5277 results about "SILICONE DIOXIDE" patented technology

The invention relates to the field of pressure sensors, in particular to a pressure sensor and a processing method, and a chip comprises a silicon substrate, a silicon dioxide dielectric layer, a device layer, a metal electrode and packaging glass. The device layer comprises a silicon carbide single crystal device layer and a silicon device layer; the silicon carbide single crystal device layer is arranged on the silicon device layer; the silicon device layer, the silicon dioxide dielectric layer and the silicon substrate are connected in sequence; the device layer is etched to form a sensitive resistor device layer, an annular sealing region and a micro-channel; the sensitive resistance device layer is isolated from the annular sealing area through the micro-channel; the device layer, the silicon dioxide dielectric layer and the silicon substrate are etched to form a cross beam etching area; the silicon substrate is etched to form a silicon pressure cavity and a beam film; the metal electrode is arranged on the top of the device layer; and the packaging glass anode is bonded at the top of the device layer or the bottom of the silicon substrate so as to solve the problems of low high temperature resistance and low sensitivity of the MEMS pressure sensor.

The invention relates to the technical field of folding screen supporting films, and particularly discloses a double-layer buffering supporting film for a flexible folding display screen and a preparation method of the double-layer buffering supporting film. The double-layer buffer supporting film for the flexible folding display screen sequentially comprises a release film layer, a first adhesive layer, a first stainless steel layer, a second adhesive layer, a second stainless steel layer and a protective film layer from top to bottom, the first adhesive layer and the second adhesive layer are prepared by curing the same pressure-sensitive adhesive composition; the pressure-sensitive adhesive composition is prepared from the following raw materials: acrylate copolymer, hydrogenated rosin glyceride, hyperbranched polyesteramide-dopamine conjugate, acylhydrazone bond modified siloxane, a curing agent and a silane coupling agent; the protective film layer comprises the following raw materials: PET particles, nano silicon dioxide, an ethylene-vinyl acetate copolymer and an antioxidant. The double-layer buffer supporting film has the advantages of being high in supporting rigidity and interlayer peel strength, and serious folds caused by long-term repeated folding of the folding screen can be relieved.

The invention provides a preparation method of a porous carbon-silicon composite negative electrode material of a lithium battery. The preparation method comprises the following steps: constructing a multi-stage template system; carrying out carbon precursor impregnation and gradient temperature carbonization on the multistage template system; removing the template to form a gradient porous carbon carrier; carrying out gradient temperature zone silane deposition; and plasma-assisted carbon coating and nitrogen doping are carried out. According to the method, a silicon dioxide sphere hard template is combined with cetyltrimethylammonium bromide and a block copolymer soft template to form a porous carbon carrier with a micropore-mesopore-macropore three-stage structure, and gradient distribution of silicon in porous carbon is realized by utilizing a three-temperature-zone fluidized bed reactor and a pulse type deposition technology, so that the silicon-based porous carbon composite material is obtained. The problem of volume expansion of the silicon material is effectively relieved and the material cycling stability is improved. The porous carbon-silicon composite negative electrode material prepared by the invention has high specific surface area, excellent ion transmission channel and good structural stability, and can be applied to a high-energy-density lithium ion battery.

The invention provides a hot in-place recycling asphalt mixture and a construction method, and relates to the technical field of asphalt mixtures, and the hot in-place recycling asphalt mixture is obtained by recycling old asphalt pavement materials in a high proportion, reducing new material consumption and carbon emission, realizing resource recycling and green construction and introducing a regenerant to recover the performance of aged asphalt. The high-temperature rut resistance, the low-temperature crack resistance, the fatigue resistance and the interface bonding strength of the mixture are synergistically improved by matching with the styrene butadiene rubber modifier, the basalt fiber, the nano silicon dioxide and other functional materials, and the mixture is ensured to be uniform and free of segregation through precise feeding sequence, high-pressure atomization spraying and forced stirring parameter control. The defects of gray materials, oil balls and the like are avoided, the compactness, the flatness and the overall structure stability of the regenerated pavement are improved, and the problems of performance degradation and insufficient durability of a traditional regenerated mixture are solved.

