27 results about "Zirconium diboride" patented technology

This invention discloses a coating for sand casting of aluminum-lithium alloys and its preparation method. The coating comprises a surface layer in contact with the sand mold and a top layer in contact with the melt. The surface layer material is an alcohol-based zirconium oxide coating containing graphene, and the top layer coating is an alcohol-based boride coating containing titanium diboride and zirconium diboride. This invention effectively improves the coating density and heat transfer rate by doping graphene with metal boride nanoparticles. Using graphene, ceramic materials, and metal borides as aggregates and dopants effectively suppresses the burn-off of light elements such as Li, reducing subcutaneous pinholes and porosity defects in the casting. Using zirconium oxide powder as aggregate increases nucleation sites, effectively improving the quality of non-ferrous metal castings.

The application relates to a preparation method of a low-density zirconium diboride-silicon carbide foam ceramic material and belongs to the technical field of foam ceramic preparation. The application aims at solving the problems of forming difficulty and sintering shrinkage of the zirconium diboride-silicon carbide foam ceramic. The preparation method is simple. The silicon carbide template prepared by impregnating a ceramic impregnation solution under vacuum conditions is dried and sintered in subsequent steps, and finally, the low-density zirconium diboride-silicon carbide foam ceramic is obtained. The low-density zirconium diboride-silicon carbide foam ceramic material prepared by the application has the characteristics of uniform structure, nanometer-level grains and excellent mechanical properties, and has a good application prospect in the high-temperature heat insulation field.

A method of using a tungsten inert gas (TIG) welding flux for super duplex stainless steel (SDSS) is used to solve the problems of low weld depth / width ratio, low corrosion resistance, and arc blow existing in the conventional TIG welding flux for duplex stainless steel. The TIG welding flux for SDSS includes 20-30 wt % of silicon dioxide (SiO2), 20-25 wt % of titanium dioxide (TiO2), 15-20 wt % of vanadium dioxide (VO2), 10-15 wt % of molybdenum trioxide (MoO3), 10-15 wt % of zirconium diboride (ZrB2), 5-10 wt % of aluminum nitride (AlN), 5-10 wt % of manganese carbonate (MnCO3) and 5-10 wt % of nickel carbonate (NiCO3).

The invention provides a hexagonal boron nitride / zirconium diboride-silicon carbide layered ceramic material as well as a preparation method and application thereof, and belongs to the technical field of ceramic materials. The preparation method comprises the following steps: firstly, respectively preparing soft-layer ceramic slurry and hard-layer ceramic slurry, then respectively carrying out tape casting to obtain hexagonal boron nitride green body laminates and ZrB2-SiC green body laminates, overlapping the two green body laminates, then carrying out degreasing and hot pressed sintering, and directionally arranging hexagonal boron nitride in the hexagonal boron nitride green body laminates to form a highly textured structure, by introducing the ZrB2-SiC green body layer sheets, the ceramic material has high strength and high toughness at the same time, and the ceramic material has excellent mechanical properties. The result of the embodiment shows that the bending strength of the prepared ceramic material is 97 MPa or above, and the fracture toughness is 4.10 MPa.m < 1 / 2 > or above.

The application relates to the technical field of ultrahigh-temperature ceramic materials, and discloses a nano ZrB2-SiC composite ceramic powder based on gradient proportioning regulation and a low-temperature preparation method thereof; in view of the technical bottlenecks such as high reaction temperature (>=1600 DEG C), large powder particle size (>=10 mu m) and difficult two-phase proportion regulation in the prior art, the application innovatively proposes a gradient temperature-subsection proportioning preparation process. By accurately controlling the raw material proportioning of n(ZrO2):n(B4C):n(Si):n(C)=3:(1.8-2.0):1:(5.5-6.0), adopting a two-stage heating procedure (SiC crystal nuclei are preferentially generated at 1200 DEG C, and ZrB2 synthesis is completed at 1500 DEG C), the low-temperature and high-efficiency synthesis of ZrB2-SiC composite powder is realized in a single process. The complete reaction temperature is successfully reduced to 1500 DEG C, the average particle size of the obtained powder is 0.5-0.6 mu m, the oxygen content is <=0.8 wt%, and the ZrB2:SiC molar ratio can be accurately regulated in the range of 2:1 to 4:1 by adjusting the Si content. The ZrB2 (101) plane and the SiC (111) plane in the powder form a semi-coherent interface, and the crystal lattice distortion rate is <=3%.

