491results about How to "Improve interface strength" patented technology

The invention relates to a galvanized steel sheet excellent in surface abrasion resistance, corrosion resistance and acid and base resistance and a water-based surface treating agent. The surface of a galvanized steel sheet is coated with the surface treating agent in a solidified mode, wherein the surface treating agent includes water-based positive ion polyurethane composite resin, compound organic silane coupling agents containing bis-organic silane coupling agents and mono-organic silane coupling agents, compound lubrication particles containing teflon-surface modification high-density polyethylene particles, oxidized graphene, water-soluble fluorine-containing compounds, water-soluble phosphorous compounds, water-soluble rare earth salt compounds and other components, and therefore the surface treatment galvanized steel sheet excellent in surface abrasion resistance, corrosion resistance and acid and base resistance is obtained. Meanwhile, the surface treatment galvanized steel sheet has good resistance, such as solvent resistance, to all kinds of chemical media.

The invention relates to a method for manufacturing a ceramic/metal composite structure. The method comprises the following steps: providing a ceramic substrate; coating a metal interfacial layer on the ceramic substrate; placing a copper sheet on the metal interfacial layer; and heating the ceramic substrate, the metal interfacial layer and the copper sheet to allow the metal interfacial layer to combine with the ceramic substrate and the copper sheet to form a strong bond. The invention also discloses a ceramic/metal composite structure.

Prepreg compositions and methods of making them from particles and a binder composition are disclosed. The methods may include placing the particles on a moving conveying belt and applying the binder composition to the particles on the moving conveying belt to form a moving mass. Alternate methods may include first placing the binder composition on the moving conveying belt and then applying the particles to the binding composition to form the moving mass. The methods may further include passing the moving mass through one or more pairs of opposed, compacting rolls, where the particles and the binder composition are pressed into further contact while passing through the compacting rolls to form the prepreg. The binder composition in the prepreg may include monomers and/or oligomers of a polymer that are capable of polymerizing into the polymer under polymerization conditions.

The invention discloses a stone aggregate wrapped by a microfine fibre polymer mortar thin layer and a preparation method thereof; the stone aggregate is formed by stone aggregate inner cores, an adhesive inner wrapping layer, a polymer cement mortar outer wrapping layer and an adhesive microfine fibre hair layer, wherein the adhesive inner wrapping layer and the stone aggregate are adhered firmly; microfine fibre filaments are anchored and rooted on the adhesive inner wrapping layer; and the polymer cement mortar outer wrapping layer and the adhesive inner wrapping layer are soluble mutually and can effectively form a whole body. Active powder in the polymer cement mortar outer wrapping layer contains silica fume, zeolite powder, finely-ground mineral slag, pulverized coal ash and the like, and can generate volcanic ash reaction with Ca(OH)2 crystal at the interface position of the set cement so as to generate gelled materials, and further carry out improved treatment on the weakest interfaces of set cement and the stone aggregate in concrete. The modified stone aggregate of the invention has good affinity with the set cement, and has higher binding power with the set cement.

The invention relates to a novel high-intensity high heat-resistance polypropylene modified composite material and a preparation method thereof. The novel high-intensity high heat-resistance polypropylene modified composite material comprises the following components: 49-69.4 percent of polypropylene, 10-30 percent of calcium sulphate whiskers, 5-25 percent of glass fibers, 5-15 percent of maleic anhydride grafted polypropylene, 0.1-0.2 percent of nucleating agents, 0.3-0.6 percent of antioxygen and 0.2-0.5 percent of lubricating agents. The preparation method comprises the following steps: firstly uniformly mixing all the components except the glass fibers in a mixer according to the proportion; mixing the mixture in a double-screw extruder; adding the glass fibers from a fiberglass intake of the double-screw extruder; and mixing the mixture in the double-screw extruder, extruding, cooling and pelletizing. The calcium sulphate whiskers and the glass fibers are mixed to reinforce the polypropylene; in addition, with the special structure of the calcium suhphate whiskers, not only the intensity and the heat-resistance of the polypropylene modified material can be enhanced, but also the size stability and the surface finish of products can be improved, and the application field of the polypropylene modified material can be enlarged.

