Novel vanadium halide redox flow battery

a redox flow battery and vanadium halide technology, applied in the direction of non-aqueous electrolyte cells, indirect fuel cells, cell components, etc., can solve the problems of reducing the life of cell components, causing bromine gas emission, etc., and achieve the effect of avoiding excessive bromine generation

Inactive Publication Date: 2006-08-17
NEWSOUTH INNOVATIONS PTY LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0087] The V(III) compound may be V203 and the V(V) compound may be V205. To avoid excessive bromine generation, the V(III) compound is added to the halide solution first and allowed to partially

Problems solved by technology

This means that the positive half-cell electrolyte always contains excess bromine or the relatively unstable Br3− or Br2Cl− species that could give rise to bromine gas emission problems during operation of

Method used

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  • Novel vanadium halide redox flow battery
  • Novel vanadium halide redox flow battery
  • Novel vanadium halide redox flow battery

Examples

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Effect test

example 1

[0166]FIG. 6 shows the initial charge-discharge curve for a vanadium halide redox flow cell containing 60 ml in each half-cell of a 2 M V(3.5+) solution in 6 M Br− plus 2 M Cl−. The cell employed a Gore Select P-03430 membrane. The cell was initially charged to a voltage of 1.25 V and discharged to a lower voltage limit of 0.25 V at a constant current of 1.0 Amp. The ratio of the initial charge time to the discharge time is seen to be approximately 1.5 showing that during the initial charge, 1.5 electrons per mole of vanadium are used in converting the V(3.5+) solution to V2+ in the negative half-cell while in the positive half-cell, V(III) ions are first oxidised to V(IV) followed by the oxidation of Br− ions to Br3−. Subsequent charge-discharge cycles gave average charge and discharge time ratios of between 1.05 and 1.1, corresponding to coulombic efficiencies of 95 to 91%.

example 2

[0167] A cell employing a solution of 3 M vanadium (III) / (IV) bromide as the active material in both half-cells was set up and evaluated as follows:

[0168] The 50:50 vanadium(III) / vanadium (IV) bromide mixture (referred to as 3 M V(3.5+) was prepared by dissolving the required amounts of vanadium trioxide and pentoxide powders in 8 M hydrobromic acid. Hydrochloric acid was also added to bring the final solution chloride concentration to 1.5 M.

[0169]FIG. 7 shows the cell voltage versus time curves obtained during the charging and discharging cycling of the cell containing 60.0 mls of the solution in each half-cell and employing a Gore Select P-03430 membrane. The cell was charged to a voltage of 1.6 V and discharged to a lower voltage limit of 0.25 V at a constant current of 2.0 Amp. The theoretical charge and discharge time, assuming complete reaction of the vanadium ions in the negative half-cell was calculated as 2.4 hours. This compares with measured charge and discharge times o...

example 3

[0170] A 3 M V(3.5+) solution was prepared by combining a 3:1 mole ratio of V2O3:V2O5 powders as follows:

[0171] Mass V2O3 used: 168.64 g

[0172] Mass V2O5 used: 62.21 g

[0173] 1000 ml of 8M HBr was mixed with 150 ml 10 M HCl, stirred and heated around to 80° C. The V2O3 powder was slowly added to the HBr / HCl mixture, followed by slow addition of the V2O5 powder. The solution was then boiled to around 150° C. for about 1 hour. The final volume was approximately 1010 ml. During the vanadium oxide dissolution, negligible bromine was detected. When the same process was repeated by simultaneously adding the vanadium trioxide and vanadium pentoxide powders to the HBr / HCl mixture, however, bromine gas was observed to form as the vanadium pentoxide oxidised the bromide ions to bromine.

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Abstract

A prior to charge vanadium halide redox cell, a vanadium halide redox cell which is at a state of charge selected from the group consisting of a zero state of charge and a near zero state of charge and vanadium halide redox cell which are fully charged and partially charged are described. The prior to charge vanadium halide redox cell comprises a positive half cell containing a positive half cell solution comprising a halide electrolyte, vanadium (III) halide and vanadium (IV) halide, a negative half cell containing a negative half cell solution comprising a halide electrolyte, vanadium (III) halide and vanadium (N) halide wherein the amounts of vanadium (III) halide, vanadium (IV) halide and halide ions in the positive and negative half cell solutions are such that in a first charging step comprising charging the prior to charge vanadium halide redox cell, a vanadium halide redox cell having a state of charge selected from the group consisting of a zero state of charge and a near zero state of charge comprising predominantly vanadium (N) halide in the positive half cell solution and predominantly V(III) halide in the negative half cell solution can be prepared. The vanadium halide redox cell which is at a state of charge selected from the group consisting of a zero state of charge and a near zero state of charge comprises a positive half cell containing a positive half cell solution comprising a halide electrolyte and a vanadium halide which is predominantly vanadium (N) halide, a negative half cell containing a negative half cell solution comprising a halide electrolyte and a vanadium halide which is predominantly vanadium (III) halide wherein the amount of vanadium (N) halide in the positive half cell solution and the amount of vanadium (III) halide in the negative half cell solution are such that the vanadium halide redox cell is at a state of charge selected from the group consisting of a zero state of charge and a near zero state of charge. The vanadium halide redox cell which is fully charged comprises a positive half cell containing a positive half cell solution comprising a halide electrolyte, a polyhalide complex, vanadium (IV) halide and vanadium (V) halide, a negative half cell containing a negative half cell solution comprising a halide electrolyte and vanadium (II) halide wherein the molar concentration of vanadium (V) and polyhalide complex:molar concentration of vanadium (II) halide is about stoichiometrically balanced. The vanadium halide redox cell which is partially charged comprises a positive half cell containing a positive half cell solution comprising a halide electrolyte, a polyhalide complex, vanadium (IV) halide and vanadium (V) halide, a negative half cell containing a negative half cell solution comprising a halide electrolyte, vanadium (II) halide and vanadium (III) halide wherein the number of moles of moles of polyhalide complex and vanadium (V): number of moles of vanadium (II) halide is about stoichiometrically balanced.

Description

TECHNICAL FIELD [0001] Disclosed is a vanadium halide redox flow cell employing a 50:50 vanadium(III) / (IV) halide solution as the initial feed electrolyte solution in both the positive and negative half cells. Also disclosed is the 50:50 V(III) / V(IV) halide feed solution for use in the positive and negative half-cells of the vanadium halide redox flow cell. A vanadium halide redox flow cell is also disclosed in which the initial feed solution for the negative half-cell is a vanadium (III) halide electrolyte and in which a vanadium (IV) halide electrolyte is used as feed solution for the positive half-cell. Methods of producing the vanadium (III), vanadium (IV) and vanadium (III) / (IV) halide electrolytes for the vanadium halide redox flow cell are also disclosed. In addition, a method of producing electricity by discharging the fully charged or partially charged vanadium halide redox flow cell or battery is disclosed, as well as methods of recharging the discharged or partially disch...

Claims

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Application Information

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IPC IPC(8): H01M8/20H01M8/18
CPCB60L11/1822B60L11/1879B60L2240/545H01M8/188H01M8/20Y02T90/14Y02T10/7005Y02T10/705Y02T10/7072Y02T90/124Y02E60/528B60L53/80B60L50/64Y02E60/50Y02T10/70Y02T90/12
Inventor KAZACOS, MICHAELSKYLLAS-KAZACOS, MARIAKAZACOS, NICHOLASL
Owner NEWSOUTH INNOVATIONS PTY LTD
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