1573 results about "Sodium oxide" patented technology

A fireproof magnesium oxide board is prepared by mixing the following raw materials, the raw material names and weight parts are as follows: 80-100 parts of magnesium oxide; 20-30 parts of anhydrous magnesium chloride; 10-20 parts of modified expanded vermiculite foaming agent; 20-30 parts of aluminum silicate fiber; 5-10 parts of sawdust; 10-15 parts of fly ash; 8-12 parts of glass magnesium board crushed powder; 1.5-5 parts of non-woven fabric; 10-20 parts of water; wherein the modified expanded vermiculite is prepared by the following steps: (1) Vermiculite is incompletely expanded and calcined; (2) acrylic acid monomer, sodium hydroxide, acrylamide monomer, initiator potassium persulfate, crosslinking aid pentaerythritol polyglycidyl ether, incompletely expanded vermiculite, and water are taken, stirred evenly and ultrasonically dispersed to obtain a first reaction solution, which is placed in a reactor for reaction to obtain a gel material; (3) the gel material is preliminarily crushed and dried, and then further crushed in a ball mill to obtain a fire-resistant expanded vermiculite with water absorption performance.

The invention provides antibacterial ceramic and a preparation method thereof. The antibacterial ceramic comprises a blank body and a glaze layer, the blank body is prepared from the following raw materials: kaolin, diatomite, montmorillonite, soapstone, bamboo charcoal powder, a first antibacterial agent, a fluxing agent, a pore forming agent, an adhesive and a reinforcing agent; the glaze layer comprises the following raw materials: kaolin, diatomite, dolomite, tourmaline, sodium oxide, a second antibacterial agent, a binder, a stabilizer and a dispersant. The method comprises the following steps: firing a molded green body by adopting stepped segmented heating, and carrying out glaze firing by adopting stepped segmented heating after glazing, thereby obtaining the antibacterial ceramic. According to the antibacterial ceramic disclosed by the invention, the antibacterial agent is added into the green body and the glaze layer, so that the influence on the antibacterial property of the green body in the firing process of the green body is avoided, the antibacterial durability is further improved, the antibacterial effect is enhanced, and the antibacterial rate on pathogenic bacteria such as escherichia coli and staphylococcus aureus reaches 99.99%.

The embodiment of the invention discloses a biological composite liquid material capable of releasing negative oxygen ions as well as a preparation method and application of the biological composite liquid material. The invention discloses a preparation method of a traditional Chinese medicine. The biological composite liquid material is prepared from 12 to 18 parts of plant extract, 1 to 4 parts of silver ion solution, 2 to 5 parts of titanium dioxide, 10 to 15 parts of nano silicon dioxide, 2 to 8 parts of sodium oxide, 1 to 6 parts of magnesium oxide dispersion liquid, 0.5 to 1.5 parts of calcium hydroxide solution, 1 to 3 parts of ferric oxide colloidal solution, 2 to 6 parts of zinc oxide dispersion liquid, 12 to 18 parts of mixed silica sol and 15 to 20 parts of nano borosilicate liquid material. 0.5-1.5 parts of a surfactant, 4-8 parts of glycerol and 10-15 parts of deionized water. The biological composite liquid material has the characteristic of efficiently releasing negative oxygen ions, can effectively improve the air quality, is good in stability, convenient to use, safe and reliable, can be widely applied to the fields of air purification, medical care, building materials and the like, and has a wide market prospect.

