19 results about "Diphosphorus" patented technology

The invention discloses flame-retardant electrical epoxy resin and a preparation method thereof in the field of epoxy resin. The flame-retardant electrical epoxy resin is prepared from the following components in parts by weight: 70 to 80 parts of bisphenol F epoxy resin, 20 to 30 parts of alicyclic epoxy resin, 20 to 40 parts of benzoxazine resin monomer, 50 to 70 parts of curing agent and 0.5 to 1.5 parts of curing accelerator. Through the functionalized benzoxazine resin monomer containing the diphosphorus structure, optimization of epoxy resin formula components and improvement of a preparation process, synergistic improvement of flame retardance, electrical insulation performance, heat resistance and mechanical performance is achieved.

The invention discloses a method for preparing a porphyrin ring-branched polybenzimidazole and a porphyrin ring-branched polybenzimidazole proton exchange membrane. The porphyrin ring-branched polybenzimidazole is prepared by the following method: in polyphosphoric acid containing phosphorus pentoxide, at least one of the aromatic tetraamine monomers shown in formula I, at least one of the dicarboxylic acid monomers shown in formula II and the tetrakis(4-carboxyphenyl)porphine shown in formula III are subjected to polycondensation reaction to obtain the porphyrin ring-branched polybenzimidazole. The invention provides a method for preparing a homogeneous proton exchange membrane using the porphyrin ring-branched polybenzimidazole. The proton exchange membrane prepared by the invention has good solubility, antioxidant stability, mechanical properties, dimensional stability and high proton conductivity.

The application discloses a preparation method and system of sodium difluorophosphate. The preparation method of sodium difluorophosphate comprises the following steps: S100, in a water-free or low-water environment, a solid-phase reaction is generated between diphosphorus pentoxide and ammonium fluoride to obtain an ammonium difluorophosphate intermediate, and volatile substances generated in the reaction process are removed and recovered; S200, in a water-free organic solvent, the ammonium difluorophosphate intermediate obtained in the step S100 is reacted with a sodium salt to obtain sodium difluorophosphate. The preparation method of sodium difluorophosphate provided by the application uses diphosphorus pentoxide and ammonium fluoride as reaction raw materials to obtain an ammonium difluorophosphate intermediate, and then reacts to obtain sodium difluorophosphate. The obtained sodium difluorophosphate has high purity and few impurities. The preparation method of sodium difluorophosphate has the advantages of cheap and easily obtained raw materials, stable chemical properties, few by-products generated in the reaction, and easy recovery, and is a green and safe preparation method of sodium difluorophosphate.

The invention provides a flame-retardant rubber conveyor belt material and a preparation method thereof, comprising the following raw materials in parts by weight: 10-20 parts of hyperbranched polysiloxane containing phosphorus heterophenanthrene structure and vinyl, 10-15 parts of functional polymer, 40-50 parts of styrene-butadiene rubber, 3-5 parts of 2-acrylamide-2-methylpropane sulfonic acid, 1-3 parts of 2,4,6-trivinyl cycloboroxane, 0.8-1.2 parts of phosphorus pentoxide, 0.3-0.5 parts of polyphosphoric acid, 2-4 parts of vulcanizing agent, 20-30 parts of reinforcing agent, 3-5 parts of coupling agent, 1-3 parts of zinc stearate; the functional polymer comprises structural units introduced by the following monomers: benzoguanamine, diisocyanate polyethylene glycol, 4,4'-diaminodiphenyl sulfide. The material has good mechanical properties, excellent wear resistance and flame retardancy, and good heat aging resistance.

The invention belongs to the technical field of organic synthesis, and particularly relates to a synthesis method of a monophosphorus or diphosphorus compound, which comprises the following steps: reacting imine and diphenylphosphine oxide serving as raw materials in a solvent in the presence of water in the presence of aluminum trichloride serving as a catalyst, and performing post-treatment after the reaction to obtain an alpha-hydroxy phosphorus compound or an alpha-diphosphorus compound; wherein imine contains a group R, diphenyl phosphine oxide contains a group R1, R is selected from one of aryl, furan and thiophene, and R1 is independently selected from one of hydrogen, alkyl and halogen. The method is simple and safe to operate, the selection of the catalyst and the solvent is green and environment-friendly, the method is an economical, environment-friendly and efficient synthesis method, the diversity of the structures of the alpha-hydroxy phosphorus compound and the alpha-diphosphorus compound is increased, and the method can be applied to practical operations such as synthesis, research and development of the alpha-hydroxy phosphorus compound and / or the alpha-diphosphorus compound.

