6375 results about "SILICONE DIOXIDE" patented technology

A method of continuous 3D printing to print an article is provided. The method includes displacing a nozzle of the 3D printer in a nozzle displacement direction; extruding the ink from the nozzle concurrently with the displacement of the nozzle to form an extrudate on the porous substrate; and displacing the rotating magnetic field in the nozzle displacement direction simultaneously with the displacement of the nozzle. The ink includes a plurality of magnetically responsive particles and a colloidal gel. The colloidal gel may include fumed silica in an aqueous solution.

The invention relates to the field of pressure sensors, in particular to a pressure sensor and a processing method, and a chip comprises a silicon substrate, a silicon dioxide dielectric layer, a device layer, a metal electrode and packaging glass. The device layer comprises a silicon carbide single crystal device layer and a silicon device layer; the silicon carbide single crystal device layer is arranged on the silicon device layer; the silicon device layer, the silicon dioxide dielectric layer and the silicon substrate are connected in sequence; the device layer is etched to form a sensitive resistor device layer, an annular sealing region and a micro-channel; the sensitive resistance device layer is isolated from the annular sealing area through the micro-channel; the device layer, the silicon dioxide dielectric layer and the silicon substrate are etched to form a cross beam etching area; the silicon substrate is etched to form a silicon pressure cavity and a beam film; the metal electrode is arranged on the top of the device layer; and the packaging glass anode is bonded at the top of the device layer or the bottom of the silicon substrate so as to solve the problems of low high temperature resistance and low sensitivity of the MEMS pressure sensor.

The invention relates to the technical field of folding screen supporting films, and particularly discloses a double-layer buffering supporting film for a flexible folding display screen and a preparation method of the double-layer buffering supporting film. The double-layer buffer supporting film for the flexible folding display screen sequentially comprises a release film layer, a first adhesive layer, a first stainless steel layer, a second adhesive layer, a second stainless steel layer and a protective film layer from top to bottom, the first adhesive layer and the second adhesive layer are prepared by curing the same pressure-sensitive adhesive composition; the pressure-sensitive adhesive composition is prepared from the following raw materials: acrylate copolymer, hydrogenated rosin glyceride, hyperbranched polyesteramide-dopamine conjugate, acylhydrazone bond modified siloxane, a curing agent and a silane coupling agent; the protective film layer comprises the following raw materials: PET particles, nano silicon dioxide, an ethylene-vinyl acetate copolymer and an antioxidant. The double-layer buffer supporting film has the advantages of being high in supporting rigidity and interlayer peel strength, and serious folds caused by long-term repeated folding of the folding screen can be relieved.

The invention provides a preparation method of a porous carbon-silicon composite negative electrode material of a lithium battery. The preparation method comprises the following steps: constructing a multi-stage template system; carrying out carbon precursor impregnation and gradient temperature carbonization on the multistage template system; removing the template to form a gradient porous carbon carrier; carrying out gradient temperature zone silane deposition; and plasma-assisted carbon coating and nitrogen doping are carried out. According to the method, a silicon dioxide sphere hard template is combined with cetyltrimethylammonium bromide and a block copolymer soft template to form a porous carbon carrier with a micropore-mesopore-macropore three-stage structure, and gradient distribution of silicon in porous carbon is realized by utilizing a three-temperature-zone fluidized bed reactor and a pulse type deposition technology, so that the silicon-based porous carbon composite material is obtained. The problem of volume expansion of the silicon material is effectively relieved and the material cycling stability is improved. The porous carbon-silicon composite negative electrode material prepared by the invention has high specific surface area, excellent ion transmission channel and good structural stability, and can be applied to a high-energy-density lithium ion battery.