The invention discloses a method for preparing a composite positive electrode material by using a waste battery, and belongs to the technical field of battery recovery. The method comprises the following steps: discharging, disassembling and sorting a waste lithium iron phosphate battery to obtain a positive plate, carrying out water treatment, separating from an aluminum foil to obtain a waste lithium iron phosphate sheet, adding sodium hypochlorite, tetraethoxysilane, deionized water and hydrochloric acid, stirring to obtain SiO2-coated iron phosphate precipitate particles and a lithium-containing solution, adding sodium hydroxide into the lithium-containing solution to adjust the pH value, and carrying out solid-liquid separation to obtain the lithium-ion battery cathode material. Adding sodium carbonate, heating and drying to obtain lithium carbonate precipitate. And adding a carbon source and alcohol into the SiO2-coated iron phosphate precipitate particles and lithium carbonate, carrying out ball milling, taking out, drying, and calcining in a protective atmosphere to obtain the positive electrode composite material. Compared with the prior art, according to the prepared positive electrode composite material, material particles contain a lithium silicate network, so that the specific discharge capacity of a battery material is effectively improved. The method is simple in process and suitable for comprehensive utilization of waste batteries.

The invention discloses a method for recovering lithium phosphate from lithium iron phosphate black powder. The method comprises the following steps: mixing black powder recovered from waste lithium iron phosphate batteries with sodium persulfate, and calcining; adding water into the obtained calcined product, dissolving, filtering to obtain water extract A and leaching residues, washing the leaching residues with water, and calcining at high temperature to obtain battery-grade iron phosphate; adding a sodium hydroxide solution into the water extract A, and reacting to obtain a water extract B; adding a trisodium phosphate solution into the water immersion liquid B, fully reacting, performing suction filtration to obtain lithium phosphate and filtrate, and cleaning and drying the lithium phosphate to obtain battery-grade lithium phosphate; and freezing and denitrifying the filtrate to obtain a denitrified solution, and adding the denitrified solution into the sodium hydroxide solution for recycling. The method does not generate wastes, recycles the filtrate in the whole process, theoretically realizes zero loss of the lithium element, prevents the iron element from entering the solution, simplifies the preparation steps of the lithium phosphate, and has the advantages of cost reduction and environmental protection.

The invention discloses a preparation method of a fly ash-Al-MOF material loaded with sodium percarbonate and acid-containing ferrous sulfate, which comprises the following steps: carrying out heat treatment on fly ash, cooling, adding into a sulfuric acid solution, stirring and mixing, carrying out solid-liquid separation, adding sodium hydroxide into a liquid product to adjust the pH value to 4.5-6 to obtain an aluminum hydroxide precipitate, washing and roasting to obtain aluminum oxide, and drying to obtain the fly ash-Al-MOF material loaded with sodium percarbonate and acid-containing ferrous sulfate. The preparation method comprises the following steps: mixing fly ash-Al-MOF with a sulfuric acid solution to obtain an aluminum sulfate solution, uniformly mixing the aluminum sulfate solution with a phthalic acid solution, carrying out solid-liquid separation, washing a solid product, carrying out freeze drying to obtain fly ash-Al-MOF, and respectively loading sodium percarbonate and acid-containing ferrous sulfate on the fly ash-Al-MOF to obtain fly ash-Al-MOF loaded with sodium percarbonate and fly ash-Al-MOF loaded with acid-containing ferrous sulfate; and uniformly mixing the two components to obtain a finished product. Compared with the existing method, the material prepared by the invention can realize long-term, stable, effective and environment-friendly remediation of the organic polluted soil, and the remediation efficiency is high.

The invention relates to the technical field of thermal insulation materials, and discloses a hollow glass bead as well as a preparation method and application thereof. The hollow glass beads are prepared from the following components in percentage by weight: 40 to 65 percent of silicon dioxide, 5 to 15 percent of boron oxide, 5 to 15 percent of sodium oxide, 2 to 8 percent of cuprous oxide, 1 to 5 percent of barium oxide, 2 to 10 percent of chromic oxide, 3.5 to 7.5 percent of nickel oxide, 1.5 to 3 percent of tin oxide and 1 to 5.5 percent of silicon carbide. Cuprous oxide, barium oxide and chromic oxide have high reflection coefficients, and heat absorption of buildings can be reduced; nickel oxide, tin oxide and silicon carbide have high radiation coefficients, heat can be dissipated into outdoor air in an infrared radiation mode, and therefore the temperature of the outer surface of a building is reduced. Cuprous oxide can significantly improve the surface cleanliness of the coating and enhance the thermal insulation performance of the coating.