The application discloses a kind of high thermal shock resistance magnesium carbon brick, which is made of the following raw materials by weight percentage: fused magnesite aggregate 60-75%, fused magnesite fine powder 10-20%, flake graphite 8-12%, thermosetting phenolic resin binder 3-4%, vitamin C 0.3-0.8%, and zirconium diboride 2.2-4.9%. The preparation process of the magnesium carbon brick disclosed in the application includes: dissolving VC in part of the phenolic resin to form an acid-based pretreatment solution; using the strategy of dry mixing aggregate with ZrB2 to make ZrB2 preferentially adhere to the surrounding of aggregate particles; then using a two-step wet mixing and material packing process of adding the VC pretreatment solution first and then adding the remaining resin, the functions of vitamin C and zirconium diboride are coordinated in resisting thermal shock, which fundamentally inhibits the structural spalling of the magnesium carbon brick in the ladle.

This invention provides a (La) 0.5 Ba 0.5 A method for preparing a B6[100]-ZrB2 eutectic composite material, and a cathode device comprising the same. In the eutectic composite material, La 0.5 B 0.5 The molar ratio of B6 to ZrB2 is 2.1:1, (La 0.5 Ba 0.5 ZrB6 is the matrix with a crystal orientation of [100]; ZrB2 is the reinforcing phase existing in the form of fibers. This eutectic composite material has high thermal emission properties and high strength and toughness.

The invention belongs to the field of electrochemistry, and particularly relates to a zirconium diboride composite positive electrode material and a preparation method and application thereof.The preparation method comprises the steps that a zirconium source and a boron source are mixed and then subjected to high-temperature heat treatment in an inert gas atmosphere in an environment with a reducing agent, and nanometer zirconium diboride is obtained; the preparation method comprises the following steps: fully dispersing nano zirconium diboride and activated carbon in a solvent, and fully grinding to obtain the zirconium diboride composite material. The electrode material prepared by the method is high in stability and good in cycle performance.

The present application relates to the technical field of battery shell production, and particularly relates to a production method of a battery aluminum shell.The present application discloses a production method of a battery aluminum shell, which comprises the following steps: after 6-series aluminum alloy is subjected to melting, degassing, continuous casting and rolling forming, the aluminum alloy is subjected to two-stage ball milling together with zirconium diboride and modified lignin to prepare a composite plate; after pretreatment through alkali washing and acid etching, the plate is coated with a lignin-zinc compound coating and solidified; after preheating, the plate is pulled through a gradient temperature mold to perform hot draw forming, and an interface reaction occurs simultaneously; after laser repair welding of defects, the plate is subjected to preheating, cooling and stabilization heat treatment; finally, the plate is subjected to precise machining such as milling and polishing to obtain a finished product.The present application can make the aluminum shell have stable microstructure and optimized interface bonding, excellent mechanical properties and corrosion resistance by means of phase composite, gradient coating and heat treatment regulation, and the process is controllable, so the present application is suitable for large-scale production of battery aluminum shells.

The invention discloses a magnesia carbon brick with high thermal shock resistance. The magnesia carbon brick is prepared from the following raw materials in percentage by weight: 60-75% of fused magnesia aggregate, 10-20% of fused magnesia fine powder, 8-12% of crystalline flake graphite, 3-4% of a thermosetting phenolic resin binder, 0.3-0.8% of vitamin C and 2.2-4.9% of zirconium diboride. The preparation process of the magnesia carbon brick disclosed by the invention comprises the following steps: dissolving VC in part of phenolic resin to form an acid group pretreatment solution; zrB is preferentially attached to the periphery of aggregate particles by adopting a dry mixing strategy of the aggregate and ZrB; and then a two-step wet mixing and ageing process of firstly adding the VC pretreatment liquid and then adding the residual resin is adopted, so that functional synergy of vitamin C and zirconium diboride in a thermal shock resisting process is realized, and structural stripping of the ladle magnesia carbon brick is fundamentally inhibited.