The invention discloses an MEMS device architecture, which comprises a cap layer, a device layer and a substrate layer, the cap layer is bonded with the device layer, the bonded whole is bonded with the substrate layer, the cap layer is manufactured based on a first silicon substrate, the bottom of the cap layer is provided with a cavity structure, and the cap layer is internally provided with a high-deep groove structure. A silicon dioxide film is arranged on the groove wall of the high-deep groove structure, polycrystalline silicon is deposited and filled in the high-deep groove structure, and a silicon dioxide layer is arranged on the upper surface of the first silicon substrate; the device layer is manufactured based on an SOI wafer and comprises a first silicon structure layer composed of top layer silicon, a buried oxide layer and a second silicon structure layer composed of back substrate silicon. The substrate layer comprises a second silicon substrate, a bottom layer cavity is formed in the top face of the second silicon substrate, and exhaust holes are formed in the bottom face of the second silicon substrate. According to the method, deep groove etching, polycrystalline silicon groove filling and bonding technologies are combined, advanced materials such as the SOI wafer and the polyimide layer are utilized, and excellent signal isolation and flexibility of various MEMS IMU applications are achieved.

The invention provides a hot in-place recycling asphalt mixture and a construction method, and relates to the technical field of asphalt mixtures, and the hot in-place recycling asphalt mixture is obtained by recycling old asphalt pavement materials in a high proportion, reducing new material consumption and carbon emission, realizing resource recycling and green construction and introducing a regenerant to recover the performance of aged asphalt. The high-temperature rut resistance, the low-temperature crack resistance, the fatigue resistance and the interface bonding strength of the mixture are synergistically improved by matching with the styrene butadiene rubber modifier, the basalt fiber, the nano silicon dioxide and other functional materials, and the mixture is ensured to be uniform and free of segregation through precise feeding sequence, high-pressure atomization spraying and forced stirring parameter control. The defects of gray materials, oil balls and the like are avoided, the compactness, the flatness and the overall structure stability of the regenerated pavement are improved, and the problems of performance degradation and insufficient durability of a traditional regenerated mixture are solved.

The invention relates to a multi-layer composite black film and a preparation method thereof. The multi-layer composite black film is formed by sequentially stacking a base material layer, a multi-layer film system and a top covering layer, the multi-layer film system is formed by alternately stacking a plurality of absorption layers and a plurality of oxide layers, the number of the layers is 7-30, an initial layer is an oxide layer, the refractive indexes of the oxide layers are the same (1.4-1.5), the thickness ratio of the oxide layers to the absorption layers is larger than 2, and the thickness ratio of the top covering layer to the absorption layers is larger than 1. And the thicknesses of the two layers are increased and then reduced from the substrate layer to the top covering layer. A buffer layer with gradually changed oxygen content is arranged between the oxide layer and the absorption layer, and both the oxide layer and the top covering layer are made of silicon dioxide. The preparation method comprises the following steps: providing the substrate layer, alternately depositing the absorption layer and the oxide layer by using a magnetron sputtering or electron beam evaporation process to form a multilayer film system, then forming the top covering layer, controlling parameters such as vacuum degree, power, temperature and the like during deposition, and forming the buffer layer in the same cavity. The multilayer composite black film has the inner surface reflectivity of less than 1% and the appearance surface reflectivity of less than 5%, and is simple in structure and low in preparation cost.

The invention discloses a lithium battery diaphragm coating based on a nano material and application thereof, and relates to the technical field of lithium battery diaphragms. The coating comprises the following raw materials in parts by weight: 15-25 parts of polystyrene maleic anhydride copolymer modified polyvinylidene fluoride, 10-20 parts of polystyrene, 2-4 parts of nano silicon nitride, 3-6 parts of a boehmite / aluminum oxide and silicon dioxide composite material, 1-2 parts of a dispersing agent and 65-90 parts of a solvent, according to the lithium battery diaphragm coating provided by the invention, the wettability and absorptivity of a diaphragm to an electrolyte are remarkably improved, meanwhile, the lithium battery diaphragm coating also has excellent thermal stability, and the diaphragm can be effectively prevented from thermal shrinkage or melting under a high-temperature condition, so that the safety performance of a battery is remarkably enhanced.

