode electrode attached to the photocathode, an anode having a first surface facing towards a first surface of the photocathode, and a separation layer located between and in contact with the first surface of the photocathode and the first surface of the anode. The separation layer is configured to create a gap between the first surface of the photocathode and the first surface of the anode. The SULS generates photoelectrons at the first surface of the photocathode that are transmitted via the gap to the anode. The SULS, the photocathode, the photocathode electrode, the anode, and the separation layer are configured together as a monolithic integrated element. An alternate electron beam device has a SULS spaced from the photocathode, an anode located between the SULS and the photocathode, a controlling electrode located between the anode and the photocathode, and a separation layer located to create a gap.

The application discloses a novel ray detector, characterized in that the novel ray detector comprises a Cerenkov radiation material window, a photocathode surface plated on a light exit surface of the Cerenkov radiation material window, a microchannel plate and a readout circuit board; wherein the Cerenkov radiation material window is a glass optical fiber panel, used for receiving incident gamma rays and inputting Cerenkov light generated by the incident gamma rays into a fiber core to the photocathode surface; the photocathode surface is used for converting the Cerenkov light into photoelectrons and transmitting the photoelectrons to the microchannel plate through a vacuum electric field; and the microchannel plate is used for inputting the received photoelectrons into the readout circuit board after amplification by multiplication. The application can realize better position resolution.

The present invention relates to a water electrolysis device comprising a plurality of nanopillars. Each nanopillar has a vertical extension in relation to a plane of extension of a substrate supporting the nanopillars. Further, each nanopillar comprises a plurality of quantum dot segments of InxGa1-xN alloy, wherein each quantum dot segment is interposed along the vertical extension between barrier segments of GaN, wherein each quantum dot segment has a thickness of less than or equal to 20 nm along the vertical extension. Moreover, each nanopillar comprises a p-side portion constituting a photoanode and an n-side portion constituting a photocathode, wherein the photoanode comprises at least one quantum dot segment and the photocathode comprises at least one quantum dot segment, wherein the photoanode and the photocathode are separated by a depletion portion comprising GaN. A system for water electrolysis comprising such a water electrolysis device is also presented.

The present application relates to a kind of manganese cadmium sulfur / silicon composite photocathode based on constant current electrodeposition method and preparation method and application thereof.The method is in situ grown with hollow microspheres structure manganese cadmium sulfur on the surface of crystalline silicon with pn junction and surface light trapping microstructure by constant current electrodeposition technology, thereby forming manganese cadmium sulfur / silicon composite photocathode.By controlling the specific conditions in the electrodeposition process, such as the type of Mn source, Cd source and S source, the concentration range thereof, the current density of electrodeposition, the time of electrodeposition, the composition of electrolyte system, such as the type of solvent and the addition of supporting electrolyte, the element ratio of manganese and cadmium in the electrodeposition process is accurately controlled, so that a uniform, dense and firmly bonded MnCdS film is formed on the surface of crystalline silicon with specific microstructure.The photocatalytic activity, water splitting efficiency and catalytic stability of the photocathode are significantly improved.

The invention discloses a double-indium-sealed image tube which comprises a tube shell, a photoelectric cathode assembled with a first end of the tube shell and a fluorescent screen assembly assembled with a second end opposite to the tube shell. A first indium sealing layer for fixing the first end and the photoelectric cathode together is arranged between the first end of the tube shell and the photoelectric cathode, and a second indium sealing layer for fixing the second end and the fluorescent screen assembly together is arranged between the second end of the tube shell and the fluorescent screen assembly. According to the double-indium-sealed image tube, pollution to the tube shell and the surface of the fluorescent screen is effectively reduced. In addition, the invention also discloses a manufacturing method of the double-indium-sealed image tube.