Lithium-ion battery electrolyte and lithium-ion battery

A lithium-ion battery and electrolyte technology, applied in secondary batteries, secondary battery repair/maintenance, circuits, etc., can solve problems such as poor cycle performance, large changes in battery internal resistance, and easy gas production during high-temperature storage, and achieve Effects of improving charge and discharge efficiency, reducing internal resistance, and low interface impedance

Inactive Publication Date: 2018-03-23
DONGGUAN SHANSHAN BATTERY MATERIALS
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  • Abstract
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AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to: address the deficiencies of the prior art, and provide an electrolyte that can be adapted to the high-nickel material system, to solve the problems of poor cycle performance and poor battery life during storage and charging of high-nickel material system batteries. During the discharge process, the internal resistance changes greatly, and the problem of high temperature storage is easy to produce gas

Method used

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  • Lithium-ion battery electrolyte and lithium-ion battery
  • Lithium-ion battery electrolyte and lithium-ion battery

Examples

Experimental program
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Effect test

Embodiment 1

[0019] Electrolyte preparation:

[0020] In a glove box filled with argon (moisture 6 , and stirred until it was completely dissolved to obtain a lithium-ion battery electrolyte.

[0021] Preparation of lithium-ion batteries:

[0022] The positive electrode active material nickel cobalt aluminum manganate (NCA), lithium carbonate, conductive agent acetylene black, binder polyvinylidene fluoride (PVDF) in N-methylpyrrolidone solvent system in a mass ratio of 95:1:2:2 After being fully stirred and mixed evenly, it is coated on Al foil, dried, and cold-pressed to obtain a positive electrode sheet with a compacted density of 3.45g / cm 3 .

[0023] Negative electrode active material artificial graphite, conductive agent acetylene black, binder styrene-butadiene rubber (SBR), thickener sodium carboxymethyl cellulose (CMC) were mixed in a deionized water solvent system according to the mass ratio of 96:2:1:1 After being fully stirred and mixed evenly, it is coated on Cu foil, dried...

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Abstract

The invention belongs to the technical field of lithium-ion batteries, in particular to a lithium-ion battery electrolyte and a lithium-ion battery. Three additives, namely an additive A, an additiveB and an additive C, are added in the in the electrolyte, wherein the additive A can improve the cycle performance of a high-nickel material battery and inhibit the battery from increasing internal resistance in high-temperature storage and cyclic processes, the charging and discharging efficiency of the battery in charging and discharging processes can be improved, and self-discharging is reduced; the additive B can form a thin and compact SEI membrane on a negative electrode interface, so that a high-nickel material has relatively low interface impedance when matching with a high-volume high-compaction negative electrode material, and lithium-ions are favorably diffused; the additive C can inhibit a high-nickel battery from producing too much gas so that a battery explosion-proof valveis sprung in the long-term storage process at high temperature, and meanwhile has positive influence on the cycle life of the battery; therefore, the electrolyte guarantees that the battery has a relatively good cyclic life, the internal resistance of the battery in the use process is reduced, and when the battery is used at high temperature, potential safety hazards, which appear as the explosion-proof valve is sprung, are avoided.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a lithium ion battery electrolyte and a lithium ion battery. Background technique [0002] Lithium-ion batteries are widely used in 3C digital products, electric vehicles, military aerospace and other fields due to their high working voltage, high energy density, long cycle life, and environmental friendliness. With the improvement of people's living standards, higher requirements are placed on the energy density and working environment of lithium-ion batteries. As we all know, the electrification of fuel vehicles is an inevitable trend in future development. The current lithium-ion power batteries are restricted by energy density and cost, which makes the promotion of electric vehicles relatively slow. Therefore, the development of high energy density power batteries is the key to solving the above problems. Among them, high-nickel system, high-voltage...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0567H01M10/0525H01M10/42
CPCH01M10/0525H01M10/0567H01M10/4235Y02E60/10
Inventor 朱学全郭力
Owner DONGGUAN SHANSHAN BATTERY MATERIALS
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