The invention relates to ultrahigh-transmittance anti-reflection multifunctional coated photovoltaic glass and a preparation method thereof, and belongs to the technical field of photovoltaic glass, the photovoltaic glass comprises a photovoltaic glass substrate, the photovoltaic glass substrate is provided with a high-transmittance reflective coating, the high-transmittance reflective coating comprises a silicon dioxide layer, a titanium dioxide layer and a nanometer material layer, and the nanometer material layer is arranged on the silicon dioxide layer. The silicon dioxide layer and the titanium dioxide layer are arranged between the photovoltaic glass substrate and the nanometer material. The preparation method comprises the following steps: S1, preparing raw materials; s2, preparing a coating; s3, coating process; s4, performing surface treatment on the nano structure; s5, coating curing and surface treatment; and S6, testing and evaluating the performance. According to the ultrahigh-transmittance anti-reflection multifunctional coated photovoltaic glass, the performance and durability of a photovoltaic cell can be remarkably improved, by arranging the high-transmittance anti-reflection coating, the light transmittance of the photovoltaic glass is improved, the overall photoelectric conversion efficiency can be improved by 5-8%, and light reflection loss is remarkably reduced.

The invention discloses a high-strength directly-buried optical cable and a preparation method thereof. Comprising at least one reinforcing piece, at least one cable core, a water-blocking tape layer, an inner protective layer, an armor layer and a high-strength outer sheath, wherein the cable core surrounds the reinforcing piece, is twisted and is filled with water-blocking cable paste; the water-blocking tape layer wraps the cable core; the inner protective layer wraps the water-blocking tape layer; wherein the cable core is composed of a loose tube filled with water-blocking fiber paste and at least one light-guide fiber accommodated in the loose tube; wherein the high-strength outer sheath is prepared from the following raw materials in parts by weight: 80 to 85 parts of high-density polyethylene, 15 to 20 parts of nylon 612, 8 to 12 parts of compatilizer, 15 to 20 parts of modified silicon dioxide, 1 to 3 parts of antioxidant and 0.7 to 1.1 parts of lubricant. The high-strength directly-buried optical cable has excellent high strength, aging resistance and wear resistance, the service life of the optical cable is remarkably prolonged, and the transmission reliability of the optical cable is remarkably improved.

The invention provides a doped electrode material based on porous silicon carbon and a preparation method thereof.The preparation method comprises the steps that a resin base material is smashed and then put into a high-temperature furnace to be subjected to a carbonization process, the carbonization temperature ranges from 300 DEG C to 1500 DEG C, an alkaline additive, a phosphorus source material and a nitrogen source material are sequentially added in the temperature interval, and phosphorus-nitrogen co-doped porous carbon is obtained; the preparation method comprises the following steps: mixing a silicon dioxide microsphere template into phosphorus-nitrogen co-doped porous carbon, adding a first coating carbon source to carry out first coating treatment, and etching the silicon dioxide microsphere template by using an etching solution to obtain a prefabricated object with a cavity structure; and putting the prefabricated object with the cavity structure into a fluidized bed reactor, introducing silicon source gas and a surface activation auxiliary agent, carrying out deposition at 400-550 DEG C, and then adding a second coating carbon source to carry out secondary coating treatment, thereby obtaining the doped electrode material based on porous silicon carbon. Therefore, the expansion coefficient of the electrode material is effectively reduced, and the rate capability is improved.

The invention relates to a catalyst for ethylene oxide ring-opening polymerization and a preparation method thereof, and belongs to the technical field of high polymer material synthesis, and the catalyst is a composite structure based on a silicon dioxide nanoparticle loaded bimetal organic complex; a modified nitrogen-containing polydentate ligand is prepared by adopting a special method, is coordinated with metal ions through covalent bonds and is loaded on silicon dioxide nanoparticles; by utilizing the high dispersity and stability of the silicon dioxide nanoparticles and the synergistic catalytic effect of the bimetal organic complex, the catalytic effect is effectively improved, the polymerization process is accelerated, the polymerization stability is enhanced, the polymerization molecular weight is improved, and the distribution is narrow.

The invention relates to a mildew-proof silicone sealant with high curing rate and high adhesive strength, and belongs to the technical field of adhesives. The anti-mildew coating is prepared from alpha, omega-dihydroxy polydimethylsiloxane, dimethyl silicone oil, fumed silica, phenoxy resin coated nano calcium carbonate, a modified hydroxypropyl-gamma-cyclodextrin loaded mildew preventive, dibutyltin dilaurate, methyltrimethoxysilane and a curing accelerator. According to the mildew-proof silicone sealant with the high curing rate and the high adhesive strength, the surface drying time is 9-13 minutes, the 24-hour curing depth is 6.3-7.2 mm, the adhesive strength is 3.0-3.6 MPa, the tensile strength is 5.8-6.4 MPa, the shear strength is 3.0-3.9 MPa, the elongation at break is 410-457%, and the mildew-proof grade is 0 grade in 30 days, 60 days, 180 days and 360 days.

