The invention relates to a high-receiving-sensitivity passive RFID system with optical link connection. By the adoption of an optical link structure, the high-receiving-sensitivity passive RFID system has the advantages of being easily applied to wiring in different environments, being very low in optical link loss under a long-distance transmission circumstance, being suitable for transmission of large volumes of data and the like, and therefore the distribution range of an antenna is enlarged, the receiving sensitivity of the system is improved, and the system is suitable for application scenarios when a large number of electronic tags are identified. The problems that according to an existing passive RFID system, the range of tag identification is small, and identification accuracy is low are solved. The high-receiving-sensitivity passive RFID system can be widely applied to the fields of warehouse management in logistics storage, identity recognition, transportation, food, medical treatment, animal management, entrance guard against theft, industry, military and the like.