The invention belongs to the field of coal gangue resource utilization, and particularly discloses a method for preparing fiber-reinforced coal gangue-based composite functional aerogel. After being activated, the coal gangue is put into an acid leaching solution to be leached, and an aluminum-rich solution is obtained; adding ammonia water into the aluminum-rich solution to adjust the pH to obtain hydroxide precipitate; adding a sodium hydroxide solution into the precipitate to react to obtain a sodium aluminate solution; neutralizing the sodium aluminate solution with hydrochloric acid to obtain an aluminum chloride solution, stirring to obtain aluminum sol, and adding ceramic fibers into the aluminum sol; violently stirring the sol, and adding epoxypropane to obtain wet gel; after aging the wet gel, carrying out surface modification to obtain hydrophobic coal gangue-based aluminum oxide and composite wet gel of the hydrophobic coal gangue-based aluminum oxide; and drying the modified wet gel at normal pressure to obtain the hydrophobic coal gangue-based aluminum oxide and the composite aerogel thereof. Ceramic fibers are introduced as a reinforcing phase, so that the compressive strength and toughness of the material are improved; the composite aerogel is subjected to surface modification, uniform modification is ensured, the contact angle is remarkably increased, the hygroscopicity is reduced, and the stability of the material is enhanced.

The invention provides a method for preparing battery-grade lithium carbonate by using waste lithium iron phosphate batteries. The method comprises the following steps: step 1, discharging, disassembling and crushing the waste lithium iron phosphate batteries to obtain lithium iron phosphate battery powder; 2, adding a sulfuric acid solution and hydrogen peroxide into the lithium iron phosphate battery powder, and filtering after reaction to obtain a lithium-containing solution and ferrophosphorus slag; 3, calcium hydroxide and sodium hydroxide are sequentially added into the lithium-containing solution to remove impurities, then sodium carbonate is added, and a purified lithium solution is obtained through filtering; 4, adding an organic solvent into the purified lithium solution, fully stirring, and filtering to obtain a sodium sulfate crystal substance and an organic mixed solution; and 5, adding sodium carbonate into the organic mixed solution, fully reacting, filtering, and washing to obtain the battery-grade lithium carbonate.

The invention belongs to the field of coal solid waste resource utilization, and relates to a method for preparing a NaP type molecular sieve by utilizing kaolinite rock type coal gangue. The method comprises the following steps: 1) crushing and grinding blocky kaolinite rock type coal gangue into powder; 2) roasting and activating the coal gangue powder to obtain metakaolin; 3) mixing and stirring metakaolin, sodium hydroxide, a silicon source and deionized water to obtain an initial solution; 4) standing and aging the initial solution to obtain a precursor solution; 5) performing dynamic hydrothermal crystallization treatment on the precursor solution to obtain crystals; and 6) washing, neutralizing, centrifuging and drying the crystal to obtain the NaP type molecular sieve. The kaolinite rock type coal gangue is used as a raw material to replace a traditional chemical raw material required by molecular sieve synthesis, and resource utilization of aluminosilicate solid waste is promoted. According to the method, seed crystals or guiding agents are not required to be added in the molecular sieve crystallization process, and special crystallization methods such as microwaves and ultrasound are also not required, so that the process is simple, the cost is low, and the method is environment-friendly.

The invention provides a CO2 mineralized cementing material based on steel slag-mineral slag-fly ash multi-element solid waste and a preparation method, and relates to the technical field of building materials. The CO2 mineralized cementing material based on the steel slag-slag-fly ash multi-element solid waste is prepared from the following raw materials in parts by mass: 10 to 15 parts of steel slag, 30 to 40 parts of slag, 50 to 60 parts of slag fly ash, 5 to 20 parts of gypsum, 1 to 5 parts of clinker, 1 to 5 parts of cement, 5 to 20 parts of exciting agent, 4 to 6 parts of cross-linking agent composition, 0.1 to 0.5 part of alkaline water and 0.1 to 0.5 part of defoaming agent. According to the invention, the steel slag, the furnace slag and the furnace slag fly ash are excited by adopting a composite exciting agent of aluminum sulfate, calcium aluminate and sodium hydroxide, the problem of early strength is successfully solved through alkali excitation and aluminate excitation, the proportion of the exciting agent is reasonably configured, the effect of the exciting agent is exerted to the maximum extent, and the mechanical strength of the CO2 mineralized cementing material is improved.

