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Silicone rubber for composite insulator and preparation method thereof

A composite insulator and silicone rubber technology, which is applied in the field of silicone rubber preparation, can solve the problems of reducing hydrophobicity and mechanical strength, and the lack of flame retardancy of silicone rubber, so as to improve flame retardancy and tracking resistance , Improve the mechanical strength, improve the effect of hydrophobic migration

Active Publication Date: 2011-05-25
PINGGAO GRP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the development of voltage level and technology, the existing silicone rubber materials can no longer meet the requirements of technological development. The electrical erosion ability and flame retardancy of rubber, but its water repellency and mechanical strength are significantly reduced, which cannot meet the current requirements for comprehensive and balanced improvement of silicone rubber properties.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The raw material formulation of the silicone rubber of the present embodiment is as follows in parts by weight: methyl vinyl silicone rubber A 40, methyl vinyl silicone rubber B 60, and the specific surface area is 200 m 2 / g fumed silica 25, aluminum hydroxide 120, silane coupling agent KH-560 3, 2-hydroxy-4-methoxybenzophenone 0.5, zinc oxide 2, triethanolamine 1, stearic acid 0.3, hydrogen-containing silicone oil with a hydrogen content of 0.5% 0.5, vinyl silicone oil 0.2, gray color masterbatch 0.5, hydroxyl silicone oil 2, 2,5-dimethyl-2,5-di-tert-butylperoxyhexane 0.6 ; The molecular weight of the methyl vinyl silicone rubber A is 500,000, and the vinyl content is 0.13%; the molecular weight of the methyl vinyl silicone rubber B is 720,000, and the vinyl content is 0.18%. Wherein the average particle size of aluminum hydroxide is controlled between 2-3 microns. Among them, the vinyl content in the vinyl silicone oil is 8%, and conventional vinyl silicone oil can ...

Embodiment 2

[0035] The raw material formulation of the silicone rubber of the present embodiment is as follows in parts by weight: methyl vinyl silicone rubber A 30, methyl vinyl silicone rubber B 70, and the specific surface area is 150 m 2 / g fumed silica 40, aluminum hydroxide 110, silane coupling agent A151 1,2,4-dihydroxybenzophenone 0.2, zinc oxide 4, triethanolamine 0.5, stearic acid 0.2, hydrogen content 0.7% hydrogen-containing silicone oil 1, vinyl silicone oil 0.6, gray color masterbatch 1, hydroxyl silicone oil 4, dicumyl peroxide 0.5; the molecular weight of the methyl vinyl silicone rubber A is 530,000, and the vinyl content 0.05%; the molecular weight of the methyl vinyl silicone rubber B is 700,000, and the vinyl content is 0.13%. Among them, the vinyl content in the vinyl silicone oil is 8.5%, and conventional vinyl silicone oil or methyl vinyl silicone oil terminated with hydroxyl groups can be used.

[0036] The preparation method of the silicone rubber of the present ...

Embodiment 3

[0043] The raw material formulation of the silicone rubber of the present embodiment is as follows in parts by weight: methyl vinyl silicone rubber A 50, methyl vinyl silicone rubber B 50, and the specific surface area is 300 m 2 / g fumed silica 50, aluminum hydroxide 130, silane coupling agent KH-570 6, 2-hydroxy-4-n-octyloxybenzophenone 2, zinc oxide 6, triethanolamine 3, stearin Acid 1, hydrogen-containing silicone oil 2 with a hydrogen content of 1%, vinyl silicone oil 2, gray color masterbatch 2, hydroxyl silicone oil 6, di-tert-butyl peroxide 1; the molecular weight of the methyl vinyl silicone rubber A is 550,000, and the vinyl content is 0.08%; the molecular weight of the methyl vinyl silicone rubber B is 750,000, and the vinyl content is 0.15%. Among them, the vinyl content in the vinyl silicone oil is 8.2%, and conventional vinyl silicone oil or methyl vinyl silicone oil terminated with hydroxyl groups can be used.

[0044] The preparation method of the silicone rub...

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Abstract

The invention discloses a silicone rubber for a composite insulator, wherein the silicone rubber comprises the following raw materials in parts by weight: 30-50 parts of methyl vinyl silicone rubber A, 50-70 parts of methyl vinyl silicone rubber B, 25-50 parts of fumed silica, 100-130 parts of aluminium hydroxide, 1-6 parts of silane coupling agent, 0.2-2 parts of ultraviolet absorber, 2-6 parts of zinc oxide, 0.5-3 parts of triethanolamine, 0.2-1 parts of stearic acid, 0.5-2 parts of hydrogen-containing silicone oil, 0.2-1 parts of vinyl silicone oil, 0.5-3 parts of color masterbatch rubber, 2-6 parts of hydroxyl silicone oil and 0.5-1 parts of vulcanizing agent. The silicone rubber provided by the invention can achieve the following performances: the tensile strength is larger than 4 MPa; the breaking elongation is larger than 350%; the peel strength is larger than or equal to 12 KN.m<-1>; the shore hardness is 60+ / -5 degrees; the thermal aging tensile strength retention is larger than or equal to 90%; the anti-creep track passes a grade of 1A4.5; the flame retardance reaches a grade of FV-0; the average static contact angle is larger than 105 degrees; the electrical surface resistivity is larger than 2*10<15> omega; the dielectric constant is smaller than 3.8; and the dielectric loss angle tangent is smaller than 0.01.

Description

technical field [0001] The invention relates to a silicone rubber for composite insulators and a preparation method of the silicone rubber. Background technique [0002] Composite insulators are composed of glass fiber composite core rods or hollow pipes and silicone rubber sheds. Compared with traditional ceramic insulators and glass insulators, composite insulators have the advantages of light weight, strong pollution flashover resistance, and simple manufacturing process. In recent years, it has developed very rapidly in our country. The silicone rubber shed is on the outside of the composite insulator mandrel or hollow pipe, which can withstand high electric field, withstand the harsh outdoor natural environment (including ultraviolet radiation, salt spray, sand and dust, high and low temperature changes, etc.) while protecting the inner mandrel or hollow pipe Therefore, the silicone rubber material used in the umbrella skirt is required to have good tracking resistance...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/07C08L83/05C08L83/06C08K13/02C08K3/36C08K3/22C08K5/14C08K5/17
Inventor 史鸿威陈延辉宋晓光平海涛
Owner PINGGAO GRP
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