The present invention relates to a laminar structure which is used in a microporous layer, an electrode layer or the like of a membrane electrode assembly for a fuel cell, and also relates to a production method for same. The laminar structure is a laminar structure which is comprised in the membrane electrode assembly (MEA) of a polymer electrolyte membrane fuel cell (PEMFC), and comprises an electrosprayed layer which is formed by the lamination of electrospraying ink, that has been charged by means of an electric field, through an electrospraying process in which the electrospraying ink is dispersed and sprayed as electrospraying liquid droplets, and, in the electrospraying process, the electrospraying substance transmission mode is set in accordance with the adjustment of electrospraying process variables. When the present invention is employed, an optimal substance transmission route is formed and three dimensional structure control is allowed through the electrospraying process and/or an inkjet printing process, and thus it is possible to simultaneously ensure economic advantages and durability when producing a laminated structure which is used in a microporous layer, an electrode layer, or the like of a membrane electrode assembly for a fuel cell.