The invention discloses high-toughness ultrathin flexible glass and a preparation method thereof, and relates to the technical field of glass manufacturing. The ultrathin flexible glass is prepared from the following raw materials: silicon dioxide, aluminum oxide, lithium oxide, sodium oxide, magnesium oxide, a modified nano reinforced phase, a high-temperature melting regulator and cerium dioxide. The modified nano reinforced phase is prepared by the following steps: pre-treating silicon carbide and silicon nitride with hydrochloric acid, and mixing with nano zirconium oxide to obtain a mixture; and modifying the mixture with a silane coupling agent to obtain the modified nano reinforced phase. The high-temperature melting regulator is a mixture of lithium borate, sodium sulfate and lithium fluoride. The preparation method of the ultra-thin flexible glass comprises the following steps: preparing the modified nano reinforced phase, melting and homogenizing the glass, forming the glass substrate, and preparing the ultra-thin flexible glass. The ultra-thin flexible glass prepared by the invention has relatively high fracture toughness and structural rigidity, excellent flexibility and bending fatigue durability, and excellent thermal shock resistance.

The invention discloses a gas-sensitive material for monitoring an environment-friendly gas characteristic substance CO as well as a preparation method and application thereof, and relates to the technical field of gas-sensitive materials. The preparation method comprises the following steps: dissolving tin tetrachloride pentahydrate, sodium hydroxide and polyvinylpyrrolidone, adding ammonium fluoride, reacting at 155-165 DEG C, drying the product, and calcining at 295-305 DEG C to obtain SnO2 nanoparticles; the preparation method comprises the following steps: performing ultrasonic mixing on SnO2 deionized water dispersion liquid and MoS2 nanosheet ethylene glycol dispersion liquid, and then drying to obtain the MoS2 / SnO2 composite material with a mesoporous hollow nanotube structure, and the volume ratio of ethylene glycol to deionized water is (0.9-1.1): 1. The MoS2 / SnO2 gas sensitive material has the advantages of low density, high pore volume, large specific surface area, high structural stability and the like. And when applied to a CO resistive sensor, the catalyst has good CO selectivity, high sensitivity and good long-term stability.

The invention discloses a preparation method of FeCoNiMnAl series high-entropy alloy powder with wave absorbing performance, which comprises the following steps: (1) uniformly mixing iron powder, cobalt powder, nickel powder, manganese powder and aluminum powder to obtain alloy raw material powder; (2) adding the alloy raw material powder, absolute ethyl alcohol and grinding balls into a ball milling tank, and carrying out high and low rotating speed alternate ball milling under the protection of inert gas; (3) after ball milling is finished, the alloy raw material powder obtained after ball milling is subjected to vacuum drying, grinding and smashing, and an intermediate product A is obtained; (4) adding a sodium hydroxide solution into the intermediate product A, and performing corrosion modification by adopting a water bath heating method; after the water bath is finished, washing a solid product obtained by solid-liquid separation to be neutral to obtain an intermediate product B; and (5) carrying out vacuum drying on the intermediate product B, and grinding and crushing. The FeCoNiMnAl series high-entropy alloy powder prepared by the preparation method disclosed by the invention has relatively excellent wave absorbing performance under the condition that the thickness is relatively small.