The invention relates to a multi-layer composite black film and a preparation method thereof. The multi-layer composite black film is formed by sequentially stacking a base material layer, a multi-layer film system and a top covering layer, the multi-layer film system is formed by alternately stacking a plurality of absorption layers and a plurality of oxide layers, the number of the layers is 7-30, an initial layer is an oxide layer, the refractive indexes of the oxide layers are the same (1.4-1.5), the thickness ratio of the oxide layers to the absorption layers is larger than 2, and the thickness ratio of the top covering layer to the absorption layers is larger than 1. And the thicknesses of the two layers are increased and then reduced from the substrate layer to the top covering layer. A buffer layer with gradually changed oxygen content is arranged between the oxide layer and the absorption layer, and both the oxide layer and the top covering layer are made of silicon dioxide. The preparation method comprises the following steps: providing the substrate layer, alternately depositing the absorption layer and the oxide layer by using a magnetron sputtering or electron beam evaporation process to form a multilayer film system, then forming the top covering layer, controlling parameters such as vacuum degree, power, temperature and the like during deposition, and forming the buffer layer in the same cavity. The multilayer composite black film has the inner surface reflectivity of less than 1% and the appearance surface reflectivity of less than 5%, and is simple in structure and low in preparation cost.

The invention discloses a lithium battery diaphragm coating based on a nano material and application thereof, and relates to the technical field of lithium battery diaphragms. The coating comprises the following raw materials in parts by weight: 15-25 parts of polystyrene maleic anhydride copolymer modified polyvinylidene fluoride, 10-20 parts of polystyrene, 2-4 parts of nano silicon nitride, 3-6 parts of a boehmite / aluminum oxide and silicon dioxide composite material, 1-2 parts of a dispersing agent and 65-90 parts of a solvent, according to the lithium battery diaphragm coating provided by the invention, the wettability and absorptivity of a diaphragm to an electrolyte are remarkably improved, meanwhile, the lithium battery diaphragm coating also has excellent thermal stability, and the diaphragm can be effectively prevented from thermal shrinkage or melting under a high-temperature condition, so that the safety performance of a battery is remarkably enhanced.

The invention discloses a high-strength directly-buried optical cable and a preparation method thereof. Comprising at least one reinforcing piece, at least one cable core, a water-blocking tape layer, an inner protective layer, an armor layer and a high-strength outer sheath, wherein the cable core surrounds the reinforcing piece, is twisted and is filled with water-blocking cable paste; the water-blocking tape layer wraps the cable core; the inner protective layer wraps the water-blocking tape layer; wherein the cable core is composed of a loose tube filled with water-blocking fiber paste and at least one light-guide fiber accommodated in the loose tube; wherein the high-strength outer sheath is prepared from the following raw materials in parts by weight: 80 to 85 parts of high-density polyethylene, 15 to 20 parts of nylon 612, 8 to 12 parts of compatilizer, 15 to 20 parts of modified silicon dioxide, 1 to 3 parts of antioxidant and 0.7 to 1.1 parts of lubricant. The high-strength directly-buried optical cable has excellent high strength, aging resistance and wear resistance, the service life of the optical cable is remarkably prolonged, and the transmission reliability of the optical cable is remarkably improved.

The invention provides a doped electrode material based on porous silicon carbon and a preparation method thereof.The preparation method comprises the steps that a resin base material is smashed and then put into a high-temperature furnace to be subjected to a carbonization process, the carbonization temperature ranges from 300 DEG C to 1500 DEG C, an alkaline additive, a phosphorus source material and a nitrogen source material are sequentially added in the temperature interval, and phosphorus-nitrogen co-doped porous carbon is obtained; the preparation method comprises the following steps: mixing a silicon dioxide microsphere template into phosphorus-nitrogen co-doped porous carbon, adding a first coating carbon source to carry out first coating treatment, and etching the silicon dioxide microsphere template by using an etching solution to obtain a prefabricated object with a cavity structure; and putting the prefabricated object with the cavity structure into a fluidized bed reactor, introducing silicon source gas and a surface activation auxiliary agent, carrying out deposition at 400-550 DEG C, and then adding a second coating carbon source to carry out secondary coating treatment, thereby obtaining the doped electrode material based on porous silicon carbon. Therefore, the expansion coefficient of the electrode material is effectively reduced, and the rate capability is improved.