The invention discloses a copper-clad plate for a printed circuit board and a preparation method of the copper-clad plate, and relates to the technical field of printed circuit board materials. The invention discloses a preparation method of a copper-clad plate for a printed circuit board, which comprises the following steps of: soaking a reinforcing material in a glue solution, and drying to obtain a prepreg; carrying out hot-pressing treatment on the prepreg and copper foil to obtain a copper-clad plate; the glue solution comprises the following raw materials in parts by weight: 15-20 parts of vinyl-terminated polyphenyl ether, 20-25 parts of epoxy resin, 20-25 parts of difunctional silicon dioxide, 15-25 parts of an organic solvent, 0.3-0.6 part of a curing agent and 0.05-0.1 part of a curing accelerator; the difunctional silicon dioxide cross-linked polyphenyl ether and epoxy resin prepared by the preparation method disclosed by the invention are used as a resin material of a glue solution, and have the characteristics of good heat resistance and excellent mechanical properties.

The invention relates to the technical field of environmental materials and water treatment, in particular to a graphene amino silica gel composite adsorbent for heavy metal wastewater treatment and a preparation method thereof.The graphene amino silica gel composite adsorbent is prepared from # imgabs0 nanoparticles, an amino-functionalized silicon dioxide coating layer, carboxylated reduced graphene oxide, a polydopamine modification layer and tetraethyl orthosilicate; the coating is prepared from the following raw materials: 3-aminopropyltriethoxysilane, 3-mercaptopropyltrimethoxysilane, N-((4-vinyl benzyl) amino) diacetic acid, chitosan, beta-cyclodextrin, hexadecyl trimethyl ammonium bromide, polyethylene glycol, L-ascorbic acid, 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide hydrochloride and N-hydroxysuccinimide. The composite adsorbent shows excellent adsorption performance on various heavy metal ions, and the adsorption performance is far higher than that of traditional adsorption materials and existing composite adsorbents.

A core-shell particle having an organic polymer core which is completely covered by a first inorganic oxide shell, wherein the first inorganic oxide shell has a silica (SiO2), an alumina (Al2O3), or a titania (TiO2); wherein the first inorganic oxide shell has a layer of a magnetic material which is disposed directly on the polymer core; further having a mesoporous second inorganic oxide shell, wherein the mesoporous second inorganic oxide shell covers the first inorganic oxide shell; wherein the mesoporous second inorganic oxide shell has silica (SiO2), alumina (Al2O3), or a titania (TiO2).

The invention provides a silicon-carbon composite material as well as a preparation method and application thereof. The silicon-carbon composite material comprises a porous carbon material; the silicon particles are distributed on the surface layer of the porous carbon material and in pore channels in the porous carbon material, the distribution concentration of the silicon particles in the surface layer of the porous carbon material is smaller than that of the silicon particles in the porous carbon material, and the particle size of the silicon particles in the surface layer of the porous carbon material is smaller than that of the silicon particles in the porous carbon material; the silicon dioxide layer is formed on the surface of the silicon particles; and the carbon coating layer is formed on the surface of the silicon dioxide layer. The lithium ion battery prepared by taking the silicon-carbon composite material as a positive electrode active material shows good electrochemical performance, and has relatively high specific capacity, good cycling stability and rate capability.

The invention discloses a preparation method of a permanent red pigment for an acid and alkali resistant coating, and belongs to the technical field of pigment preparation, a 2B acid derivative is diazotized and then coupled with 2-hydroxy-3-naphthoic acid, then a calcium chloride aqueous solution is added for color lake to obtain pigment particles, and finally the surfaces of the pigment particles are coated with silicon dioxide to obtain the permanent red pigment for the acid and alkali resistant coating. According to the permanent red pigment for the acid and alkali resistant coating prepared by the preparation method disclosed by the invention, the acid and alkali resistance and environmental stability of the pigment are further enhanced while the excellent characteristics of original pigment red 48: 2 are maintained, and the application performance of the pigment is remarkably improved.

