The invention provides an anti-overcharging additive used for a
lithium battery electrolyte, and the
lithium battery electrolyte comprising the additive, and relates to the technical field of the
lithium ion battery. The anti-overcharging additive mainly consists of
biphenyl, phenylcyclohexane, diflurodiphenyl,
fluorobenzene and lithium
difluorophosphate, wherein the
biphenyl, phenylcyclohexane and diflurodiphenyl are used as electrical
polymerization type compounds, so that a
cell can have corresponding over-charging additives for reaction in different
voltage sections in an over-charging process constantly; meanwhile, by virtue of interaction of
fluorobenzene and phenylcyclohexane, the electrical
polymerization film forming impedance degree of phenylcyclohexane in a
low voltage section can be lowered; by adding lithium
difluorophosphate, increasing of impedance caused by
voltage section micro film forming in normal use of the
cell due to addition of the over-charging additives of
biphenyl, phenylcyclohexane, diflurodiphenyl,
fluorobenzene, and the like can be lowered; and furthermore, the
lithium battery electrolyte comprising the anti-overcharging additive can block
thermal breakdown possibly caused by overcharging in a mild manner, so that performance degradation of the
cell in the overcharging condition can be further avoided.