A core-shell particle having an organic polymer core which is completely covered by a first inorganic oxide shell, wherein the first inorganic oxide shell has a silica (SiO2), an alumina (Al2O3), or a titania (TiO2); wherein the first inorganic oxide shell has a layer of a magnetic material which is disposed directly on the polymer core; further having a mesoporous second inorganic oxide shell, wherein the mesoporous second inorganic oxide shell covers the first inorganic oxide shell; wherein the mesoporous second inorganic oxide shell has silica (SiO2), alumina (Al2O3), or a titania (TiO2).

The invention relates to the technical field of high-performance polyester, in particular to a high-strength low-shrinkage polyester fiber and a preparation method thereof. The defects that existing polyester fibers are poor in strength and shrinkage resistance are overcome. The preparation method comprises the following steps: mixing the modified resin, the modified nano silicon dioxide, the composite antioxidant, the composite nucleating agent and the composite lubricant, and carrying out melt spinning. Wherein the modified resin is prepared from the following raw materials: dimethyl terephthalate, isophthalic acid, ethylene glycol and isosorbide; the modified nano silicon dioxide comprises nano silicon dioxide, KH570 and silver nitrate; the composite antioxidant comprises an antioxidant 1010, an antioxidant 168 and an antioxidant 1222; the composite nucleating agent comprises sodium benzoate and nano montmorillonite; the composite lubricant is prepared from ethylene bis stearamide and pentaerythritol stearate. The prepared polyester fiber is high in strength, high in shrinkage resistance and suitable for manufacturing of outdoor equipment.

The invention provides a SiO2 / TiO2 / PMMA radiation refrigeration film and a preparation method thereof, and relates to the technical field of passive daytime radiation refrigeration films. The radiation refrigeration film is prepared from the following raw materials: N, N-dimethylformamide, polymethyl methacrylate, silicon dioxide and titanium dioxide. The invention relates to a preparation method of a SiO2 / TiO2 / PMMA radiation refrigeration film. The preparation method comprises the steps of preparing silicon dioxide, preparing titanium dioxide, synthesizing composite sol and preparing the SiO2 / TiO2 / PMMA radiation refrigeration film. The SiO2 / TiO2 / PMMA radiation refrigeration film prepared by the invention has high reflectivity in the ultraviolet-visible-near infrared band and high emissivity in the infrared band, can realize 8.4 DEG C sub-environment refrigeration, and is low in cost and simple in process flow.

The embodiment of the invention provides a glass-based structural member as well as a preparation method and application thereof, and the preparation method comprises the following steps: carrying out at least one pre-plating cleaning selected from alkali cleaning, acid pickling and plasma treatment on a glass substrate, so that the surface water drop angle of the glass substrate is in a range of 10-30 degrees; forming a dielectric layer comprising a silicon dioxide layer on the surface of one side of the glass substrate cleaned before plating; forming an anti-fingerprint layer on the silicon dioxide layer; si-CH2 bonds are formed between the silicon dioxide layer and the anti-fingerprint layer. After the glass base material is cleaned before plating, the binding force between the SiO2 layer formed on the glass base material and the glass base material and the binding force between the anti-fingerprint layer and the SiO2 layer are both high, so that the thickness of the SiO2 layer and the anti-fingerprint layer can be large, the structure of the whole coating is stable, and the glass-based structural part can have good abrasion resistance, good scratch resistance and a lasting anti-fingerprint effect; and the application requirements in the fields of electronic equipment and the like can be well met.

The invention discloses low-migration UV ink-jet ink and a preparation method thereof, and belongs to the technical field of novel ink. Comprising the following components in parts by mass: 10-15 parts of a dynamic cross-linked polyurethane acrylate oligomer, 5-8 parts of an epoxy silicone resin oligomer, 2-3 parts of modified silicon dioxide, 4-5 parts of a photoinitiator, 15-20 parts of sorbic acid modified color paste, 1-2 parts of nano cerium oxide and 0.5-1 part of an antioxidant. The molecular chain of the dynamic cross-linked polyurethane acrylate oligomer prepared by the invention contains an active group capable of forming a cross-linked structure and a dynamic covalent bond. The groups and bonds promote molecular chain crosslinking when the ink is cured, a three-dimensional network is formed, and the molecular crosslinking density is improved. Through interaction of palmitic acid modified silicon dioxide and oligomer, the palmitic acid modified silicon dioxide is uniformly dispersed in a matrix and interferes molecular chain movement during curing, so that the crosslinking density is further improved, an ink film layer is more compact and firmer, the wear resistance and the scratch resistance are improved, and the tinting strength and the stability are indirectly enhanced.