The application of the invention discloses a preparation method of a polypropylene nano composite material, which comprises the following steps of: (1) proportionally fusing and blending inorganic nano particles and maleic anhydride grafted polypropylene on an internal mixer, an open mill or a screw extruder to obtain a reinforcing agent master batch; (2) proportionally fusing and blending a beta crystal type nucleating agent and the maleic anhydride grafted polypropylene on the internal mixer, the open mill or the screw extruder to obtain a flexibilizer master batch; and (3) proportionally diluting and dispersing the reinforcing agent master batch and the flexibilizer master batch in a polypropylene high-polymer substrate, and carrying out injection molding to obtain the polypropylene nano composite material. With the preparation method, the technical problem that the nano particles and the nucleating agent agglomerate in the polypropylene substrate is well solved; when the flexibility of the modified polypropylene material is greatly improved, strength, rigidity, heat deflection temperature and other parameters are also improved to a certain extent, and simultaneously the density of the material is hardly increased so that a series of high-strength, high-flexibility and high-heat resistance modified polypropylene materials can be prepared.

The invention relates to a concrete pavement material for heavy traffic roads and a preparation method thereof. The material is composed of a component A, a component B and a component C in a mass ratio of 1:(0.2-0.6):(4-8). The component A comprises the following components in parts by mass: 40-80 parts of epoxy resin, 0-20 parts of epoxy reactive diluent, 10-50 parts of elastic modifier, 0.2 part of defoaming agent and 0.2 part of dispersing agent. The component B comprises the following components in parts by mass: 100 parts of curing agent, 0-10 parts of curing accelerator and 1 part of coupling agent. The component C comprises the following components in parts by volume: 100 parts of fine stone, 30-300 parts of fine sand, 130-800 parts of waste rubber particle, 50-100 parts of waste rubber powder and 10-20 parts of crystal whisker. Compared with the prior art, the concrete pavement material for heavy traffic roads has the advantages of high strength, favorable durability, favorable roadability, energy saving, environment friendliness and the like, and is convenient for construction.

The present invention provides polymeric substrates comprising a biocompatible coating and methods of preparation thereof. In particular, the coating may be a ceramic material, especially a calcium phosphate material, which may be functionally graded. The invention provides the ability to apply high quality coatings to polymeric substrates without damaging the substrate (e.g., melting the polymeric material). The functionally graded coating can provide crystalline calcium phosphate near the coating interface with the substrate and provide amorphous calcium phosphate at the outer surface of the coating.

The invention belongs to the technical field of nano materials, and in particular relates to a method for preparing a hybrid composite material of carbon fibers/carbon nanotubes/bismaleimide resin. The method comprises the following steps: after carboxylating, acylating and chlorinating the surfaces of purified carbon nanotubes and dried carbon fibers, introducing diamine or polyamine with a feature structure thereon, wherein a large amount of the diamine or the polyamine are jointed on the surfaces of the carbon nanotubes and the carbon fibers; performing an addition reaction on the carbon nanotubes jointed with the amidogen and the bismaleimide resin to obtain a carbon nanotubes-containing bismaleimide resin linear block polymer serving as a substrate; and compositing the substrate and the carbon fibers in a certain mode to form a multi-dimensional hybrid composite material structure linked by covalent bonds finally. The method has the advantages of strengthening and toughening bismaleimide by using the strength and the toughness of the carbon nanotubes, improving the bonding strength between the bismaleimide and the carbon fiber substrate surface, improving overall performance of the multi-dimensional hybrid composite material of the carbon fibers/the carbon nanotubes/ the bismaleimide resin, and widening the application of the carbon fibers, the carbon nanotubes and the bismaleimide resin.

The invention relates to high-strength lightweight aggregate concrete and a preparation method thereof, and belongs to the technical field of building material concrete. The lightweight aggregate concrete is prepared from the following raw materials in parts by weight: 105-118 parts of cement, 180-185 parts of light coarse aggregate, 120-125 parts of fine aggregate, 65-70 parts of mineral admixtures, 9-24 parts of modified polypropylene fiber, 3.4-3.8 parts of concrete admixtures and 65-70 parts of water. The preparation method comprises the following steps that the raw materials are weighed according to the formula ratio, the light coarse aggregate is added into water accounting for one half of the total water amount for pre-wetting for 45-60 minutes, then the fine aggregate is added, stirring is carried out for 1-2 minutes, the cement, the mineral admixtures and the modified polypropylene fiber are continuously added, uniform stirring is carried out, then the concrete admixtures andthe rest water are added, and uniform stirring is carried out so as to obtain the high-strength lightweight aggregate concrete. The high-strength lightweight aggregate concrete and the preparation method thereof have the advantages that the strength is high, and the quality is stable.

