557 results about "Copper matrix" patented technology

The invention belongs to the technical field of preparation of electronic packaging materials, and particularly designs a copper-based composite material with high thermal conductivity and a preparation method thereof. The copper-based composite material is made of a reinforcement and a binder through a prefabricated injection molding process to make a reinforcement prefabricated part, wherein the size of the reinforcement particle is 7-60 μm, and it is composed of silicon carbide particles, diamond particles or aluminum nitride particles. One or two of them; the copper matrix is ​​directly placed on the reinforcement preform, wherein the copper matrix is ​​electrolytic copper or oxygen-free copper, and the volume ratio of the reinforcement to the copper matrix is ​​50-75%: 25-50 %, made by pressure infiltration process. The preparation method adopts the injection molding process of the prefabricated part and the pressure impregnation process to prepare the high thermal conductivity copper matrix composite material. The thermal conductivity of the copper-based composite material in the present invention is higher than that of the aluminum-based composite material with the same reinforcement system, the material itself has low density and small thermal expansion coefficient, which meets the requirement of light weight of the packaging material.

The invention provides a preparation method of copper matrix graphene alloy. The method comprises the following steps: preparing graphene and copper and/or copper alloy mixed powder, carrying out cold pressing, and carrying out sintering molding. The method improves an original preparation technology of the copper matrix graphene alloy, and has the advantages of production period and cost reduction, simple process operation, simple required device, high production efficiency, low preparation cost, and easy realization of large-scale industrialization.

The invention relates to a high heat-conducting copper-based composite material and a preparation method thereof, belonging to the technical field of electronic packaging materials. The copper-based composite material consists of 50-80 percent by volume of electroplated diamond particles and 20-50 percent by volume of copper. The electroplated diamond particles and a caking agent are mixed according to the volume ratio of 1:1-4:1 and are produced into a diamond prefabricated part by using an injection forming process of the prefabricated part; and a copper matrix is directly placed on the diamond prefabricated part or is melt and poured on the diamond prefabricated part to be produced into the high heat-conducting copper-based composite material by using a pressure infiltration process. The copper-based composite material has higher heat conductivity ratio than that of an aluminum-based composite material; by plating the surface of diamond, the interface bonding of the matrix copper and the diamond can be improved and the interface heat resistance can be reduced; in addition, the material has low density and small thermal expansion coefficient and meets the requirement for light quality of packaging materials.

A method for the fabrication of a double-sided electrical interconnection flexible circuit (200) particularly useful as a substrate for an area array integrated circuit package. A copper matrix with studs (203) is pressed through a dielectric film (201) having a copper layer on the opposite surface, thereby forming an intermediate structure for a flex circuit with self-aligned solid copper vias in a one step process. The contacts are reinforced by plating both surfaces with a layer of copper, and conventional processes are used to complete the circuit patterning.

The invention discloses preparation for the brake pad of a high-speed train via a powder metallurgy method and by taking dispersion-strengthened copper as a matrix material. According to the oxide dispersion-strengthened copper, a copper matrix is strengthened by oxide dispersion particles, and the dispersion-strengthened copper chooses dispersion-strengthened copper powder in which nanometre Al2O3 is in a ratio of 0.03-5% by weight; and the formula of the brake pad comprises 50-70wt% of dispersion-strengthened copper powder, 5-20wt% of Fe powder, 4-15wt% of (flaky) C powder, 1-10wt% of SiO2 powder, 1-7wt% of Al2O3 powder, 1-7wt% of Sn powder, 1-3wt% of Pb powder, and 1-10wt% of MoS2 powder. The dispersion-strengthened copper-based brake pad is obtained by uniformly mixing the powders in a ratio, moulding by cold-pressing, then performing pressure sintering with a steel backing. Compared with the traditional copper-based brake pad, the brake pad taking the dispersion-strengthened copper as a matrix is enhanced in matrix strength, high in thermal conductivity, good in stability, good in fatigue performance and wear resistance, and less in wear on dual discs.

