The invention relates to the field of fuel
cell anode catalysts, in particular to a preparation method of a Pd / h-BNNSs / rGO composite catalyst for a
direct ethanol fuel cell, which comprises the following steps: taking reduced
graphene oxide (rGO) as a substrate and compounding 5-20% by
mass of
hexagonal boron nitride nanosheets (h-BNNSs) to form a composite carrier;
palladium (Pd) nanoparticles accounting for 16 + / -0.5 wt% of the total
mass of the catalyst are loaded on the catalyst; the preparation method mainly comprises the following steps: preparing
graphene oxide (GO) by an improved Hummer method, carrying out
ultrasonic dispersion on GO and h-BNNSs, carrying out
hydrothermal reaction at 180 DEG C for 6 hours, carrying out
freeze drying to prepare a composite carrier, and loading Pd by a NaBH4 reduction method. The catalyst shows excellent performance on
ethanol electrooxidation in an alkaline medium, has an electrochemical active area up to 202.31 m < 2 > / g,
peak current density (5.9 times of commercial Pd / C) of 5549.0 mA / mg, excellent stability that activity attenuation is only 50% after 300 cycles, and remarkably improved
CO poisoning resistance (the Jf / Jb ratio reaches 1.35), and shows strong industrial application potential.