Preparation method of highly-textured Ti2AlN ceramics

A textured and highly advanced technology, applied in the field of preparation of highly textured Ti2AlN ceramics, can solve the problems of insignificant orientation effect, high equipment requirements, high equipment energy consumption, etc. Equipment simple effect

Inactive Publication Date: 2016-12-07
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This new technology uses heated explosive reactions to create fine particles called titanium nitride (Ti2/Al) ceramia). These tiny particles have many advantages that make it better than previous methods like other techniques such as chemical vapor deposition or physical processes used during manufacture. They also provide higher strength when they were formed by burning them together instead of separately preparation.

Problems solved by technology

This patented describes different ways for creating special types of aluminum nitride called cubic phases, including those containing titanium atoms and tantalum atom elements. These structures provide unique characteristics like being able to resist extreme temperatures without losing strength over longer periods of use compared to existing cerams made from metals alone.

Method used

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  • Preparation method of highly-textured Ti2AlN ceramics

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Step 1: Use the powder with a molar ratio of Ti:Al:TiN=1.5:1.5:1 as the initial raw material, the ball milling medium is alcohol, the ratio of material to ball is 1:2, and the speed is 300rpm. After 4 hours of ball milling, it is cold pressed and formed Thermal explosion reaction sintering is carried out in the discharge plasma sintering equipment, the sintering temperature is 650°C, and after holding for 2 minutes, it is rapidly cooled and the oxide layer on the surface of the green body is ground off, crushed and passed through a 300-mesh sieve to obtain Ti 2 AlN ceramic powder;

[0019] Step 2: Take a certain amount of Ti 2 Fill the AlN ceramic powder into a mold with a diameter of 12mm and perform discharge plasma pre-sintering in an ordinary box furnace. The initial temperature is room temperature. When the sintering temperature reaches 900°C, uniaxially pressurize to 40MPa and then cool directly;

[0020] Step 3: Put the sintered green body obtained in Step 2 int...

Embodiment 2

[0022] Step 1: Use the powder with a molar ratio of Ti:Al:TiN=1.1:1.1:1 as the initial raw material, the ball milling medium is alcohol, the ratio of material to ball is 1:3, and the speed is 400rpm. After 4 hours of ball milling, it is cold pressed and formed Thermal explosion reaction sintering is carried out in the discharge plasma sintering equipment, the sintering temperature is 700°C, after 2 minutes of heat preservation, it is rapidly cooled and the oxide layer on the surface of the green body is ground off, crushed and passed through a 300-mesh sieve to obtain Ti 2 AlN ceramic powder;

[0023] Step 2: Take a certain amount of Ti 2 Fill the AlN ceramic powder into a mold with a diameter of 12mm and perform discharge plasma pre-sintering in an ordinary box furnace. The initial temperature is room temperature. When the sintering temperature reaches 950°C, uniaxially pressurize to 30MPa and cool directly;

[0024] Step 3: Put the sintered green body obtained in Step 2 int...

Embodiment 3

[0027] Step 1: Use the powder with a molar ratio of Ti:Al:TiN=1:1:1 as the initial raw material, the ball milling medium is alcohol, the ratio of material to ball is 1:3, and the speed is 200rpm. After 4 hours of ball milling, it is cold pressed and formed Thermal explosion reaction sintering is carried out in the discharge plasma sintering equipment, the sintering temperature is 900°C, and after holding for 2 minutes, it is rapidly cooled and the oxide layer on the surface of the green body is ground off, crushed and passed through a 300-mesh sieve to obtain Ti 2 AlN ceramic powder;

[0028] Step 2: Take a certain amount of Ti 2 Fill the AlN ceramic powder into a mold with a diameter of 18mm and perform discharge plasma pre-sintering in an ordinary box furnace. The initial temperature is room temperature. When the sintering temperature reaches 1100°C, uniaxially pressurize to 50MPa and then cool directly;

[0029] Step 3: Put the sintered green body obtained in Step 2 into a...

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Abstract

Disclosed is a preparation method of highly-textured Ti2AlN ceramics. The method comprises the steps that firstly, Ti, Al and TiN powder are adopted as initial raw materials, thermal explosion reaction sintering is performed, rapid cooling is performed, an oxidation layer on the surface of a blank is rubbed away, breaking and sieving are performed, Ti2AlN ceramic powder is obtained, then, a certain amount of Ti2AlN ceramic powder is taken to be added into a mold, and discharge plasma presintering is performed, when the sintering requirement meets the requirement, single-shaft pressurization and cooling are performed, finally, the sintered blank body is placed into the graphite mold, after the temperature of a cavity to be reacted meets the requirement, single-shaft pressurization and heat preservation are performed, then, cooling is performed to the room temperature, a highly-textured Ti2AlN ceramic block is obtained, a thermal explosion reaction can be used for rapidly preparing the high-purity and small-grain Ti2AlN ceramic block, the Ti2AlN ceramic block with grains with high preferred orientation is obtained through the discharge plasma sintering technology, and the method has the advantages of being easy and convenient to implement, high in sintering speed, and suitable for large-scale production.

Description

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Claims

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Application Information

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Owner SHAANXI UNIV OF SCI & TECH
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