The present application relates to big data analysis technical field, specifically to a kind of mineral fertilizer production quality control method based on big data, comprising the following steps: reading phosphorus ore diphosphorus pentoxide content and potassium ore impurity calcium magnesium content, generating incoming material quality correlation coefficient set, the numerical values in the incoming material quality correlation coefficient set are weighted combination mapping, and incoming material comprehensive characteristic parameter matrix is generated.The present application introduces finished product granulation pulverization rate, acid-base neutralization consumption determination value into the inversion process of significant dynamic threshold, so that front-end raw material fluctuation and middle section operation fluctuation can accept the reverse check of end quality boundary, thereby obtaining stronger quality causal through capability, abnormal positioning capability and interception specificity, which can not only compress the path length of raw material difference transmission to finished product defect, but also reduce the misjudgment risk caused by empirical threshold, and can also enhance the identification accuracy of batch fluctuation, working condition drift and quality instability precursor.

To provide a diphosphorus pentasulfide composition that can improve the lithium ion conductivity of the obtained sulfide-based inorganic solid electrolyte material.SOLUTION: A diphosphorus pentasulfide composition, which is a diphosphorus pentasulfide composition for sulfide-based inorganic solid electrolyte material, and in which the mole ratio (S / P) of the sulfur (S) content to the phosphorus (P) content is 2.40 or more and 2.49 or less.SELECTED DRAWING: None

The invention relates to the technical field of chemical synthesis, and particularly discloses a method for constructing chiral 2, 3-disubstituted butyrate through asymmetric hydrogenation of tetra-substituted alpha, beta-unsaturated carboxylic acid derivatives, and chiral ester and chiral amide prepared through the method. According to the present invention, the beta-unsaturated carboxylic acid derivative is adopted as the substrate, hydrogenation is performed to construct the chiral ester and the chiral amide, the catalyst preparation method is simple, the performance is stable, and the good chiral selection effect and the good conversion rate can be obtained under the high substrate / catalyst condition; the metal catalyst is prepared from a metal nickel complex and a diphosphorus chiral ligand (R, R)-QuinoxP *. The method provided by the invention has the characteristics of high enantioselectivity, high yield and high conversion number (TON). The method can be used for synthesizing various substituted chiral esters and amides, can be used as important intermediates for preparing various medicines, and has important significance on the production of the medical industry.

There is provided a diphosphorus pentasulfide composition according to the present embodiment, in which a degree of crystallinity calculated from a spectrum obtained by X-ray diffraction using a CuKa ray as a ray source is equal to or more than 40% and equal to or less than 80%, in a DSC curve of the diphosphorus pentasulfide composition obtained by measurement using a differential scanning calorimeter under conditions of a start temperature of 25°C, a measurement temperature range of equal to or more than 30°C and equal to or less than 350°C, a temperature rising rate of 5°C / min, and an argon atmosphere of 100 ml / min, an endothermic peak is observed in a temperature range of equal to or more than 280°C and equal to or less than 300°C, and a heat of fusion of the endothermic peak is equal to or more than 60 J / g and equal to or less than 100 J / g.