The invention belongs to the technical field of glass materials, and discloses thermal shock resistant transparent high borosilicate glass which comprises the following components in percentage by weight: 60-70% of silicon dioxide, 18-22% of diboron trioxide, 4-7% of aluminum oxide, 3-5% of magnesium oxide, 2-4% of alkali metal oxide, 0.5-1.5% of nano silicon nitride and 0.5-1% of nano aluminum titanate. The thermal shock temperature difference of the glass within the temperature change range of 20-200 DEG C is larger than or equal to 180 DEG C, the light transmittance within the visible light range of 400-760 nm is larger than or equal to 85%, the alkali metal oxide is composed of sodium oxide and potassium oxide, the weight ratio of the sodium oxide to the potassium oxide is 1: 1-3: 1, the average particle size of the nanometer silicon nitride is smaller than or equal to 100 nm, and the nanometer silicon nitride is evenly dispersed in the glass matrix; according to the thermal-shock-resistant transparent high borosilicate glass and the preparation method thereof, the thermal shock resistance and light transmittance of the glass are improved by optimizing the chemical components of the glass and adding the special nanoparticles in cooperation with a specific preparation process, and the thermal shock resistance of the glass is improved. The problems that existing high borosilicate glass is insufficient in thermal shock resistance and low in light transmittance in a high-temperature environment are solved.

The invention discloses an optical-grade PET release film and a preparation method and application thereof, and belongs to the technical field of PET release liners.The preparation method comprises the steps that organic silicon resin, polyacrylate and functional silicone oil serve as raw materials, hexadecafluorophthalocyanine copper serves as a catalyst, sodium hydroxide provides hydroxyl anions, and hydroxyl-containing fluorinated hydroxyaniline is obtained; amino groups on the surface of fluorinated hydroxyaniline react with carboxyl groups of graphene oxide and are grafted on the surface of graphene oxide, then hydroxyl groups in the fluorinated hydroxyaniline and carboxyl groups of acrylic acid are subjected to esterification reaction under the action of a catalyst, so that acrylic acid is grafted on fluorinated modified graphene oxide, and the fluorinated modified graphene oxide is obtained. Therefore, hydroxyl and epoxy functional groups on the surface of the graphene oxide are consumed, hindering of electron transmission is reduced, the conductivity of the release film is improved, and the antistatic requirement of the release film is met.

The invention relates to a method for synthesizing mordenite by using coal gangue as a raw material. The method comprises the following steps: firstly, carrying out acid treatment and activation on the coal gangue, extracting a silicon source and an aluminum source in the coal gangue as raw materials by accurately adjusting the use amount of sodium hydroxide, and finally preparing the pure-phase mordenite by accurately adjusting the content of acetic acid. The method for synthesizing the mordenite from the coal gangue is low in experiment cost, simple in process, good in repeatability and convenient for large-scale popularization to realize high value-added utilization of the coal gangue.

The present invention discloses a 3D three-dimensional glaze, which comprises the following components in percentage by weight: 45% - 60% of silicon dioxide, 17% - 25% of aluminum oxide, 1% - 2% of calcium oxide, 0.06% - 1.2% of magnesium oxide, 0.4% - 0.6% of sodium oxide, 1% - 3% of potassium oxide, 10% - 20% of zirconium oxide, 0.2% - 0.6% of zinc oxide, and 1% - 3% of boron oxide; the loss on ignition of the 3D three-dimensional glaze is 1.8% - 3.6%. The preparation method of the 3D three-dimensional glaze is to quantitatively weigh powders such as zirconium silicate, quartz powder, calcined alumina, potassium feldspar, ceramic frit powder, sodium carboxymethyl cellulose, and industrial tripolyphosphate, and then sequentially add the powders and emulsifying wax into water and stir to obtain a glaze slurry. After adjusting the viscosity of the glaze slurry, the 3D three-dimensional glaze is obtained by passing through an 80-mesh sieve. The present invention improves the adhesion of the 3D three-dimensional glaze on the surface of the green body, and when fired directly or in combination with other glazes, the three-dimensional glaze lines will not collapse, crack, have bubbles or breakpoints.