Disclosed is a structure and method for forming a structure including a SiCOH layer having increased mechanical strength. The structure includes a substrate having a layer of dielectric or conductive material, a layer of oxide on the layer of dielectric or conductive material, the oxide layer having essentially no carbon, a graded transition layer on the oxide layer, the graded transition layer having essentially no carbon at the interface with the oxide layer and gradually increasing carbon towards a porous SiCOH layer, and a porous SiCOH (pSiCOH) layer on the graded transition layer, the porous pSiCOH layer having an homogeneous composition throughout the layer. The method includes a process wherein in the graded transition layer, there are no peaks in the carbon concentration and no dips in the oxygen concentration.

The invention discloses a making method of clay modified by silane coupling agent with butadiene styrene rubber nanometer composite material, wherein the silane coupling agent is gamma-aminotriethylene silane and di-(gamma-triethylene propyl) tetrasulfide, which comprises the following steps: making gamma-aminotriethylene silane modified clay liquid suspension under normal temperature; blending with butylbenzene rubber emulsion completely; flocculating; washing; drying; fusing; sulfurizing to obtain the product; adding di-(gamma-triethylene propyl) tetrasulfide to obtain the modified clay and butadiene styrene rubber nanometer composite material of gamma-aminotriethylene silane and di-(gamma-triethylene propyl) tetrasulfide.

The invention discloses a functional gradient cement-based composite material enhanced by a nano material and a preparation method thereof. The composite material is composed of two or more of high-strength mortar, high-strength crude aggregate concrete, the fiber-enhanced super-high performance concrete, and the fiber-enhanced crude aggregate concrete according to isopyknic ratio. The nano material is doped into the composite material, an aperture and a gap of a gelling system can be filled with the material taken as a micro aggregate, the hydration rate at an early stage of cement paste is increased; at the same time, the gradient design is employed, by aiming at out-phase in the composite material and an interface in a functional zone, the performance of the cement-based composite material is effectively improved, and the functional gradient cement-based composite material is prepared, and the performances of intensity, toughness, impact resistance, penetration resistance, and blast resistance are greatly increased.

The invention relates to a preparation method of a multicomponent-modified carbon-fiber-reinforced epoxy resin composite material, which comprises the following steps: oxidizing carbon nanotubes (CNTs) with strong acid; carrying out acyl-chlorination and amination on the oxidized CNTs sequentially with thionyl chloride and diamine to introduce amino functional group; oxidizing carbon fiber with strong oxidizing acid, and carrying out acyl-chlorination treatment with thionyl chloride to introduce acyl chloro group; mixing the prepared modifying CNTs and modifying carbon fiber to perform graft reaction, thereby obtaining the CNTs-grafted carbon fiber; mixing the CNTs-grafted carbon fiber with polyhedral oligomeric silsesquioxane (POSS) to perform graft reaction, thereby obtaining the binary POSS-grafted carbon fiber; and sufficiently infiltrating the binary POSS-grafted carbon fiber in the base resin, and carrying out hot pressing to perform curing formation. The CNTs and POSS cografted on the carbon fiber surface can improve the surface topography of the carbon fiber, increase the contact area with the resin base and penetrate into the resin base under the anchoring action, so that the interfacial mechanical mesh action is higher.

The invention discloses a polyamide composite material which comprises, by weight, 20.0% to 40.0% of polyamide 6 with a low viscosity, 10.0% to 30.0% of polyamide 6 with a medium viscosity, 5.0% to 20.0% of a polar low temperature impact modifier, 1.0% to 8.0% of a wear-resisting agent, 0.2% to 5.0% of a heat stabilizer, 0.5% to 5.0% of a lubricant and 20.0% to 45.0% of a reinforcing component. The material has excellent performance and is especially applicable to preparation of cable rollers. The invention also discloses a preparation method for the polyamide composite material. According tothe method, polyamide 6 with a low viscosity, polyamide 6 with a medium viscosity, the low temperature impact modifier, the wear-resisting agent, the heat stabilizer and the lubricant are stirred anduniformly mixed; an obtained mixture is added into a double-screw extruder, and the reinforcing component is added into the double-screw extruder to prepare the polyamide composite material. The method has the advantages of simple operation and suitability to industrial production.