The application discloses a zirconium diboride-based ultrahigh-temperature ceramic material and a preparation method and a preparation device thereof, and comprises the following steps: S1, preparing a zirconium diboride ceramic blank; S2, placing the zirconium diboride ceramic blank into a heating element to perform sintering by electrifying, the blank is wrapped by the heating element, the heating element is made of conductive material, and the sintering condition is that a direct-current power supply outputs constant power, the output power is 1300-2300 W, the holding time is 10-90 s, and then the power supply is disconnected to naturally cool. The heating element can be rapidly heated by high-power electrification, a high-temperature temperature field is formed between the upper and lower surfaces of the heating element, heat is conducted into the blank through heat radiation, the blank is sintered, and thus densification is completed, a very fast heating rate is realized, the dense ultrahigh-temperature ceramic is prepared in a short sintering period, the traditional sintering mode that is high in energy consumption and long in time consumption is broken, and large-batch production can be performed in a very short period.

The invention relates to a preparation method of ceramic boron-phenolic composite resin, and aims to solve the problems of poor mechanical property, reduced heat resistance and the like of the existing phenolic resin material. The preparation method comprises the following steps: 1, dissolving boron phenolic resin in absolute ethyl alcohol under a heating condition; 2, adding a mixed filler into the resin solution under a water bath heating condition, wherein the mixed filler is prepared from calcined kaolin, aluminum oxide, low-melting-point glass powder, diboron trioxide and zirconium diboride; 3, carrying out pre-curing treatment; 4, performing vacuum curing treatment; and 5, final curing treatment. By screening and designing the ceramic forming agent components and determining the optimal ratio of the ceramic forming agent components, the mechanical property of the boron phenolic resin laminated board is remarkably enhanced, the heat resistance and the mechanical property are remarkably improved, the synergistic effect of the ceramic matrix and the ceramic forming agent is utilized, a filler system is constructed, and the service life of the boron phenolic resin laminated board is prolonged. And efficient ceramic conversion of the material in combustion and high-temperature extreme environments is ensured, so that the composite material is endowed with excellent ablation resistance and high-temperature stability.

The application discloses a low-residual-stress superhard titanium alloy zirconium diboride film and a preparation method thereof, and steps are as follows: step 1: a zirconium diboride target, a titanium target and a zirconium target are respectively installed on three radio frequency power sources; step 2: a substrate is subjected to impurity removal treatment and is placed on a base; step 3: a reaction chamber is vacuumized; inert gas is introduced until the pressure of the reaction chamber is 0.1 Pa; and pre-sputtering treatment is carried out; step 4: the base bias is set to 20 V, and the rotating speed is 5 rpm; the radio frequency power source provided with the zirconium target is first started, the power is set to 50 W, and a transition layer is plated on the surface of the substrate; then the other two radio frequency power sources are simultaneously started to carry out sputtering, and a preliminary composite film is obtained; and step 5: the preliminary composite film is annealed in a vacuum environment at 800 DEG C to obtain a final composite film. The hardness of the application reaches 42 GPa, the residual stress is only 0.359 GPa, and the oxidation resistance and high-temperature friction and wear resistance are simultaneously improved.

This invention discloses an electro-erosion resistant metal-based composite contact material with a gradient textured interface and its preparation process, relating to the technical field of metal-based electrical contact materials for low-voltage electrical appliances. The process includes the following steps: S1. Preparation of surface functional phase precursor: Preparing a preform containing nano-scale zirconium diboride-titanium diboride multiphase precursor clusters as an intermediate raw material for introducing the multiphase reinforcing phase; S2. Gradient preform forming: Preparing a core high-conductivity layer preform, an intermediate gradient transition layer preform, and a surface electro-erosion resistant functional layer preform respectively; wherein, the surface preform is obtained by cold pressing after mixing the surface functional phase precursor with matrix metal powder in a certain proportion. Through the core processes of asynchronous rolling pre-control and segmented gradient annealing, the material texture orientation is directionally controlled, resulting in a core high-conductivity layer. This texture exhibits the lowest lattice scattering probability and the smallest effective electron mass along the electron transport direction.