The invention belongs to the technical field of metallurgy, and particularly relates to a method for recovering valuable metals from smelting electric dust. The method comprises the following steps: S1, adding sulfuric acid, ferric sulfate and hydrogen peroxide into the smelting electric dust, and after reaction, carrying out solid-liquid separation to obtain an acidic leaching solution and acidic leaching residues; s2, sodium hydroxide is added into the acid leaching residues obtained in the step S1, the pH value of the acid leaching residues is adjusted to 13.5 or above, and alkaline leaching liquid and alkaline leaching residues are obtained after reaction; s3, sulfuric acid is added into the alkaline leachate obtained in the step S2, the pH value of the alkaline leachate is adjusted to 10.0-12.5, and neutralization liquid and lead slag are obtained after reaction; and S4, roasting the lead slag obtained in the step S3 to obtain lead oxide. According to the method, ferric sulfate is added in the acid leaching process of the smelting electric dust, leaching of arsenic can be effectively inhibited, and efficient separation and recovery of valuable metal can be effectively achieved by subsequently changing the acid-base environment of the reaction.

An ultra-thin flexible glass and its preparation method belong to the technical field of glass manufacturing. The raw materials of the ultra-thin flexible glass are composed of silicon dioxide, aluminum oxide, sodium oxide, boron trioxide, calcium oxide, lithium oxide, a composite toughening agent, a composite flux, and a composite fining agent. The ultra-thin flexible glass prepared by the present invention has an ultimate bending radius of 2-3 mm, a maximum number of bending times of 350,000-360,000 times, a surface compressive stress of 916-937 MPa, a Vickers hardness of 610-623 MPa, and an elastic modulus of 79-82 GPa.

The invention discloses a method for synthesizing a Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst by adopting a solvothermal method, and belongs to the technical field of catalysts. The preparation method comprises the following steps: preparing copper molybdenum sulfide by using cuprous oxide as a template, synthesizing copper molybdenum sulfide with high purity and good crystallinity by combining a solvothermal method, preparing manganese cadmium sulfide by using manganese acetate, cadmium acetate, sodium hydroxide and thioacetamide as raw materials, adding copper molybdenum sulfide before a hydrothermal reaction, successfully modifying the manganese cadmium sulfide by constructing a heterojunction, and preparing the copper molybdenum sulfide modified manganese cadmium sulfide. The Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst is synthesized, and the photocatalytic hydrogen production rate of the cadmium manganese sulfide is improved. Moreover, the hydrogen production rate of the Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst prepared by the invention can reach 8233 mu mol / (g.h), which is 2.08 times of the hydrogen production rate of pure cadmium manganese sulfide, and 1.24 times of the hydrogen production rate of cadmium manganese sulfide loaded with 1% platinum.

The invention discloses an acrylic pigment rod and a manufacturing method thereof. The acrylic pigment rod comprises the following raw materials: 30-60% of a solvent, 3-18% of a water-soluble adhesive, 5-15% of stearic acid, 5-20% of a sodium hydroxide solution, 8-15% of a humectant, 1-3% of a dispersant and 3-10% of a pigment. The water-soluble adhesive contains a water-soluble acrylic resin. The preparation method comprises the following steps: uniformly mixing the pigment, the dispersing agent and part of the humectant, grinding to obtain a color paste, dissolving the water-soluble adhesive in the solvent to obtain an adhesive solution, and putting the stearic acid, the sodium hydroxide solution, the humectant and the color paste into the adhesive solution to obtain a pigment semi-finished product; and pouring the pigment semi-finished product into a pen body mold, and cooling and molding to obtain the acrylic pigment rod. The manufacturing method is simple and reasonable, and the obtained acrylic pigment rod has the advantages that the acrylic pigment rod can be used for smoothly writing and drawing on various base materials, is good in covering power and soluble in water, and enables a picture to have a shading effect; and the market demand is met.

