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319results about How to "Reduce crosslink density" patented technology

Low-modulus monocomponent de-ketoxime type room temperature sulfurized silicone sealant and preparation method thereof

The invention discloses a low-modulus monocomponent de-ketoxime type room temperature sulfurized silicone sealant and a preparation method thereof. The silicon sealant is prepared from hydroxyl end-blocked dimethylsiloxane, a plasticizer, white mineral oil, gas phase method silica aerogel, a reinforcing filler, aluminum stearate, pigment, a crosslinking agent, a vulcanization accelerator, a silane coupling agent and a catalyst. The preparation method comprises the following steps: 1) uniformly mixing the hydroxyl end-blocked dimethylsiloxane, the plasticizer, the white mineral oil, the gas phase method silica aerogel, the reinforcing filler, the aluminum stearate and the pigment, and drying the mixture fully to obtain a premix compound; 2) performing vacuum full kneading on the premix compound to obtain base; 3) adding the crosslinking agent, the vulcanization accelerator and the silane coupling agent into the base, performing vacuum stirring uniformly;4) adding the catalyst into the base, performing vacuum stirring uniformly, discharging the mixture, and performing filling and sealing. The low-modulus monocomponent de-ketoxime type room temperature sulfurized silicone sealant provided by the invention has the advantages of neutral solidification, strong bonding power, excellent mechanical property, and good heat resistance and oil resistance.
Owner:GUANGDONG RES INSTITITUTE OF PETROCHEM & FINE CHEM ENG

Epoxy adhesive toughened by tertiary-amide modified liquid nitrile butadiene rubber

The invention discloses an epoxy adhesive toughened by tertiary-amide modified liquid nitrile butadiene rubber. The adhesive is prepared from the following components in parts by weight: 100 parts of bisphenol-A or bisphenol-F epoxy resin, 8 to 60 parts of amine curing agent and 10 to 70 parts of tertiary-amide modified liquid nitrile butadiene rubber. The curing condition is that all components are uniformly mixed and are cured at a room temperature for 4 to 7 days or are cured at a temperature of 50 DEG C for 1 day. The adhesive has main properties that the tensile strength is 20 to 40 MPa, the elongation at break is 5 percent to 30 percent, the impact strength is 20 to 150 kJ / m2 and high-temperature glass transition temperature is 90 to 120 DEG C. The toughened epoxy adhesive disclosed by the invention has the advantages that excellent mechanical property and excellent toughness are obtained; the curing cross-linking density of the epoxy resin is improved, the high-temperature glass transition temperature of the epoxy adhesive is not reduced, and the high-temperature usage temperature of the adhesive is not reduced while the adhesive is toughened by utilization of the characteristics of catalyzing and curing epoxy functional groups by a tertiary amine group.
Owner:NANJING UNIV
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