This invention provides an iron-based secondary
hydrogen conversion catalyst, its preparation method, and its application. The catalyst is prepared by treating
alumina with N and Mg, and then using the treated
alumina as a support. The iron loading is 10-25% of the
alumina mass. When used in the secondary
hydrogen conversion reaction, the catalyst achieves a conversion rate of 92.6%-98.4%. This invention introduces
alkali metal ions onto the surface of the nitrided alumina, forming a thin-shell distribution on the
support surface, reducing
diffusion resistance and thus improving catalytic activity. Simultaneously, a
magnesium-aluminum
spinel structure is formed on the modified
support surface, providing more tetrahedral defect sites for the
active components, further enhancing catalytic activity. The catalyst particle strength is ≥350 N / cm². 2 The wear rate is less than 0.5%, which significantly improves the flow resistance of the catalyst
bed under the conditions of positive and negative
hydrogen conversion.