The invention discloses a large-size
single crystal gold sheet based on polycrystalline
gold film recrystallization and a preparation method of the large-size
single crystal gold sheet, the thickness of the gold sheet is 10-100nm, the transverse size of the
single crystal gold sheet is greater than 20 microns, and the transverse size of the large-size single
crystal gold sheet is greater than 50 microns. According to the method, the single
crystal gold piece is synthesized based on polycrystalline
gold film recrystallization, the coverage rate of the single
crystal gold piece can reach more than 1000 pieces per
square centimeter, only two substances of
tetra-n-octyl
ammonium bromide and gold are involved, compared with a solution growth method, impurities are more difficult to introduce, the synthesized gold piece has fewer surface pollutants, and the quality of the gold piece is improved. The covering of another substrate plays an indispensable role in the initial
nucleation link of the gold platelets, and no gold platelets are synthesized if
nucleation cannot be carried out. And meanwhile, large-size growth is also facilitated in the subsequent growth link, so that compared with the prior art, a gold sheet with a larger size can be obtained within the same time, the
root mean square roughness of the surface of the single crystal gold sheet is smaller than 0.5 nm, the ultra-flat surface quality is achieved, and the optical loss of the single crystal gold sheet is greatly reduced.