The present invention discloses a high-temperature resistant building ceramic tile and a preparation method thereof, and relates to the field of ceramic technology. When preparing high-temperature resistant building ceramic tiles, the present invention first reacts vinyl-terminated amino silicone oil and 2-amino-4-pyridinemethyl mercaptan, and then reacts with 2-(diphenylphosphine)benzaldehyde to obtain modified polysiloxane; secondly, clay and a mixed iron salt solution are mixed, and coprecipitated under the action of sodium hydroxide to obtain modified clay; finally, modified clay, magnesium trisilicate, titanium carbide, zirconium diboride, aluminum oxide, and boron nitride are mixed and ground, pressed into a blank, dried and sintered, and then sprayed with modified polysiloxane to obtain the high-temperature resistant building ceramic tile. The high-temperature resistant building ceramic tile prepared by the present invention has good high-temperature resistance and self-cleaning performance.

This invention discloses a titanium alloy composite material based on fused ring conjugated molecules and its preparation method. In the composite material, the surface of the titanium alloy is coated with a fused ring conjugated molecular film. The titanium alloy has a multilayer deposition structure, and a mixture of zirconium diboride (ZrB2) powder or V powder is coated between the layers. In this invention, the titanium alloy material is formed by multilayer deposition, and a mixture of ZrB2 powder or V powder is added between the layers. Cyclic heat treatment modification is adopted, which significantly improves the hardness value of the titanium alloy composite material. At the same time, coating the titanium alloy component with a fused ring conjugated molecular film improves the photothermal properties of the titanium alloy composite material and solves the problems existing in the existing titanium alloy materials. After the above-mentioned multi-step heat treatment process, the hardness of the titanium alloy component is increased by 64.96% compared with that before treatment. After uniformly coating the surface of the component with a fused ring conjugated molecular film, the temperature increases to 41.4 °C after 50 min of irradiation without heat treatment, and to 50.8 °C after 50 min of irradiation with heat treatment.

The invention relates to a rare earth oxide modified ceramic heat-proof material and a preparation method thereof. The rare earth oxide modified ceramic heat-proof material comprises the following components in percentage by mass: 58-78% of ZrB2, 12-30% of rare earth oxide and 10-30% of silicon carbide, the zirconium diboride is modified by the rare earth oxide, so that the work function of the ceramic composite material is reduced; the sintering time and the sintering temperature are effectively reduced by adopting a spark plasma sintering technology, and abnormal growth of crystal grains is inhibited, so that the ceramic composite material has good mechanical properties. The rare earth oxide modified zirconium diboride superhigh-temperature ceramic composite material is a heat-proof material with high-temperature resistance and low work function performance, and can meet the requirements of a novel electronic transpiration cooling thermal protection technology on a material with heat resistance and low work function.

The application provides an anti-erosion ceramic-magnesium-based composite refractory brick and a preparation method thereof, and belongs to the technical field of ceramic composite magnesium refractory bricks. Raw material components of the refractory brick include ceramic composite material, fused magnesia, boron-nitrogen-doped carbon-silane modified magnesium-aluminum spinel intermediate, fused magnesium-chromium powder, zirconium diboride, silicon powder, silicon-iron-nitride boron composite additive and the like. The boron-nitrogen-doped carbon-silane modified magnesium-aluminum spinel intermediate is prepared by coating fused magnesium-aluminum spinel powder with PEG and boron-nitrogen-doped carbon black, then modifying with a silane coupling agent, and sintering. The ceramic composite material includes tabular corundum particles, micron alumina and ZrO2@SiC whiskers. The silicon-iron-nitride boron composite additive is prepared by ball milling silicon-iron alloy powder, boron nitride powder and PEG2000. The multi-phase synergistic design breaks through the performance short board of traditional single-system refractory bricks, and realizes overall balance and balanced improvement of hardness, wear resistance, corrosion resistance, thermal shock resistance and hydration resistance.

The present invention discloses a photocurable 3D printing slurry for zirconium diboride-based ultrahigh-temperature ceramics, a printing method, and applications thereof. The photocurable printing slurry is formulated using a zirconium diboride-based ultrahigh-temperature ceramic sol-gel precursor xerogel powder. This significantly improves the curing depth of the photocurable 3D printing slurry. This facilitates the printing of high-precision, defect-free zirconium diboride-based ultrahigh-temperature ceramic green bodies. Furthermore, by optimizing the sintering temperature, the present invention can produce porous zirconium diboride-based ultrahigh-temperature ceramics.