The invention relates to the technical field of high-performance polyester, in particular to a high-strength low-shrinkage polyester fiber and a preparation method thereof. The defects that existing polyester fibers are poor in strength and shrinkage resistance are overcome. The preparation method comprises the following steps: mixing the modified resin, the modified nano silicon dioxide, the composite antioxidant, the composite nucleating agent and the composite lubricant, and carrying out melt spinning. Wherein the modified resin is prepared from the following raw materials: dimethyl terephthalate, isophthalic acid, ethylene glycol and isosorbide; the modified nano silicon dioxide comprises nano silicon dioxide, KH570 and silver nitrate; the composite antioxidant comprises an antioxidant 1010, an antioxidant 168 and an antioxidant 1222; the composite nucleating agent comprises sodium benzoate and nano montmorillonite; the composite lubricant is prepared from ethylene bis stearamide and pentaerythritol stearate. The prepared polyester fiber is high in strength, high in shrinkage resistance and suitable for manufacturing of outdoor equipment.

The invention provides a SiO2 / TiO2 / PMMA radiation refrigeration film and a preparation method thereof, and relates to the technical field of passive daytime radiation refrigeration films. The radiation refrigeration film is prepared from the following raw materials: N, N-dimethylformamide, polymethyl methacrylate, silicon dioxide and titanium dioxide. The invention relates to a preparation method of a SiO2 / TiO2 / PMMA radiation refrigeration film. The preparation method comprises the steps of preparing silicon dioxide, preparing titanium dioxide, synthesizing composite sol and preparing the SiO2 / TiO2 / PMMA radiation refrigeration film. The SiO2 / TiO2 / PMMA radiation refrigeration film prepared by the invention has high reflectivity in the ultraviolet-visible-near infrared band and high emissivity in the infrared band, can realize 8.4 DEG C sub-environment refrigeration, and is low in cost and simple in process flow.

The invention relates to a preparation method of a coaxial cellulose-based aerogel fiber fabric for daytime radiation refrigeration, which is characterized in that coaxial fibers take pure cellulose as a core, a skin layer comprises hollow silicon dioxide and low-concentration cellulose, and the hollow silicon dioxide is uniformly dispersed in the cellulose; the preparation method comprises the following specific steps: S1, preparing hollow silicon dioxide with an adjustable particle size; s2, preparing a hollow silicon dioxide / cellulose mixed spinning solution; s3, dissolving cellulose; s4, carrying out coaxial wet spinning; s5, carrying out multi-step solvent replacement; s6, performing continuous normal-pressure drying; s7, weaving fibers; the woven aerogel fiber fabric can effectively scatter sunlight, and the solar reflectivity (gt; 92%), and the emissivity (gt; 96%); the preparation method is green and environment-friendly, the operation is simple, the continuous and large-scale production of the cellulose-based aerogel fiber can be realized, and the prepared coaxial aerogel fiber fabric can show excellent radiation refrigeration performance in the daytime.

The embodiment of the invention provides a glass-based structural member as well as a preparation method and application thereof, and the preparation method comprises the following steps: carrying out at least one pre-plating cleaning selected from alkali cleaning, acid pickling and plasma treatment on a glass substrate, so that the surface water drop angle of the glass substrate is in a range of 10-30 degrees; forming a dielectric layer comprising a silicon dioxide layer on the surface of one side of the glass substrate cleaned before plating; forming an anti-fingerprint layer on the silicon dioxide layer; si-CH2 bonds are formed between the silicon dioxide layer and the anti-fingerprint layer. After the glass base material is cleaned before plating, the binding force between the SiO2 layer formed on the glass base material and the glass base material and the binding force between the anti-fingerprint layer and the SiO2 layer are both high, so that the thickness of the SiO2 layer and the anti-fingerprint layer can be large, the structure of the whole coating is stable, and the glass-based structural part can have good abrasion resistance, good scratch resistance and a lasting anti-fingerprint effect; and the application requirements in the fields of electronic equipment and the like can be well met.

