The invention relates to the technical field of
cement admixtures, in particular to a preparation process of an environment-friendly
cement raw material grinding-aid
grinding agent. According to the process, electrolytic
manganese residues and
industrial waste alkali liquor are used as raw materials, and the core is that multi-step synergistic
chemical modification is performed: firstly, the electrolytic
manganese residues are subjected to low-temperature
plasma activation pretreatment to increase surface active sites; secondly, carrying out graft copolymerization on
lignin in the
industrial waste alkali liquor by utilizing an RAFT (Reversible Addition-Fragmentation
Chain Transfer)
polymerization technology, and introducing carboxyl and
amide groups to synthesize a zwitterionic
polymer; then, mixing the modified electrolytic
manganese residues with modified alkali liquor, and inducing to generate a nano precursor with a core-shell structure through a supramolecular self-
assembly and bionic silicification principle; and finally, carrying out
spray drying to obtain a final product. According to the mineralizer disclosed by the invention, the grindability and the burnability of
cement raw materials can be remarkably improved, the clinker burning
coal consumption can be reduced, more importantly, marine cement can be endowed with excellent
chloride ion penetration resistance, and meanwhile, high-added-value
resource utilization of
solid wastes is realized.