The invention discloses a high-content steel slag-based functionalized nano-composite cementing material and a preparation method thereof, and belongs to the technical field of solid waste resource comprehensive utilization. The nano composite cementing material is prepared from the following raw materials in parts by mass: 50 to 65 parts of steel slag, 10 to 20 parts of fly ash, 10 to 25 parts of carbide slag, 8 to 15 parts of desulfurized gypsum, 0.3 to 1.0 part of nano silicon dioxide and 0.003 to 0.03 part of silane coupling agent. On the basis of a solid waste synergism theory and an internal alkali excitation effect, quaternary solid wastes such as steel slag and fly ash are optimized and compounded by adopting methods of mechanical-thermal activation, addition of modified nano silicon dioxide, synergistic gelling between solid wastes and the like; the paint is prepared through gradient grinding and a medium-temperature wet curing process. The preparation method is simple, high-temperature calcination is not needed, cement clinker and exogenous excitant do not need to be added, the obtained cementing material can replace part of cement to be applied to the fields of road bases, mine filling, low-carbon building material products and the like, resource utilization and high-value utilization of regional bulk industrial solid waste can be achieved, and carbon emission and production cost are effectively reduced.

The invention discloses a preparation method of an intelligent response type soil conditioner based on a nano composite material, and belongs to the technical field of soil improvement. The modifier is prepared from 10 to 15 parts of modified chitosan, 15 to 25 parts of nano silicon dioxide, 20 to 30 parts of biochar-loaded polyglutamic acid, 8 to 15 parts of humic acid-sodium alginate microcapsules, 3 to 5 parts of trace element slow-release particles, 1 to 2 parts of a pH response type cross-linking agent and 15 to 25 parts of a functional agent. The soil conditioner researched and developed by the invention can flexibly adapt to complex and changeable soil environments, can sensitively sense dynamic changes of key environmental indexes such as soil humidity, pH value and temperature, automatically and accurately regulates and controls the release rate and the action effect of the soil conditioner, realizes multiple functions such as water retention, acid regulation, fertility increase and pollution resistance in a one-stop manner, and has a wide application prospect. High efficiency, long-term effect and ecological environment friendliness of soil improvement are comprehensively achieved, a new road is opened up for global soil improvement, and agricultural yield increase, ecological restoration and urban green development are assisted.

The utility model relates to the technical field of power semiconductor devices, and discloses a super-junction VDMOS device resistant to static breakdown, which comprises a drain electrode and a grid electrode, an N + substrate is deposited on the upper surface of the drain electrode, a buffer layer is arranged above the N + substrate, a first N-epitaxial layer grows on the upper surface of the buffer layer, and a second N-epitaxial layer grows on the lower surface of the buffer layer. A first N-epitaxial layer is grown on the substrate, a P-region is formed in the first N-epitaxial layer through ion implantation diffusion, a second N-epitaxial layer grows on the first N-epitaxial layer, highly-doped P columns are arranged on the two sides in the second N-epitaxial layer, a heavily-doped region hole potential barrier region is arranged on one side of each P column, and a lightly-doped region hole potential well region is arranged on the lower side of one side of each P column. According to the VDMOS device, the thickness of the gate dielectric layer is increased, the total thickness of the gate dielectric layer is 100 nm, the single-particle shrinkage-through effect of the VDMOS device can be effectively improved, the gate dielectric layer is composed of 20 nm silicon dioxide and 80 nm trisilicon nitride, the single-particle shrinkage-through resistance characteristic of the device is further improved, and under the same gate voltage, gate-source electric leakage is reduced.

The invention discloses an MXene-based coating with a near-infrared light induction interaction effect and a preparation method of the MXene-based coating, and relates to the technical field of coatings. The preparation method comprises the following steps: a nano microcapsule and MXene powder are subjected to in-situ growth to form a composite dispersion liquid, the nano microcapsule is of a core-shell structure, a shell layer material is selected from at least one of polyaniline, polyurea, polyurethane, polyacrylate and silicon dioxide, a core contains a functional substance, and the surface of the core contains a porous material. The functional substances are selected from at least two of a corrosion inhibitor, a fluorescent indicator and a lubricant; adding a thermal reversible coating containing dynamic covalent bonds and a curing agent into the composite dispersion liquid, and uniformly mixing to form a homogeneous coating; and spraying the homogeneous coating on the surface of a base material, and curing to obtain the coating. The coating is high in mechanical strength, has a near-infrared light triggered self-repairing function, is high in self-repairing rate, and can realize multiple functions such as fluorescence labeling, corrosion early warning and lubrication coordinated regulation and control.