The invention discloses low-migration UV ink-jet ink and a preparation method thereof, and belongs to the technical field of novel ink. Comprising the following components in parts by mass: 10-15 parts of a dynamic cross-linked polyurethane acrylate oligomer, 5-8 parts of an epoxy silicone resin oligomer, 2-3 parts of modified silicon dioxide, 4-5 parts of a photoinitiator, 15-20 parts of sorbic acid modified color paste, 1-2 parts of nano cerium oxide and 0.5-1 part of an antioxidant. The molecular chain of the dynamic cross-linked polyurethane acrylate oligomer prepared by the invention contains an active group capable of forming a cross-linked structure and a dynamic covalent bond. The groups and bonds promote molecular chain crosslinking when the ink is cured, a three-dimensional network is formed, and the molecular crosslinking density is improved. Through interaction of palmitic acid modified silicon dioxide and oligomer, the palmitic acid modified silicon dioxide is uniformly dispersed in a matrix and interferes molecular chain movement during curing, so that the crosslinking density is further improved, an ink film layer is more compact and firmer, the wear resistance and the scratch resistance are improved, and the tinting strength and the stability are indirectly enhanced.

The invention relates to the technical field of power cables, and provides a medium-voltage fireproof cable, which comprises a conductor, and an insulating layer, an armor layer and a sheath layer which are sequentially arranged outside the conductor, the insulating layer comprises the following components in parts by weight: 70-80 parts of polyethylene, 5-10 parts of a flame retardant, 3-5 parts of a cross-linking agent, 1-2 parts of a plasticizer and 1-3 parts of an antioxidant; the sheath layer comprises the following components in parts by weight: 100 parts of polyvinyl chloride, 8-16 parts of a flame retardant, 1-2 parts of a plasticizer, 1-3 parts of an antioxidant and 5-10 parts of filler; the filler comprises silicon dioxide, inorganic fibers and tetrapod-like zinc oxide whiskers. According to the technical scheme, the problem that the strength and the aging resistance of the cable in the prior art are poor is solved.

The invention provides an aerogel-based heat-preservation, heat-insulation and waterproof composite coating material for a building outer wall and a preparation method thereof, and belongs to the field of building materials. Through hydrophobic modified silicon dioxide aerogel, a lightweight heat insulation frame is provided, and the waterproofness and compatibility are improved; the mechanical property and the crack resistance are enhanced through the modified potassium titanate nanofibers, and self-adaptive heat insulation is achieved; the thermoelectric effect, the wear resistance and the thermal regulation performance are optimized through plasma treatment and polyaniline coated tungsten carbide nanoparticles; the heat management performance, the crack resistance and the comprehensive heat insulation and waterproof capacity are improved through graphene oxide composite modified boron nitride; the flexibility, the hydrophobicity and the interfacial compatibility are improved through organic silicon modified bisphenol A epoxy resin; and the performance of the coating is optimized through the synergistic effect of the components.

The invention discloses a high-content steel slag-based functionalized nano-composite cementing material and a preparation method thereof, and belongs to the technical field of solid waste resource comprehensive utilization. The nano composite cementing material is prepared from the following raw materials in parts by mass: 50 to 65 parts of steel slag, 10 to 20 parts of fly ash, 10 to 25 parts of carbide slag, 8 to 15 parts of desulfurized gypsum, 0.3 to 1.0 part of nano silicon dioxide and 0.003 to 0.03 part of silane coupling agent. On the basis of a solid waste synergism theory and an internal alkali excitation effect, quaternary solid wastes such as steel slag and fly ash are optimized and compounded by adopting methods of mechanical-thermal activation, addition of modified nano silicon dioxide, synergistic gelling between solid wastes and the like; the paint is prepared through gradient grinding and a medium-temperature wet curing process. The preparation method is simple, high-temperature calcination is not needed, cement clinker and exogenous excitant do not need to be added, the obtained cementing material can replace part of cement to be applied to the fields of road bases, mine filling, low-carbon building material products and the like, resource utilization and high-value utilization of regional bulk industrial solid waste can be achieved, and carbon emission and production cost are effectively reduced.

