Provided are a hydroxyl-protected alcohol of the formula R—O-Pg, wherein Pg is a protecting group of the Formulae (I), (II), wherein Y is R1, OR1, or NR1R1a; Z is O, NR2 or CR2R2a; W is CO or SO; R1, R1a, R2, R2a, R3, R3a, R4 and R4a include H, a saturated or unsaturated alkyl, an aryl, and a saturated or unsaturated alkyl comprising an aryl; a, b, c, d, e and f include H, a halogen, a saturated or unsaturated alkyl, a hydroxyl, an alkoxy, an aryloxy, an aralkoxy, a cyano, a nitro, a sulfhydryl, an alkyl or aryl sulfoxy, are alkyl or aryl sulfonyl, a keto, a thioketo, an ester, an amide, an amino, an alkylamino or a dialkylamino; and R represents the organic residue of the hydroxyl-protected alcohol; a hydroxyl-protected alcohol which includes a thermally cleavable 2-amidoethoxycarbonyl hydroxyl-protecting group; and a deprotection method, which includes heating the hydroxyl-protected alcohol at a temperature effective to cleave thermally the hydroxyl-protecting group therefrom.