The invention discloses a preparation method and application of a Cu2O-SnO2 / g-C3N4 ternary composite photocatalytic material.The preparation method comprises the steps that firstly, carbon-nitrogen precursor powder is roasted to obtain g-C3N4 powder, then the g-C3N4 powder, tin oxide powder, a surfactant, a copper source and deionized water are evenly mixed to obtain a mixed solution, then a sodium hydroxide solution is added into the mixed solution drop by drop, the mixed solution is stirred to be uniform, and the Cu2O-SnO2 / g-C3N4 ternary composite photocatalytic material is obtained. The preparation method comprises the following steps: adding the Cu2O-SnO2 into a reaction kettle, adding ascorbic acid to obtain a mixed solution, carrying out a hydrothermal reaction on the mixed solution, cooling to normal temperature, and finally carrying out centrifugal separation, washing, drying and grinding to obtain the Cu2O-SnO2 / g-C3N4 ternary composite photocatalytic material. According to the preparation method disclosed by the invention, the three materials of Cu2O, SnO2 and g-C3N4 are used for constructing a dual-action mechanism of Z-schema and a p-n junction, so that the photocatalytic performance is effectively improved.

The present invention relates to the field of rubber materials, specifically a silicone rubber-based composite insulator for high-voltage power transmission and a preparation method thereof. A silicone rubber-based composite insulator for high-voltage power transmission and a preparation method thereof, comprising the following steps: preparation of SiC-azodicarbonamide multilayer composite filler; preparation of silicone oil stabilizer; modification of SiC-azodicarbonamide multilayer composite filler; compounding and vulcanization of methylvinylphenyl silicone rubber. The present invention uses the characteristic that dopamine forms a polydopamine film when it meets an alkali, controls the time of adding SiC after adding a sodium hydroxide solution, so that azodicarbonamide adheres to the SiC surface during the formation of the polydopamine film, and then obtains a SiC-azodicarbonamide multilayer composite filler with many pores and a large specific surface area after a layer of SiC is attached by polydopamine, which can be better filled and compounded with methylvinylphenyl silicone rubber, so that the two are fully in contact and tightly connected, and the mechanical properties and thermal conductivity of the silicone rubber composite material are improved as a whole.

The invention discloses a method for preparing a mine filling cementitious material by using cyanide tailings, comprising the following steps: weighing dried cyanide tailings, secondary aluminum ash, barium slag and phosphogypsum in proportion, and putting them into a tank mixer for mixing; after uniform mixing, adding sodium hydroxide solution for wetting, and using a tablet press to press the powder into a cubic green body, and placing the green body in an oven for drying without overlapping; putting the dried green body into a high-temperature box-type muffle furnace for calcining; adding phosphogypsum into the calcined clinker phase, crushing the green body, and sending the green body into a ball mill for ball milling treatment to obtain a cementitious material, and using tailings as aggregates, and supplemented with a polycarboxylic acid water reducer, and adding water to prepare a cementitious material for mine filling; the invention uses cyanide tailings as raw materials, and combines industrial solid wastes such as barium slag, secondary aluminum ash and phosphogypsum, and adopts a one-step activation method to prepare a cementitious material, which can simultaneously complete the decyanation and detoxification of the tailings and the activation of the tailings, has a simple process flow, and the prepared filling material has a fast hydration and hardening rate, good fluidity and high mechanical strength.

The invention discloses high-strength high-temperature-resistant fireproof industrial glass and a preparation method thereof, and relates to the technical field of glass manufacturing. The industrial glass is prepared from the following raw materials: silicon dioxide, boric oxide, aluminum oxide, sodium oxide, potassium oxide, niobium phosphate, a composite reinforcing component and a clarifying agent, the composite reinforcing component is prepared from hafnium oxide, gadolinium oxide and zinc oxide; the clarifying agent is obtained by mixing cerium dioxide and tin oxide. The preparation method of the industrial glass comprises the following steps: preparing functional components, melting glass, forming a glass substrate, and preparing the industrial glass. The prepared industrial glass is high in strength, good in high-temperature stability and excellent in fireproof performance.