The invention relates to a concrete anti-cracking self-repairing agent in the technical field of building materials, and aims to solve the problem that concrete cracks are difficult to self-repair. According to the technical scheme, the self-repairing agent is characterized by comprising a microbial repairing unit formed by ZSM-5 type zeolite molecular sieve loaded bacillus pasteurii spores, mesoporous silica particles loaded with L-calcium aspartate and Fe3O4 (at) SiO2 core-shell nanoparticles which are fixed through an in-situ polymerization coating layer to form a magnetic thermal response capsule layer coating the surface of the microbial repairing unit, pLGA microspheres containing yeast extract are positioned on an interface of zeolite and hydrogel, and a trehalose-anhydrous calcium chloride eutectic compound is used as a directional mineralization accelerant. The concrete anti-cracking self-repairing agent provided by the invention is mainly used for intelligent identification and self-repairing of concrete cracks, and efficient repairing is realized through a microbial mineralization, calcium ion slow release and magnetic thermal response synergistic mechanism.

The invention discloses a polyether siloxane defoaming agent for water-based paint and a preparation method of the polyether siloxane defoaming agent, and relates to the technical field of defoaming agents. The polyether siloxane defoaming agent for the water-based paint comprises the following raw materials in parts by weight: 60-75 parts of polyether modified silicone oil, 5-8 parts of silicon paste, 3-5 parts of a dispersing agent, 2-4 parts of silicon dioxide, 5-10 parts of an emulsifying agent and 2-5 parts of a surfactant. The polyether siloxane defoaming agent for the water-based paint, prepared by the invention, has good defoaming and foam-inhibiting properties and stability.

The invention relates to the field of materials, in particular to a silicon dioxide aerogel composite thermal insulation material and a preparation method thereof. The silicon dioxide aerogel composite thermal insulation material is prepared by taking silicon dioxide aerogel, phenolic resin, a nano zirconium oxide graft and a locust bean gum graft as main raw materials and taking n-pentane, UV-327, hexamethylenetetramine and an antioxidant 1010 as auxiliary materials. The nano zirconium oxide graft and the locust bean gum graft are added into the silicon dioxide aerogel material, so that the prepared silicon dioxide aerogel composite material has excellent heat-insulating property, flame-retardant property and toughening effect, and the comprehensive requirements of the use scene of the silicon dioxide aerogel composite material on toughness and flame retardance are met; and the application market is expanded.

The invention belongs to the technical field of drilling fluid, and particularly relates to a free radical polymerization water-based drilling fluid composition and a preparation method thereof. The invention relates to a core-shell composite particle-containing water reducer which comprises deionized water, salts (NaCl / KCl), alkalis (Na2CO3 and NaOH), barium sulfate and core-shell composite particles X. The particle is composed of a silicon dioxide core and a polymer shell layer, and the shell layer is formed by free radical copolymerization of acrylamide, 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid and is covalently connected with the core through silanization treatment. Under the conditions of high salinity, strong alkali and high solid phase weighting, the drilling fluid simultaneously realizes the following effects: (1) high-density bearing and low-viscosity pumpability are realized; (2) compact plugging and water loss reduction and low formation damage flowback can be realized; and (3) stable rheology rock carrying, lubrication and friction resistance reduction. The problem that three aspects of performance are difficult to consider in the prior art is solved, and the drilling fluid is suitable for drilling of deep wells, ultra-deep wells and complex stratums and has remarkable industrial application value.

The invention relates to the technical field of cable materials, in particular to a thermoplastic low-smoke halogen-free flame-retardant polypropylene cable material and a preparation method thereof. The modified thermoplastic low-smoke halogen-free flame-retardant polypropylene cable material is prepared from the following components in parts by weight: 30 to 36 parts of polypropylene, 12 to 16 parts of toughening agent, 10 to 16 parts of POE (Polyolefin Elastomer) compatilizer, 88 to 102 parts of flame retardant, 0.5 to 0.9 part of antioxidant, 1 to 2 parts of lubricant and 3 to 6 parts of modified nano particles, the modified nano particles are prepared from nano silicon dioxide and methyl methacrylate through graft polymerization. By adding the modified nanoparticles, the performance of the cable material is remarkably improved, so that the cable material achieves better balance and effect in the aspects of mechanical property, flame retardant property, electrical property, aging property, low-temperature property and the like.

