A hydrophilic chain extender of sulfonic acid type which pertains to chemical product, and preparation thereof. The invention mainly aims to solve the problems of slow reaction rate of hydrophilic chain extender used in aqueous polyurethanel industry, low content of aqueous resin, low heat resistance, low adhesion strength when applying to adhesive. The eligible product is obtained by fully dissolving multi-amine such as 0.5-1.5 parts of ethylenediamine into solvent, reacting with olefin sulfonate such as 5-9 parts of vinyl sodium sulfonate solution with about 25% of water for 4-30 hours at the temperature of 40-100 DEG C., vacuum distilling to remove solvent, dissolving with water, alcohol or ketone, vacuum distilling to remove all solvent for another time after deposition and filter. Stability treatment for storage is further carried out by adding water. The final product is slightly turbid vicous liquid in light yellow color and oil state, with density at 1.16-1.21 g/ml, pH at 11-12, content of ammonia at 6.9+-0.9g NH3/100g, effective content 40-55%. The invention can widely used into production of aqueous polyurethane of different fields, which has a fast reaction rate, high yield, highly enhanced content of solid in prepared aqueous resin, and obviously improved resistance of heat, acid, alkali, hard water, and is greatly beneficial for preparation of adhesive.