The invention provides a high-conductivity high-strength copper-iron alloy and a preparation method thereof. The Fe precipitation phase in the alloy is uniformly distributed in a sub-micron level in acopper matrix, and the content of Fe is 5-25 wt%; and the conductivity is 45-60% IACS, and the tensile strength is 620-1360 MPa. The preparation method of the alloy comprises the following steps of firstly, preparing alloy powder by an atomization method; then, carrying out sintering treatment on the alloy powder, so as to obtain a sintered blank; carrying out wire drawing treatment on the sintered blank to obtain the wire material; and finally, carrying out aging treatment on the wire material to obtain the copper-iron alloy. The high-conductivity high-strength copper-iron alloy prepared cansolve the problem that iron-phase distribution in the high-strength and high-conductivity copper-iron alloy is not uniform, the sub-micron level uniform distribution of the Fe precipitation phase inthe copper matrix can be realized, and the alloy strength is improved to the maximum extent on the premise that the high conductivity of the alloy is kept.

To provide a composite material member for semiconductor device, an insulated semiconductor device and non-insulated semiconductor device using the composite material member, which are effective for obtaining a semiconductor device that alleviates thermal stress or thermal strain occurring during production or operation, has no possibilities of deformation, degeneration and rupture of each member, and is highly reliably and inexpensive. The composite material member for semiconductor device is characterized by being a composite metal plate with particles composed of cuprous oxide dispersed in a copper matrix, in which a surface of the composite metal plate is covered with a metal layer, and a copper layer with thickness of 0.5 mum or larger exists in an interface formed by the composite metal plate and the metal layer.

The invention discloses a graphene-aluminum oxide hybrid reinforced copper-based composite material. The composite material comprises 0.1-1.0 wt% of graphene, 1.0-1.2 wt% of Al2O3, and the balance copper. According to the copper-based composite material, the graphene and the aluminum oxide are adopted as complex-phase reinforcement bodies, zero-dimensional aluminum oxide particles can be effectively pinned through a special two-dimensional structure of a nano graphene sheet, a steric-hinerance effect is generated, accordingly, the agglomeration phenomenon of the particles is effectively reduced, and the particles are uniformly scattered; and the surface of the graphene is subjected to chemical nickel-plating and modification treatment, thus, the wettability and the interface bonding situation between the graphene/copper matrixes can be obviously improved, ideal interface bonding is achieved, accordingly, the synergistic effect between the graphene and the aluminum oxide particles is realized to the greatest extent, and the combination properties including strength, hardness, electrical conductivity, and friction and wear properties of the copper-based composite material are comprehensively improved.

The invention relates to a carbon nanotube-metal composite enhanced copper-based composite material and a preparation method thereof, and belongs to the field of preparation of composite materials. The preparation method comprises the following steps: preparing colloidal sol by using soluble salts containing metallic elements and copper ions and carbon nanotube as raw materials, carrying out spray granulation by using the colloidal sol through a spray dryer so as to obtain nanoscale mixed powder, calcining the mixed powder in an oxygen-free atmosphere so as to obtain black powder, reducing the black powder in a hydrogen atmosphere so as to obtain carbon nanotube-metallic element composite enhanced copper-based powder, carrying out isostatic press moulding on the mixed powder, and then sintering in the hydrogen atmosphere so as to obtain the carbon nanotube-metallic element composite enhanced copper-based composite material, wherein the content of a metallic element X in the composite material is 0.1-2wt%, and the content of the carbon nanotube in the composite material is 0.1-2wt%. The preparation method has the advantages that corresponding carbides can be formed, the problem of reinforcement agglomeration caused by poor interface bonding between reinforcement and a copper matrix is solved, and the copper-based composite material with excellent combination properties can be obtained.

The invention discloses a high-strength and high-conductivity heat-resistant Cu-Fe-Y-Mg alloy material with electromagnetic wave shielding performance and a preparation method thereof, and the copperalloy comprises Cu, Fe, Mg and Y elements; and the mass percentage of Fe is greater than or equal to 5% and is smaller than the mass percentage of Cu, and the Fe is uniformly distributed in the alloymaterial. The copper alloy uses a large amount of inexpensive iron element in the composition design; due to the immiscibility of copper and iron in the molten state, the starting alloy is mainly copper in the smelting process, a small amount of iron is added for melting, and after melting, Cu-Fe master alloy is added in a master alloy manner, alloy elements yttrium and magnesium are jointly addedin the smelting, which acts as a modificator and promotes the uniform distribution of the iron phase in the copper matrix in the solidified state, so that the alloy product finally has uniform properties, electromagnetic wave shielding performance and high strength and high thermal conductivity. The copper alloy material is suitable for non-vacuum large-scale industrial manufacturing.