The invention relates to a preparation method of a glass fiber/carbon nanotube/epoxy resin multi-dimensional hybrid composite material. The preparation method provided by the invention comprises the following steps of: treating glass fiber with a silane coupling agent; carrying out surface carboxylation and chlorination on carbon nanotubes, then introducing diamine or polyamine to the carbon nanotubes, and modifying the carbon nanotubes connected with an amino group by a polybasic anhydride compound to prepare the carbon nanotubes carrying an anhydride group; dispersing the treated carbon nanotubes in an epoxy resin matrix by ultrasonic oscillation and high-speed stirring, and curing with an organic anhydride curing agent; and compounding the obtained carbon-nanotube-containing epoxy resin polymer used as a matrix with the coupling-agent-treated glass fiber to form a multi-dimensional hybrid composite material structure linked through covalent bonds. The preparation method provided by the invention has the advantages that: the composite material is convenient to prepare, the dispersion of the carbon nanotubes in epoxy resin is improved, and the strength and toughness of the carbon nanotubes are utilized to toughen epoxy resin and to improve the bonding strength with the base surface of the glass fiber, thereby enhancing the overall performance of the glass fiber/carbon nanotube/epoxy resin multi-dimensional hybrid composite material and broadening the applications of the glass fiber, carbon nanotubes and epoxy resin.

The invention relates to high modulus cold-mixed asphalt as well as a preparation method and a mixture thereof. The asphalt composition comprises the following components in parts by weight: 58-60 parts of petroleum asphalt, 1.5-3.0 parts of a polymer, 1.5-2.5 parts of a compatilizer, 1.0-2.5 parts of an emulgator and 0.3-1.2 parts of an interface repairing agent. The emulgator is in a twin structure with a polar group and a nonpolar group. According to the technology provided by the invention, the modulus of the emulsified asphalt cold-mixed mixture and the cold-recycling mixture is improved, and the mixture can be used as a material of a base layer, a lower surface layer and a middle surface layer of a newly constructed road and a reorganized and expanded road or used for structural repair of high-grade highways, thereby finding a convenient, energy-saving and environment-friendly solution capable adopting 100% reclaimed materials for structural repair of high-grade highways. With the adoption of the scheme of quick setting, the construction time is shortened and the cost is saved.

The invention discloses a high-performance long glass fiber-reinforced TPU (thermoplastic polyurethane) composite material. The composite material comprises the following components in parts by mass: 35-75 parts of thermoplastic polyurethane elastomer, 20-60 parts of long glass fiber, 3-8 parts of compatilizer, 0.4-1.5 parts of flow modifier, 0.2-0.5 part of chain extender, 0.4-0.6 part of heat stabilizer and 0.4-0.6 part of ultraviolet absorber. According to the composite material, TPU with high surface hardness is taken as the base material, the flow modifier is used for improving the fluidity of the matrix, the chain extender is added for improving the molecular weight of TPU so as to prepare the high-performance long glass fiber-reinforced TPU composite material, the strength and rigidity of the TPU material are improved, the toughness of the TPU material is improved, and the cost of the material is lowered. The preparation method is simple, is simple and convenient to operate, has high benefit, and is applicable to industrial production.

The invention relates to the technical field of foaming materials, and discloses a degradable foaming material and a preparation method thereof. The degradable foaming material is prepared from, by mass, 30-80 parts of poly(butylene adipate-co-terephthalate); 10-40 parts of polylactic acid; 10-40 parts of modified starch; 1-2 parts of a chain extender; 0.1-2 parts of a plasticizer; 1-4 parts of an assistant crosslinker; 0.1-1.5 parts of an antioxidant; 0.1-1.5 parts of a lubricant and 3-20 parts of a foaming agent. By blending and modifying PLA through PBAT, on one hand, the melting point of PLA can be remarkably reduced, the melt extrusion temperature during subsequent coiled material extrusion is further reduced, decomposition of a chemical foaming agent is inhibited, and decomposition of the foaming agent is completely controlled in the foaming stage of a high-temperature foaming furnace; and on the other hand, the advantages and disadvantages of PBAT and PLA materials are combined, and the degradable foaming material with excellent ductility, tensile strength and comprehensive performance is obtained.