The present application relates to a kind of trace Br doped Co3O4
Nanowire anode material, preparation method and electrochemical disinfection device, and preparation method includes: the pretreated
nickel foam is obtained by
pickling, cleaning,
drying foam
nickel;Soluble
cobalt salt,
urea,
ammonium fluoride and
sodium bromide are dissolved in water, mixed to obtain precursor solution, pretreated
nickel foam is immersed in and
hydrothermal reaction is carried out, and
cobalt oxide precursor containing
bromine is grown on the foam
nickel base;Then calcine in
oxygen-containing
atmosphere,
anode material is obtained.The material is doped in the lattice by replacing the
lattice oxygen of Co3O4 Br, and
ammonium fluoride is used as structure directing agent to induce
nanowire formation.The present application also provides an electrochemical disinfection device comprising the
anode material.The present application realizes the selective generation of
bromine radicals in high-
chlorine and low-
bromine water body by bromine
doping, and at the same time, the electric perforation effect is generated by
nanowire tip, so as to realize efficient disinfection and greatly reduce halogenated by-products, with the advantages of safety, speed, no secondary
pollution.