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137results about How to "Fast cross-linking" patented technology

Method for preparing crosslinkable polyethylene cable material

The invention discloses a preparation method of crosslinkable polyethylene cable material, which includes the steps and the following components are represented in proportion by weight: throwing polyethylene 75-95 proportion by weight, ethylene-vinyl acetate copolymer 0-20 proportion by weight, unsaturated silicone hydride 1.0-5 proportion by weight, free radical evocating agent 0.1-0.5 proportion by weight, organotin catalyst 0.1-1 proportion by weight, organic acid compound 0.1-1 proportion by weight, anti-oxidant 0.1-0.5 proportion by weight, anti-copper agent 0.1-0.5 proportion by weight, and lubricant 0.5-2 proportion by weight into the high speed mixing machine with rotary speed at 80-120 rpm for mixing 15-25 minutes, and then adding the mixture into the double-screw extruder, melting and prilling for obtaining crosslinkable polyethylene cable material. The method provided by the invention mixes all the material and dispersing uniformly, and then executes grafting reaction, thereby realizing more uniform grafting reaction and guaranteeing homogeneity of the crosslinking process, in addition, the invention uses organic acid compound which remarkably improves catalysis function of organotin catalyst, and improves crosslinking speed of silicone hydride, and overcomes the defect that the conventional silicone hydride crosslinked plastic can be linked only in warm water or steam environment with long time cooking, thereby saving production cost for manufacturer considerably. The crosslinkable polyethylene cable material obtained according to the invention is extruded by plastic cable extrusion machine unit for obtaining cable insulation layer, and is placed under the condition of 23 DEG C. with 50% humidity for one day naturally, then the crosslinking process is finished, moreover the product can pass performance indexes of hot extension performance test, dynamics test and aging characteristic test according to the national standard request.
Owner:SHANGHAI JIAO TONG UNIV

Bi-crosslinking mussel binding protein bionic hydrogel for tissue adhesive and preparation method of bi-crosslinking mussel binding protein bionic hydrogel

The invention relates to a bi-crosslinking mussel binding protein bionic hydrogel for a tissue adhesive and a preparation method of the bi-crosslinking mussel binding protein bionic hydrogel. The hydrogel is obtained by taking mercapto group modified chitosan containing dopa residues as a matrix and performing bi-crosslinking under the condition of four-arm polyethyleneglycol succinimidyl carbonate and sodium periodate. The preparation method comprises the following steps of preparation of dopa residue modified chitosan, preparation of dopa residue and mercapto group modified chitosan, preparation of four-arm polyethyleneglycol succinimidyl carbonate and preparation of the bi-crosslinking mussel binding protein bionic hydrogel. In the preparation method provided by the invention, by takingthe sodium periodate as a crosslinking agent which performs rapid crosslinking and the four-arm polyethyleneglycol succinimidyl carbonate as a crosslinking agent which is relatively slow in reaction,the hydrogel is prepared by bi-crosslinking, the crosslinking speed is rapid, and the prepared hydrogel has very good adhesion performance, biocompatibility and mechanical strength and is hydrogel which can be used for the tissue adhesive.
Owner:DONGHUA UNIV

Konjac glucomannan glycosyl antibacterial hydrogel fiber and preparation method thereof

The invention discloses a konjac glucomannan glycosyl antibacterial hydrogel fiber and a preparation method thereof. The fiber comprises the following raw material components in parts by weight: 50-100 parts of konjac glucomannan polymerizable monomers, 100-800 parts of alginate, 10-20 parts of organic guanidine salt polymerizable monomers, 10000-40000 parts of deionized water and 0.1-5 parts of an initiator. The preparation method comprises the following steps: (1) preparing modified konjac glucomannan with double bonds on side groups and the organic guanidine salt polymerizable monomer; (2)preparing a spinning liquid; and (3) preparing a hydrogel fiber by using a two-step crosslinking method. The preparation method disclosed by the invention is simple and safe, low in cost, rich in material and good in experiment repeatability; no high-voltage electric field is used in the preparation process, no organic solvent is used, no pollution can be caused, cell damage can be avoided, and cell packaging can be achieved; the prepared hydrogel is not only uniform, controllable in size, high in mechanical property and good in water absorption performance, but also good in biocompatibility,and has an excellent antibacterial property and a wide application prospect, particularly in the field of sanitary materials.
Owner:DONGHUA UNIV

Double-layer coextruded insulation LED ultraviolet crosslinking colored low-smoke halogen-free flame-retardant cable material and preparation method thereof

ActiveCN110951141AGood flame retardant synergistic performanceGood copper aging resistancePlastic/resin/waxes insulatorsInsulated cablesPolymer scienceAntioxidant
The invention discloses a double-layer coextruded insulation LED ultraviolet light crosslinking colored low-smoke halogen-free flame-retardant cable material. The cable material is composed of an inner-layer insulating material and an outer-layer insulating material, and the inner-layer insulating material is composed of a maleic anhydride grafted ethylene-octene copolymer, polyethylene, an ethylene-octene copolymer, a flame retardant, a flame retardant synergist, an antioxidant, a metal deactivator, a lubricant, a photoinitiator, a multifunctional group cross-linking agent and a color masterbatch; and the outer-layer insulating material is composed of maleic anhydride grafted polyethylene, an ethylene-vinyl acetate copolymer, syndiotactic 1,2-polybutadiene, the flame retardant, the flameretardant synergist, the antioxidant, the lubricant, the photoinitiator, the multifunctional crosslinking agent and the color master batch. The double-layer coextruded inner-layer insulating materialand the outer-layer insulating material are extruded, and then can be fast crosslinked online through LED irradiation equipment, various properties of cables can meet JG / T 441-2014, the mechanical properties and the electrical properties of the cable are excellent, the flame retardant property is good, and the service life of the cable can reach 70 years or longer.
Owner:SHANGHAI KAIBO SPECIAL CABLE FACTORY
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