The invention relates to a method for constructing a super-hydrophobic membrane on the surface of a copper matrix, and relates to a method for constructing a super-hydrophobic membrane, which solves the problems of complex steps of constructing the super-hydrophobic surface and large toxicity of raw materials in the conventional method. In the method, a sliver layer with a micro-nanometer structure is generated by replacement reaction of copper and silver nitrate, a rough surface is constructed on the copper matrix, and a self-assembly membrane is formed on a silver surface by utilizing long-chain carboxylic acid to reduce surface energy. When the method is used, the construction of the rough surface and surface modification are completed in one step, equipment and a process is simple, and the method is easy to operate; and the toxicity of the raw materials is low, and environmental pollution is small. The method is suitable for the large-scale industrial production of the super-hydrophobic membrane.

The invention relates to a high strength, high conductivity graphene/copper nanocomposite material and a preparation method and application thereof. A copper matrix of the composite material is uniformly distributed in three-dimensional nanometer scale, the scale is between 10-100 nm, preferably, 30nm-80nm; and graghene is of a three-dimensional interconnection network structure in the composite material, and the number of average layers is 1-100. The obtained graphene/copper nanocomposite material has the characteristics of high strength, high modulus and high conductivity, and can be used asvarious types of conductive materials.

The invention provides a process method for preparing an aluminide penetrating layer on the surface of pure copper or a copper alloy by combining the thermal spraying technology and the thermal treatment technology, which comprises the following steps: firstly, spraying a layer of pure aluminium coating on the surface of a copper product through arc; secondly, performing shot blasting and sealingagent coating treatment on the surface of the coating; and finally, performing thermal treatment at a temperature of between 800 and 900 DEG C, maintaining the temperature for 2 to 4 hours, and obtaining an aluminide layer over 3mm on the surface of the pure copper. The aluminide layer prepared by the method has good combination with a copper substrate, good antioxidant performance and good wear resistance. The method can prepare the aluminide penetrating layer, and also can prepare aluminium-molybdenum, aluminium-silicone, aluminium-chromium binary or multi-metallic diffusion layers.

A method for preparing tungsten-copper or molybdenum-copper high-voltage contact materials by direct forming. Firstly, the raw material powder is uniformly mixed according to the composition ratio of the high-voltage contact, and then the mixed raw material powder is input into the powder feeding system of the cold spraying system. Or spraying with heated gas, under the action of high-pressure gas, the raw material powder collides with the copper substrate to undergo plastic deformation, and then deposits on the surface of the copper base to form a high-voltage contact material, and finally the formed tungsten copper or molybdenum copper high-voltage contact material Use directly or after annealing at 1000-1400°C for 30-60 minutes. The invention simplifies the process, overcomes the high-temperature deformation of the copper base, distributes the copper solidified phase finely and uniformly, reduces the equipment cost of cold spraying, improves the safety of the working process, is suitable for online processing, and saves spraying cost.

The invention discloses a method for laser cladding Co-based alloy coating on the surface of a blast-furnace tuyere, which includes the following steps of: (1) preprocessing the surface of an air outlet of the blast-furnace tuyere; (2) praying predeposited base alloy on the surface of the air outlet; (3) before being fed into a CO2 laser, preprocessing a blast-furnace tuyere workpiece; (4) feeding powder in a backward synchronous way or a coaxial way, and then multi-pass cladding Co-based alloy powder at the work layer of the air outlet of the blast-furnace tuyere which is predeposited by the gas argon arc welding by the CO2 laser; simultaneously, protecting the region which is processed in the laser cladding way by inert gases; and (5) follow-up processing. Under the premise of not affecting the thermal conductance of the copper matrix, the method can obtain the coating with high-hardness, wear-resistance and high temperature oxidation-resistance and can make the coating firmly bonded with the matrix in a metallurgical way; therefore, the method can significantly prolong the service life of the blast-furnace tuyere. In addition, the method has the advantage of low cost and can be used in the partial restoration of a waste blast-furnace tuyere.