The invention discloses a method for preparing iron oxide and high-purity phosphorus pentoxide from phosphorus-containing and iron-containing waste, and relates to the technical field of solid waste utilization. The method comprises the following steps: crushing solid phosphorus-containing and iron-containing wastes, heating and melting in an inert environment, and spraying the molten phosphorus-containing and iron-containing wastes into a first reaction furnace in a blowing manner, or introducing oxygen-containing gas into the first reaction furnace when liquid phosphorus-containing and iron-containing wastes are sprayed into the first reaction furnace in a blowing manner; raising the temperature of the first reaction furnace to 360-900 DEG C, and keeping the temperature for 30-60 minutes to obtain a P2O5 steam crude product and iron oxide; collecting a P2O5 steam crude product from the top of the first reaction furnace, and collecting iron oxide from the bottom of the first reaction furnace; and introducing the collected P2O5 steam crude product into a second reaction furnace, and raising the temperature to be higher than 360 DEG C to obtain high-purity P2O5 steam. The method disclosed by the invention has the advantages of simple process flow, small wastewater generation amount, high phosphorus element recovery rate and high phosphorus pentoxide purity.

The synthesis process comprises the following steps: by taking lactic acid and o-phenylenediamine as raw materials, carrying out condensation reaction in water by taking solid acid as a catalyst to obtain 2-alpha-hydroxyethyl benzimidazole; the preparation method comprises the following steps: mixing 2-alpha-hydroxy ethyl benzimidazole and micron-sized magnetic iron powder, putting the mixture into water, and adding hydrogen peroxide for catalytic oxidation to obtain 2-acetyl benzimidazole; the preparation method comprises the following steps: putting 2-acetylbenzimidazole into glacial acetic acid, adding bromine, and carrying out bromine substitution reaction by taking MOF (Metal Organic Framework) powder taking trivalent Fe as a central metal as a catalyst to obtain 2-dibromoacetylbenzimidazole hydrobromide; the preparation method comprises the following steps: adding formamide and phosphorus pentasulfide into ethyl acetate, reacting at 30-45 DEG C for 1-2 hours, adding 2-dibromoacetyl benzimidazole hydrobromide, introducing ammonia gas to catalyze a cyclization reaction, filtering after the reaction is finished, cooling filtrate to separate out a solid, separating the solid, and washing to obtain the thiabendazole. Compared with the prior art, higher yield can be obtained, the reaction conditions are mild, the catalyst and the solvent are easy to separate for recycling, raw material waste is reduced, and the resource recovery difficulty is reduced.

The invention belongs to the technical field of organic synthesis, and particularly relates to a diphosphine oxide compound, a photochemical synthesis method of the diphosphine oxide compound and application of the diphosphine oxide compound in flame retardance and aging resistance of resin. The diphosphine oxide compound can be used as a flame retardant, and the polyphosphine oxide compound prepared from the diphosphine oxide compound can be used as an anti-aging agent. The diphosphorus oxide compound disclosed by the invention can well realize flame retardance of various high polymer materials including polyurethane and epoxy resin. The poly (diphosphorus oxide) compound disclosed by the invention shows relatively good anti-aging performance in a polyurethane material.

The present application relates to the technical field of organic phase change material, and more particularly to an intrinsic flame-retardant solid-solid phase change material, a preparation method thereof, a battery module and application thereof.The preparation raw material of the intrinsic flame-retardant solid-solid phase change material comprises a boron phosphate ester of a phase change substance with a hydroxyl group, expanded graphite, an amino-containing flame retardant and an isocyanate compound; and the preparation raw material of the boron phosphate ester of the phase change substance with a hydroxyl group comprises a phase change substance with a hydroxyl group, boric acid and diphosphorus pentoxide.The intrinsic flame-retardant solid-solid phase change material has the advantages of flame retardation, mechanics and thermal stability.

The invention relates to a preparation method of a lithium-containing sulfide, lithium thiophosphate and a sulfide solid electrolyte. The preparation method comprises the following steps: providing a first raw material containing liquid phosphorus pentasulfide and / or liquid sulfur and a second raw material containing a lithium element; wherein the second raw material containing the lithium element comprises lithium sulfide powder or liquid lithium; in an inert gas atmosphere, the first raw material and the second raw material are contacted and react in a reactor; the reaction temperature ranges from 280 DEG C to 500 DEG C. According to the method, the liquid phosphorus pentasulfide and the second raw material containing the lithium element are contacted and react at a relatively low temperature, so that the problem of low purity possibly caused by a grinding process is avoided, the lithium-containing sulfide with high purity and controllable particle size can be obtained through rapid, continuous and large-scale production, and the production cost is reduced.