The utility model relates to the technical field of carbon dioxide capture, in particular to a device for capturing carbon dioxide by using sodium hydroxide and sodium carbonate, which comprises a spray tower, a power box, a gas outlet pipe, a gas inlet mechanism and a spray mechanism, the gas inlet mechanism is arranged on the inner bottom wall of the spray tower and used for blowing flue gas into the spray tower, and the spray mechanism is arranged in the spray tower and used for spraying a sodium hydroxide solution to the flue gas entering the spray tower. And meanwhile, the spraying effect of the sodium hydroxide solution is improved through the spraying mechanism, so that the problem of relatively low spraying efficiency in the sodium hydroxide spraying process in the related technology is solved.

The invention relates to the technical field of oily sludge treatment, in particular to an oily sludge recycling-harmlessness comprehensive treatment process and equipment thereof.The oily sludge recycling-harmlessness comprehensive treatment process comprises the following steps that S1, dehydration treatment is conducted, specifically, firstly, impurities in oily sludge are removed and crushed through pretreatment equipment, so that subsequent treatment of the oily sludge is facilitated; s2, tempering treatment: adding a tempering agent, such as acetic acid, sodium hydroxide, hydrogen peroxide, calcium oxide, diatomite and polyacrylamide (PAM), into the sludge to improve the performance of the sludge, the addition amount of the sodium hydroxide is 0.5-5% of the dry weight of the sludge, the addition amount of the hydrogen peroxide is 0.5-3% of the dry weight of the sludge, the addition amount of the calcium oxide is 1-10% of the dry weight of the sludge, and the addition amount of the diatomite is 1-10% of the dry weight of the sludge; the addition amount of the diatomite is 1%-5% of the dry weight of the sludge, and the addition amount of the PAM is 0.01%-0.5% of the dry weight of the sludge. According to the oil-containing sludge treatment device, oil-containing sludge can be conveniently and rapidly pretreated through the arranged rotation adjusting device, so that impurities in the sludge can be fully treated.

The invention discloses a method for recycling iron phosphate from chemical nickel-plating waste liquid, which belongs to the technical field of industrial wastewater treatment and recycling, and comprises the following steps: S1, chemical nickel-plating waste liquid pretreatment: putting the chemical nickel-plating waste liquid into an electrolytic bath for electrolytic treatment, adding calcium salt into the electrolyzed waste liquid to remove sulfate ions, adding a sodium hydroxide solution to further remove nickel ions to obtain nickel-removed waste liquid; s2, Fenton oxidation: adding hydrogen peroxide and a surface-modified coated nano zero-valent iron Fenton catalyst into the nickel-removed waste liquid, and carrying out Fenton oxidation to obtain iron phosphate precipitate; s3, separating the iron phosphate precipitate from the wastewater; s4, electro-Fenton oxidation: finally, carrying out electro-Fenton oxidation on the cleaning wastewater and the wastewater subjected to filter pressing to obtain iron phosphate precipitate. The efficiency and purity of recovering iron phosphate from the chemical nickel-plating waste liquid are improved, and the problems of low iron phosphate recovery rate and insufficient catalyst stability in the prior art are solved.

The invention discloses a rare earth recovery method of ionic rare earth acid-soluble slag, which comprises the following steps: adding water into ionic rare earth concentrate acid-soluble slag for size mixing to obtain mixed slurry; adding a sodium hydroxide solution with the concentration of 50-100g / L into the mixed slurry for alkaline conversion, filtering and washing to obtain first wastewater and an alkaline cake; water is added into the alkali cake for size mixing, alkali cake slurry is obtained, the solid-liquid weight ratio of the alkali cake to the water is 1: (1-2), the alkali cake slurry is heated for acid dissolution, the pH is controlled to be 0.5-1.0, and a rare earth crude product solution is obtained after filtering and water washing; precipitating the rare earth crude product solution with an oxalic acid solution, filtering, and washing to obtain second wastewater and an oxalic acid rare earth mixture; and firing the oxalic acid rare earth mixture at a high temperature to obtain the mixed rare earth oxide. The process is simple in technology, short in flow, less in three wastes, stable and reliable in operation and low in cost, and the rare earth recovery rate reaches 90% or above.