The present invention relates to a gas barrier composite film for a hydrothermally processable package,
wherein at least one gas barrier layer containing a gas barrier resin and an inorganic layered compound is interposed between a base film layer and a sealing material layer, and
an adhesive layer is further formed on both sides of the gas barrier layer by applying an adhesive composition comprising: a base material mainly comprising a polyurethane resin having at least one functional group selected from the group consisting of an amino group, a hydroxyl group, and a carboxyl group; and a curing agent comprising an isocyanate curing agent and an epoxy curing agent, at the following functional group ratio:
I/P=0.3 to 30.0
E/P=1.5 to 25.0
(here, “P” represents the total number of moles of primary and secondary amino groups, hydroxyl groups, and carboxyl groups contained in the base material, “I” represents the number of moles of isocyanate groups contained in the isocyanate curing agent, and “E” represents the number of moles of epoxy groups contained in the epoxy curing agent).