The invention discloses a continuous casting thermal compound device which comprises a bracket, a steel plate conveying device fixedly connected with the bracket, a sealing and heating device, an alloy metal thermal-insulation device, an alloy layer rolling and leveling device, a cooling device, a rolling roll device and an alloy melting device; an outlet at the bottom of the alloy metal thermal-insulation device is communicated with a chute runner at the top of a steel plate conveyer belt; an ultrasonic device is arranged below the chute runner; the cooling device is composed of multi-row orientated nozzles; all parts are regulated by a control system. The continuous casting thermal compound device is utilized for continuous casting and thermal compound of the copper lead alloy and the steel to produce a bimetallic bearing material; the copper lead-steel bearing material produced by the device of the invention has slender alloy structure, where the lead shows a short-shoot shape and a small part thereof has a shape of ball and is distributed uniformly on the copper matrix, without net-like structure or discontinuous net-like structure; the bearing material also has good homogeneity of structure, with relatively high bonding strength between duplex metals and stable and reliable quality.

The invention relates to a foamy carbon/copper matrix or aluminum matrix composite material with high thermal conductivity and a preparation method thereof, belonging to the technical field of electronic packaging materials. The composite material comprises 30 to 50 (v)% of foamy carbon and 50 to 70 (v)% of copper alloy or aluminum alloy, wherein, the porosity of foamy carbon is 50 to 70% and is identical with the value of the the content of copper alloy or aluminum alloy expressed as volume percent. According to the invention, a graphite die filled with foamy carbon is put in a vacuum pressure infiltration furnace, when a degree of vacuum reaches 0.01 to 1 Pa and temperature rises to be 100 to 300 DEG C higher than the melting point of the matrix, i.e., copper alloy or aluminum alloy, molten copper alloy or aluminum alloy liquid is casted into the graphite die from a medium frequency induction furnace for pressure infiltration, and the composite material is obtained after the vacuum pressure infiltration furnace is cooled and the die is removed. The composite material prepared in the invention has low density, isotropic thermal conduction performance and excellent workability, and can meet requirements of lightweight, high thermal conductivity, good dimensional stability and the like for electronic packaging materials.

The invention discloses a method for preparing a graphene reinforced copper base composite material. Uniformly mixed graphene and copper powder are covered by a thin pure copper chip; the pouring speed is not higher than 1 mm/s; the influence on the graphene dispersing process by flowing of molten copper in the pouring process is controlled; and the temperature of the poured molten copper is not lower than 1080 DEG C and not higher than 1200 DEG C. The method can prominently improve distribution of graphene in a copper matrix in the process of using a casting method to prepare the graphene reinforced copper base composite material, and enhances the material strength and hardness; the average hardness of the graphene reinforced copper base composite material in the method can reach above 80 HV; the electric conductivity under normal temperature is not lower than 80% IACS; and the heat conducting coefficient under normal temperature is not lower than 339 w/(mK).

The invention discloses a copper-based mosaic structure interface diamond coating and a preparation method and application thereof. The coating consists of a copper-diamond composite coarse sanding plating layer, a copper reinforcing layer, a copper-diamond composite thin sanding layer and a CVD diamond epitaxial growth layer from the bottom to the top. The preparation method comprises the following steps of: 1, depositing the copper-diamond composite coarse sanding plating layer, the copper reinforcing layer and the copper-diamond composite thin sanding layer on a copper matrix in turn to obtain a workpiece deposited with the copper-diamond composite plating layer; and 2, performing homogeneous epitaxial growth on the diamond exposed on the surface of the workpiece deposited with the copper-diamond composite plating layer in a CVD diamond deposition system to obtain the continuous diamond coating. The copper-based mosaic structure interface diamond coating has the advantages of high purity, few impurities, low thermal stress and firm combination with the matrix, and is an ideal choice of a microelectronic heat sink material.