The invention discloses a composite modified material for a lithium niobate wafer, and relates to the technical field of nano materials. The material is composed of an anti-corrosion passivation matrix and a function enhancement component, wherein the anti-corrosion matrix adopts a silicon nitride / SiO2 multi-layer composite layer, atomic layer deposition titanium dioxide and magnetron sputtering aluminum oxide to form cascade protection; the functional layer comprises lead sulfide nanoparticles and nano silicon dioxide, and is directionally modified by a silane coupling agent and a perfluoropolyether surfactant. During preparation, PbS nano-particles are synthesized by combining a PECVD-ALD-magnetron sputtering stepped deposition process (200-150 DEG C) with a solvothermal method, and finally, the PbS nano-particles are formed through spin coating-annealing (300-400 DEG C). The optical loss of the material under the wavelength of 1550 nm is smaller than 0.2 dB / cm, the acid and alkali corrosion resistance is larger than 240 h, the lead dissolution rate is smaller than 0.1 ppm, the interface state density is reduced by 2 orders of magnitude, the contradiction between lithium niobate wafer surface degradation, photoelectric property degradation and lead-containing material environment risk is solved, and the material is suitable for 5G optical waveguide and quantum integrated device packaging.

The invention discloses a preparation method of a passivation contact cell with double tunneling polycrystalline silicon layers. A first tunneling oxide layer, a first intrinsic amorphous silicon layer, a low-doping p-type amorphous silicon layer, a second tunneling oxide layer, a high-doping p-type amorphous silicon layer and a first silicon dioxide mask layer are sequentially deposited in a p region on the back surface of a silicon wafer; sequentially depositing a third tunneling oxide layer, a second intrinsic amorphous silicon layer, a low-doping n-type amorphous silicon layer, a fourth tunneling oxide layer, a high-doping n-type amorphous silicon layer and a second silicon dioxide mask layer in an n region on the back surface of the silicon wafer; and the p-type amorphous silicon and the n-type amorphous silicon are simultaneously converted into p-type polycrystalline silicon and n-type polycrystalline silicon through high-temperature annealing crystallization treatment, so that the preparation of the p-region and n-region dual-tunneling passivation contact structure of the TBC battery is realized. The doping level and passivation performance of the p-region p-type polycrystalline silicon and the n-region n-type polycrystalline silicon are improved, the conversion efficiency of the TBC battery is improved, the production steps are reduced, and the preparation cost is reduced.

The invention relates to a silicon-carbon composite material with a porous structure and a preparation method thereof, and the silicon-carbon composite material with the porous structure comprises an N / P co-doped porous carbon skeleton with micropore, mesopore and macropore channel networks, and amorphous or low-crystalline nanometer silicon particles which are uniformly loaded in the porous carbon skeleton and have the average particle size of 15-40nm, the mass percent of silicon in the composite material is 40-60%, and good interface bonding is formed between silicon and carbon. The preparation method mainly comprises the following steps: firstly, preparing an N / P co-doped porous carbon skeleton through a template method in combination with high-temperature carbonization and N / P source co-pyrolysis; and hydrolyzing an organic silicon source in the carbon skeleton to form silicon dioxide, and performing low-temperature metal thermal in-situ reduction to obtain the nano-silicon loaded composite material. Through a unique porous carbon skeleton design and a precise in-situ composite strategy of nano silicon, the prepared material shows high specific capacity, high initial coulombic efficiency and excellent cycling stability and rate capability when being used as a negative electrode of a lithium ion battery.

The invention discloses a self-cleaning photovoltaic super-hydrophobic coating based on a nano-porous structure and a preparation method of the self-cleaning photovoltaic super-hydrophobic coating, and belongs to the technical field of photovoltaic panel coatings. The coating comprises the following components in percentage by mass: 15-25% of nano porous silicon dioxide particles, 5-10% of a low surface energy modifier, 3-8% of photocatalytic nano titanium dioxide, 30-40% of organic silicon resin and the balance of deionized water. The coating has super-hydrophobicity, photocatalytic decomposition of organic matters and wear resistance, can solve the problems of photovoltaic panel dust accumulation, bird droppings, organic matter pollution and the like, and improves the power generation efficiency of a photovoltaic system.

