The invention discloses a self-reaction substance
drying process safety assessment and classification method based on
thermal analysis kinetics. The method comprises the following steps: performing a multi-heating-rate programmed heating test on a self-reaction substance under a closed condition by adopting DSC to obtain an exothermic initial temperature, a peak temperature and a specific exothermic quantity, constructing a
thermal decomposition kinetic model based on the obtained data, and solving kinetic parameters such as apparent
activation energy and pre-exponential factors; combining an
energy conservation equation and a
thermal explosion theory, predicting a self-accelerated
decomposition temperature SADT under an adiabatic condition TD24 and a given filling and heat dissipation condition, determining a temperature safety threshold value of a
drying process according to the SADT, and dividing a working condition safety interval; further introducing three dimensionless safety factors including a temperature
safety margin, a time
safety margin and a
thermal explosion margin, constructing a comprehensive
risk index, and carrying out risk grade division on the
drying working condition. The method provided by the invention has the advantages of low sample consumption, simple test conditions and standardized calculation process, can quantitatively evaluate the safety drying temperature upper limit of different self-reaction substances and under different
process conditions, and provides a reliable basis for drying
process design and
safety control of the self-reaction substances.