The invention provides an intelligent nanometer container capable of preventing corrosion of copper and copper alloy, and preparation and application methods thereof, belonging to the technical field of corrosion prevention. Mesoporous silica microspheres with controllable particle size can be obtained by adjusting preparation conditions; by supporting a corrosion inhibitor reacting with a copper matrix, a protective film can be formed on the surfaces of copper and copper alloy thereof, so as to effectively inhibit the corrosion of the copper and copper alloy thereof; the surface of the mesoporous silica microspheres supported with large-capacity high-efficiency corrosion inhibitor is modified, and after the modified mesoporous silica microspheres are applied to an intelligent self-restoration anti-corrosion coating, not only can the compatibility of the mesoporous silica microspheres with the coating resin be further improved, but also the purpose of automatically controlling release rate of the corrosion inhibitor can be realized, and the purpose of remarkably improving the prevention effect of the common organic anti-corrosion coating and prolonging the prevention service life can be achieved. Especially when the coating is damaged, the coating has self-restoration function, and the prevention service life of the coating can be prolonged.

The invention relates to the field of preparation of two-dimensional transition-group metal carbide new materials and preparation thereof by chemical vapor deposition (CVD), particularly a high-quality ultrathin two-dimensional transition-group metal carbide crystal and a preparation method thereof. The preparation method is suitable for preparing large-area high-quality ultrathin two-dimensional transition-group metal carbides. The preparation method comprises the following steps: by using a copper foil (top layer)/transition group metal foil (bottom layer) bimetal lamination as a growth matrix, carrying out catalytic cracking on a carbon source at high temperature by a CVD technique to grow the ultrathin two-dimensional transition metal carbide crystal, and etching to remove the copper matrix, thereby obtaining the ultrathin two-dimensional transition group metal carbide crystal. The high-quality ultrathin two-dimensional transition-group metal carbide crystal has the characteristics of simple preparation technique, controllable product thickness and size and the like, and is suitable for large-area preparation, thereby laying a foundation for the research and application of the high-quality ultrathin two-dimensional transition-group metal carbide crystal in the fields of catalysis, energy storage, wear-resistant coatings, transparent conducting films, heat management and two-dimensional superconduction.

The invention relates to a method for preparing a copper-base tungsten coating through a compounded process of laser and thermal spraying. The method is characterized by comprising the following steps of: preparing a nickel base alloy transition bottom layer on the surface of a copper matrix by using a low pressure plasma coating system, and remelting the transition bottom layer with laser beams; and then preparing an intermediate transmission layer and the tungsten coating of a Ni-W alloy by using the low pressure plasma coating system, and then remelting with the laser beams to obtain the tungsten coating. By using a gradient coating structure, the method effectively solves the problem of thermal stress caused by mismatching of the coefficient of thermal expansion of the copper and the tungsten, and improves the cohesion strength of the tungsten coating and the matrix, the tungsten coating and the tungsten coating. The coating and the matrix can achieve metallurgical bonding by using the laser beam remelting, bonding property is also improved and the tungsten coating with compact surface is obtained. The tungsten coating prepared by the method has excellent anti-heat radiation and anti-thermal shock properties and is suitable to be used as heated end component materials in equipment, such as first wall material in a ray target, a rocket nozzle, an airplane nozzle throat and a nuclear fusion device.

The present invention provides a copper alloy material having high strength and a high electric conductivity, to provide a method of manufacturing a copper alloy conductor using the same, to provide a copper alloy conductor obtained by the method, and to provide a cable or a trolley wire using the copper alloy conductor. The method of manufacturing a copper alloy conductor 18 comprises the steps of: (F1) adding and dissolving In 12 of 0.1 to 0.7 weight% to a copper matrix 11 containing oxygen of 0.001 to 0.1 weight% (10 to 1,000 weight ppm) to form a molten copper alloy 14, (F2) performing a continuous casting with the molten copper alloy 14, rapidly quenching a casting material 15 to a temperature by at least 15[deg.]C or more lower than a melting point of the molten copper alloy 14, controlling the casting material 15 at a temperature equal to or lower than 900[deg.]C, and (F3) performing a plurality of hot rolling processes to the casting material 15 such that a temperature of a final hot rolling is within a range of from 500 to 600[deg.]C to form the rolled material 16.