The invention discloses a high-temperature-resistant, bending-resistant and high-flexibility polyimide film for flexible display and a preparation method of the high-temperature-resistant, bending-resistant and high-flexibility polyimide film. According to the polyimide film, by introducing the nano silicon dioxide particles and constructing the porous structure design, the problems that a traditional polyimide film is insufficient in stability in a high-temperature environment, cracks are likely to be generated after bending, and the flexibility is poor are effectively solved. The polyimide film disclosed by the invention is prepared by adopting a diamine monomer and a dianhydride monomer as main raw materials, adding nano silicon dioxide particles, and carrying out solution polymerization, gelation, pore regulation and control and thermal imidization processes. The obtained polyimide film has a micron-sized porous structure, keeps stable at a high temperature of 400 DEG C, does not generate cracks after being bent for 100,000 times, has tensile strength of more than or equal to 150MPa, elongation at break of more than or equal to 25% and light transmittance of more than or equal to 85%, and is suitable for a substrate material of a flexible display device.

The invention discloses a household nano self-cleaning material containing rare earth elements and a preparation method of the household nano self-cleaning material, and aims at solving the problems that a traditional self-cleaning material is narrow in light response range, single in function, poor in durability, non-environment-friendly in preparation process and the like. The material comprises 5-15 parts of rare earth oxide, 50-70 parts of nano titanium dioxide, 10-20 parts of mesoporous silica, 3-8 parts of a fluorinated modifier and 2-5 parts of a bio-based adhesive. Wherein the rare earth elements are doped in titanium dioxide crystal lattices, so that the forbidden band width is reduced, the photocatalytic response range is widened to visible light, and the photocatalytic efficiency is remarkably improved. The preparation method of the material comprises the steps of precursor preparation, hydrothermal reaction, fluorination modification and coating forming, a low-temperature hydrothermal method, supercritical CO2 modification and a photocuring technology are adopted, and the material has the functions of self-cleaning, antibiosis and VOCs degradation, is suitable for various base materials such as household building materials, textiles and electric appliance surfaces, meets the composite requirements of modern home for health and environmental protection, and has wide application prospects. And the preparation process is green and pollution-free, and conforms to the sustainable development concept.

The invention relates to the technical field of materials adaptive to extreme environments, and discloses cross-scale gradient co-doped multifunctional composite aerogel as well as a preparation method and application of the cross-scale gradient co-doped multifunctional composite aerogel. The multifunctional composite aerogel is co-doped with ultraviolet light-screening agent nano-particles, infrared light-screening agent nano-particles and functional nano-particles in a cross-scale gradient manner, and is used for performing selective filtration and full-spectrum regulation and control on sunlight penetrating through the transparent aerogel; the ultraviolet light-screening agent particles are titanium dioxide nano particles; the infrared opacifying agent particles are indium tin oxide nanoparticles; and the functional nanoparticles are silver nanorods. The composite aerogel provided by the invention improves the anti-ultraviolet performance and high-temperature heat insulation performance of the aerogel and provides a function of enhancing photosynthesis of plants, and meanwhile, the transmittance of the transparent aerogel in the visible light band of sunlight is not obviously reduced.

The invention relates to the technical field of photovoltaic module frames, in particular to a self-cleaning weather-proof aluminum alloy photovoltaic module frame and a preparation method thereof, and aims to improve the self-cleaning capacity of the photovoltaic module frame, a layer of self-cleaning coating is prepared on the basis of an aluminum alloy frame body. The boric acid ester chain extender containing the fluorine element and the fluorine-containing polyol are added, and the fluorine element has extremely strong electronegativity, so that the water resistance of the resin can be effectively improved, the surface energy of the material is reduced, the surface friction is reduced, the friction resistance is improved, the adsorption of dust on the surface of a metal frame can be reduced, and the material is kept clean for a long time; a reversible covalent bond boric acid ester bond is further introduced into the boric acid ester chain extender, so that the purpose of self-repairing is achieved, hydrophobic nano-silica is further added into the coating, the friction resistance and hydrophobic capacity of the aluminum alloy photovoltaic module frame are further improved, and the service life of the aluminum alloy photovoltaic module frame is prolonged. And the durability of the material exposed in an external atmospheric environment is improved.