The present application belongs to the field of polymer material technology, and in particular, relates to a polyimide composite material, a preparation method thereof, and an application thereof. The preparation method of the polyimide composite material comprises the steps of: preparing a polyamic acid slurry from a diamine monomer, a dianhydride monomer, and an organic solvent; preparing a mixed slurry from the polyamic acid slurry and a nanomaterial, and then performing a spinning imidization treatment to obtain a polyimide composite material; wherein the nanomaterial comprises at least one of nano silicon carbide, aluminum nitride, carbon nanotubes, graphene, and nano silicon dioxide. By blending polyimide with other nanomaterials having high thermal conductivity to improve its thermal conductivity, the thermal conductivity of the polyimide composite material is optimized and improved, and its heat dissipation capacity in a high temperature working environment is enhanced, while having high tensile strength and thermal conductivity. The service life of the polyimide composite material is extended, and its application range can be further expanded, such as in the back panel assembly of a smartphone.

The invention discloses a preparation method of an intelligent response type soil conditioner based on a nano composite material, and belongs to the technical field of soil improvement. The modifier is prepared from 10 to 15 parts of modified chitosan, 15 to 25 parts of nano silicon dioxide, 20 to 30 parts of biochar-loaded polyglutamic acid, 8 to 15 parts of humic acid-sodium alginate microcapsules, 3 to 5 parts of trace element slow-release particles, 1 to 2 parts of a pH response type cross-linking agent and 15 to 25 parts of a functional agent. The soil conditioner researched and developed by the invention can flexibly adapt to complex and changeable soil environments, can sensitively sense dynamic changes of key environmental indexes such as soil humidity, pH value and temperature, automatically and accurately regulates and controls the release rate and the action effect of the soil conditioner, realizes multiple functions such as water retention, acid regulation, fertility increase and pollution resistance in a one-stop manner, and has a wide application prospect. High efficiency, long-term effect and ecological environment friendliness of soil improvement are comprehensively achieved, a new road is opened up for global soil improvement, and agricultural yield increase, ecological restoration and urban green development are assisted.

The invention relates to the technical field of wastewater resourceful treatment, in particular to a functional membrane for recycling precious metals in wastewater and a preparation method of the functional membrane. The specific preparation method comprises the following steps: preparing a polyamide spinning solution, carrying out electrostatic spinning on the spinning solution to form a polyamide fiber net, stably combining hollow mesoporous nano silicon dioxide on the fiber net through carboxymethyl chitosan, and grafting an epoxy silane coupling agent on the surface of the hollow mesoporous nano silicon dioxide to obtain the hollow mesoporous nano silicon dioxide fiber net. Finally, adipic dihydrazide is grafted on the hollow mesoporous nano silicon dioxide through a ring-opening reaction. Organic polyamide is used as a film forming substance, the raw material cost is low, the method is suitable for large-scale industrial production, the recovery rate of precious metal ions is high, and the film body has good mechanical strength and can stably operate for a long time.

The utility model relates to the technical field of power semiconductor devices, and discloses a super-junction VDMOS device resistant to static breakdown, which comprises a drain electrode and a grid electrode, an N + substrate is deposited on the upper surface of the drain electrode, a buffer layer is arranged above the N + substrate, a first N-epitaxial layer grows on the upper surface of the buffer layer, and a second N-epitaxial layer grows on the lower surface of the buffer layer. A first N-epitaxial layer is grown on the substrate, a P-region is formed in the first N-epitaxial layer through ion implantation diffusion, a second N-epitaxial layer grows on the first N-epitaxial layer, highly-doped P columns are arranged on the two sides in the second N-epitaxial layer, a heavily-doped region hole potential barrier region is arranged on one side of each P column, and a lightly-doped region hole potential well region is arranged on the lower side of one side of each P column. According to the VDMOS device, the thickness of the gate dielectric layer is increased, the total thickness of the gate dielectric layer is 100 nm, the single-particle shrinkage-through effect of the VDMOS device can be effectively improved, the gate dielectric layer is composed of 20 nm silicon dioxide and 80 nm trisilicon nitride, the single-particle shrinkage-through resistance characteristic of the device is further improved, and under the same gate voltage, gate-source electric leakage is reduced.