This invention discloses a wear-resistant zirconium-aluminum-silicon composite ceramic material and its preparation method, relating to the field of wear-resistant alumina ceramic technology. The raw materials include the following parts by weight: 90 parts alumina, 15-40 parts fused silica, 10-30 parts zirconium frit, 2-8 parts zirconium diboride, 1-7 parts lithium magnesium silicate, 0.5-2.0 parts cerium oxide, and 0.3-1.5 parts yttrium oxide; the alumina includes micron-sized alumina, nano-sized alumina, and mesoporous alumina. The preparation method of the wear-resistant zirconium-aluminum-silicon composite ceramic material includes the following steps: S1. Mixing and ball-milling the raw materials according to the required proportions, and then sieving to obtain raw material powder; S2. Subjecting the raw material powder to low-temperature oxidation calcination, vacuum hot-pressing calcination, and high-temperature nitrogen calcination, respectively. The wear-resistant zirconium-aluminum-silicon composite ceramic material of this invention exhibits excellent fracture toughness and maintains good strength even at high temperatures.

The invention relates to the technical field of battery shell production, in particular to a production method of a battery aluminum shell. The invention discloses a production method of a battery aluminum shell, which comprises the following steps: carrying out melting, degassing, continuous casting and rolling forming on a 6-series aluminum alloy, and carrying out two-stage ball milling on the 6-series aluminum alloy, zirconium diboride, modified lignin and the like to obtain a composite board; after alkali washing and acid etching pretreatment, a lignin-zinc compound coating is coated and cured; after preheating, the plate is drawn through a gradient temperature mold to be subjected to hot drawing forming, and interface reaction is synchronously carried out; after the defects are subjected to laser repair welding, preheating shaping, cooling and stabilizing heat treatment are performed; and finally, a finished product is obtained through milling, polishing and other precision machining. According to the method, through phase composition construction, gradient coating and heat treatment regulation and control, the aluminum shell has a stable microstructure and optimized interface combination, the mechanical property and corrosion resistance are excellent, the process controllability is high, and the method is suitable for large-scale production of the battery aluminum shell.

The present application relates to oil and gas field resource development cementing material technical field, specifically to a kind of temperature-resistant high-thermal-conductivity external admixture for cementing cement and preparation method thereof, the temperature-resistant high-thermal-conductivity external admixture for cementing cement includes 40wt. 60wt. 30wt. 45wt. 10wt. 15wt. By percentage of weight, high-thermal-conductivity reinforcing material, reinforcing material and polyetherimide, the high-thermal-conductivity reinforcing material is the mixture formed after modification of the mixture of molybdenum disilicide, tungsten diboride, zirconium diboride, titanium diboride by mass ratio (5-7):(1-2):(1-2):1.This temperature-resistant high-thermal-conductivity external admixture for cementing cement has the characteristics of strong high-temperature resistance, high thermal conductivity, good toughness, etc., good compatibility with cement, does not affect the working performance of cementing cement slurry system, can participate in cement hydration reaction, improve the high-temperature resistance of cementing cement slurry.

The application discloses a surface coating of an induction coil of a medium-frequency welding machine and a preparation method thereof. The surface coating comprises a transition layer and a surface layer. The transition layer is composed of nickel-aluminum, aluminum oxide and coated powder in a weight ratio of 85-90:5-8:5-10. The surface layer is composed of aluminum oxide and potassium silicate in a weight ratio of 94-98:2-6. The coated powder is formed by coating zirconium diboride with calcium fluoride. The thickness of the transition layer is 30-150 microns. The thickness of the surface layer is 200-500 microns. The prepared coating has good bonding strength and insulation performance, and the preparation method is simple and efficient, and is suitable for various industrial applications.

The invention belongs to the technical field of organic silicon heat-resistant paint, and particularly relates to organic silicon heat-resistant finish paint and a preparation method thereof. The paint is prepared from the following components in parts by weight: 30 to 40 parts of phenyl silicone resin, 6 to 11 parts of functional substance, 5 to 10 parts of pigment, 5 to 8 parts of filler, 1 to 2 parts of dispersing agent BYK-333, 0.5 to 1 part of defoaming agent PMX-2005cST dimethyl silicone oil, 0.5 to 1 part of flatting agent BYK-306, 0.5 to 1.5 parts of crosslinking catalyst tetrabutyl titanate, 20 to 25 parts of solvent dimethylbenzene and 5 to 10 parts of solvent cyclohexanone. Wherein the functional substance is prepared from zirconium diboride, silicon nitride and calcium stearate. In the preparation process of the organosilicone heat-resistant finish paint, the functional substance composed of zirconium dioxide, silicon nitride and calcium stearate is added, so that the water vapor transmission rate can be reduced, and a metal base material can be protected.