The invention discloses a method for synthesizing gem-difluorocyclopropane through asymmetric hydrogenation of gem-difluorocyclopropene under catalysis of rhodium, gem-difluorocyclopropene ester or ketone is used as a reaction substrate 1, a chiral diphosphorus ligand of rhodium is used as a catalyst, gem-difluorocyclopropane 2 is synthesized through asymmetric hydrogenation, and the enantiomeric excess can reach 97.9%. The method is simple, convenient and practical to operate, high in enantioselectivity and good in yield, and the reaction has green atom economy and is environment-friendly.

To provide a novel diphosphorus pentasulfide composition that is useful for the production of sulfide-based inorganic solid electrolyte material.SOLUTION: The diphosphorus pentasulfide composition of the present embodiment has a crystallinity degree calculated from a spectrum obtained by X-ray diffraction using CuKα ray as a radiation source, of 40% or more and 80% or less, and has an endothermic peak observed in a temperature region of 280°C or higher and 300°C or lower in a DSC curve of the diphosphorus pentasulfide composition obtained by measurement using a differential scanning calorimeter under the conditions of a starting temperature of 25°C, a measurement temperature range of 30 to 350°C, a temperature increasing rate of 5°C / min, and an argon atmosphere of 100 ml / min, and the amount of heat of fusion for the endothermic peak is 60 J / g or more and 100 J / g or less.SELECTED DRAWING: Figure 2

Provided is a diphosphorus pentasulfide composition for a sulfide-based inorganic solid electrolyte material, in which a molar ratio (S / P) of a content of sulfur (S) to a content of phosphorus (P) is 2.40 or higher and 2.49 or lower. In the diphosphorus pentasulfide composition for a sulfide-based inorganic solid electrolyte material, in a DSC curve of the diphosphorus pentasulfide composition obtained by measurement using a differential scanning calorimeter under conditions of a start temperature of 25° C., a measured temperature range of 30° C. to 350° C., a temperature increase rate of 5° C. / min, and an argon atmosphere with a flow rate of 100 ml per minute, an endothermic peak is shown in a temperature range of 280° C. or higher and 300° C. or lower, and a half-width of the endothermic peak is 4.1° C. or higher.

The invention provides a method for preparing 1, 4-butanediol from acrolein by two steps, and belongs to the technical field of fine chemical engineering. Acrolein reacts with synthesis gas under the combined action of a rhodium catalyst, monophosphine / diphosphorus and a bisphosphite ligand, and 1, 4-butanedialdehyde is generated with high selectivity. And carrying out hydrogenation on the 1, 4-butanedialdehyde by using a copper-based catalyst to generate the 1, 4-butanediol. The process is easy to operate and suitable for large-scale production; acrolein is adopted as a reaction raw material, carbonylation is carried out at one end, carbonylation selectivity is higher, and the synthesis route of 1, 4-butanediol is enriched.

The invention discloses a chiral ligand catalyst and application of the chiral ligand catalyst to preparation of high-selectivity trans-1, 4 cyclohexanediol through hydroquinone hydrogenation reaction, and the catalyst is composed of a precursor, a ligand, a carrier and a metal salt; the precursor and the ligand are RhCl3 and a chiral diphosphorus ligand; the carrier is any one of silica gel 60, activated carbon, TiO2, gamma-Al2O3 or a NaY type molecular sieve; the metal salt is any one or more of nitrates or phosphates of Na, Fe, Co, Zn and Cu. The invention also provides a preparation method of the catalyst and application of the catalyst in preparation of high-selectivity trans-1, 4 cyclohexanediol through hydroquinone hydrogenation reaction. According to the chiral ligand catalyst and the application of the chiral ligand catalyst in preparation of high-selectivity trans-1, 4-cyclohexanediol through hydroquinone hydrogenation reaction, a cheap and easily available way is designed, the production cost is reduced, and the catalyst can effectively improve the proportion of the trans-1, 4-cyclohexanediol product.