The invention discloses a preparation method of a soluble ZrC / ZrB2 complex-phase ultrahigh-temperature ceramic precursor. The preparation method comprises the following steps: S1, dissolving zirconium tetrachloride in absolute ethyl alcohol, adding acetylacetone, heating and stirring to obtain a zirconium-containing precursor solution; s2, dissolving a boron source in an absolute ethyl alcohol solution, adding concentrated sulfuric acid, heating, stirring and removing moisture to obtain a boron-containing mixed solution; s3, dropwise adding the boron-containing mixed solution into the zirconium-containing precursor solution, and continuously heating and stirring to obtain a mixed solution; s4, adding a hydroxyl-containing carbon source into the mixed solution, and stirring to obtain viscous reddish brown liquid; and S5, removing redundant solvent in the reddish brown liquid, and performing vacuum drying to obtain the soluble ZrC / ZrB2 complex-phase superhigh-temperature ceramic precursor. The soluble ZrC / ZrB2 complex-phase superhigh-temperature ceramic precursor provided by the invention solves the problems of high raw material cost, high pyrolysis temperature and low solubility of the prepared precursor in a low-toxicity environment-friendly solvent in the existing preparation of the ZrC ceramic precursor.

The present invention discloses a high-strength and tough interlocking structure ZrB2 ceramic and its preparation method and application, belonging to the technical field of zirconium diboride ceramics. The method includes: first, pre-oxidizing ZrC powder and SiC powder, then mixing and ball-milling them with ZrB2 powder, and performing two-step sintering assisted by direct current to obtain a high-strength and tough interlocking structure ZrB2 ceramic. The pre-oxidized ZrC powder and SiC powder provide a process liquid phase at high temperature, and at the same time, a direct current is applied to induce anisotropic growth of ZrB2 grains and couple them into an interlocking structure, thus obtaining a high-strength and tough interlocking structure ZrB2 ceramic. The process liquid phase and the applied direct current can effectively promote the growth of ZrB2 grains into lamellar shapes, and the lamellar grains are coupled to form an interlocking structure, which not only improves the fracture toughness of ZrB2-based ceramics but also improves the strength of ZrB2-based ceramics; the process liquid phase formed at high temperature does not remain in the final ZrB2-based ceramics, improving the high-temperature mechanical properties of ZrB2-based ceramics; the preparation process is simple, with a short cycle and high efficiency, and can be mass-produced.

The invention relates to a preparation method of a high-thermal-expansion aluminum phosphate-based high-temperature adhesive. The preparation method comprises the following operation steps: preparing a high-expansion regulator from mixed boron carbide and zirconium diboride; adding silicon powder into the regulator to prepare an adhesive filler; performing hydro-thermal synthesis to obtain an aluminum phosphate gel base solution; doping zirconium hydroxide into the gum base solution to prepare an adhesive base solution; and mixing the adhesive basic solution with the filler to prepare the high-expansion aluminum phosphate-based high-temperature-resistant adhesive. According to the high-temperature adhesive disclosed by the invention, the aluminum phosphate gel base solution doped with zirconium hydroxide is used as the adhesive base solution, and the content of zirconium dioxide in the adhesive is further increased by adding zirconium diboride, so that the aim of improving the thermal expansion coefficient of the adhesive is fulfilled. The high-temperature adhesive can provide shear strength not lower than 3 MPa for ZrO2 ceramic within the treatment temperature range of RT-1500 DEG C. When the treatment temperature is higher than 600 DEG C, the shear strength of the bonding piece is increased along with the increase of the heat treatment temperature, and the shear strength of the bonding piece calcined at 1500 DEG C is 41.2 MPa. After treatment at 1500 DEG C, the thermal expansion coefficient of the calcined adhesive can reach 8.9 * 10 <-6 > K <-1 >, which is obviously improved compared with that of a commercial aluminum dihydrogen phosphate adhesive.