Surface modification method for waste rubber powder

A technology of waste rubber powder and surface modification, applied in plastic recycling and recycling technology, etc., can solve the problems of lower concrete strength, lower concrete compression and bending strength, large differences in physical and chemical properties, etc., to improve mechanical properties and durability. The effect of improving the interfacial bonding strength and improving the interfacial compatibility

Active Publication Date: 2018-02-09
SHANXI PROVINCIAL RES INST OF COMM
View PDF3 Cites 19 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing cement concrete pavement is highly brittle, has weak impact resistance, and is prone to cracks under the action of internal stress (temperature stress and humidity stress). Waste rubber mixed into cement concrete can form a structural deformation center that absorbs strain energy, significantly improving the concrete Excellent brittleness and impact resistance, reducing various diseases caused by internal stress
[0004] However, the incorporation of rubber will lead to a significant decrease in the compressive and bending strength of concrete. The main reasons are: the rubber material is an organic material with poor hydrophilicity; the cement paste is an inorganic material with strong hydrophilicity, and the physical and chemical properties of the two are quite different. , poor compatibility, and weak interfacial adhesion, resulting in a significant decrease in concrete strength, hindering the large-scale application of rubber concrete in pavement engineering
[0005] At present, many scientific researchers mainly use NaOH solution, NaCl solution, water, CCl 4 solution, polymer emulsion, polyacrylamide, polyvinyl acetal, silane coupling agent, etc. to modify the surface of rubber powder to improve the interfacial compatibility and interfacial bonding strength between rubber powder and cement slurry. Improve the strength of rubber concrete, but when using the above treatment method, with the increase of rubber content, the decrease of concrete bending strength is still obvious

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Surface modification method for waste rubber powder
  • Surface modification method for waste rubber powder

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A new method for surface modification of waste rubber powder, which comprises the following steps: (1) treating the surface of waste rubber powder with clear water; (2) treating the surface of waste rubber powder with an alkaline solution; (3) treating the surface of waste rubber powder with a coupling agent; (4) nano-silica coating treatment on the surface of waste rubber powder; (5) crushing treatment of modified waste rubber powder aggregates.

[0026] The waste rubber powder is 100 mesh superfine rubber powder. Surface clean water treatment of the waste rubber powder: Soak the waste rubber powder in clean water with constant stirring for 20 minutes, and then dry it. The alkaline solution treatment on the surface of the waste rubber powder: Soak the waste rubber powder in a NaOH saturated solution for 4 hours, then rinse it twice with clean water, and then dry it. The waste rubber powder surface coupling agent treatment: the silane coupling agent KH550 is made into ...

Embodiment 2

[0029] A new method for surface modification of waste rubber powder, which comprises the following steps: (1) treating the surface of waste rubber powder with clear water; (2) treating the surface of waste rubber powder with an alkaline solution; (3) treating the surface of waste rubber powder with a coupling agent; (4) nano-silica coating treatment on the surface of waste rubber powder; (5) crushing treatment of modified waste rubber powder aggregates.

[0030] The waste rubber powder is 150 mesh superfine rubber powder. Surface clean water treatment of the waste rubber powder: Soak the waste rubber powder in clean water with constant stirring for 30 minutes, and then dry it. The alkaline solution treatment on the surface of the waste rubber powder: Soak the waste rubber powder in a NaOH saturated solution for 6 hours, rinse it with clean water for 3 times, and then dry it. The waste rubber powder surface coupling agent treatment: the silane coupling agent KH560 is made into...

Embodiment 3

[0033] A new method for surface modification of waste rubber powder, which comprises the following steps: (1) treating the surface of waste rubber powder with clear water; (2) treating the surface of waste rubber powder with an alkaline solution; (3) treating the surface of waste rubber powder with a coupling agent; (4) Silicon dioxide coating treatment on the surface of waste rubber powder; (5) Crushing treatment of modified waste rubber powder aggregates.

[0034]The waste rubber powder is 200 mesh superfine rubber powder. The surface water treatment of the waste rubber powder: the waste rubber powder is soaked in clean water and treated with constant stirring for 40 minutes, and then dried. The alkaline solution treatment on the surface of the waste rubber powder: Soak the waste rubber powder in a NaOH saturated solution for 8 hours, rinse it with water for 3 times, and then dry it. The waste rubber powder surface coupling agent treatment: the silane coupling agent KH570 i...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
bleeding rateaaaaaaaaaa
bleeding rateaaaaaaaaaa
Login to view more

Abstract

The invention belongs to the technical field of high polymer materials and particularly relates to a surface modification method for waste rubber powder. The method comprises the following specific steps: firstly, carrying out clear water treatment on the surface of the waste rubber powder; secondly, carrying out alkaline solution treatment on the surface of the waste rubber powder; thirdly, carrying out coupling agent treatment on the surface of the waste rubber powder; fourthly, carrying out nano-silica coating treatment on the surface of the waste rubber powder; fifthly, carrying out crushing treatment on the modified waste rubber powder aggregate. Compared with the prior art, the surface modification method of the waste rubber powder disclosed by the invention, has the advantages thatthe comprehensive mechanical properties of the waste rubber powder as well as interfacial compatibility and interfacial bonding strength between the waste rubber powder and cementing materials such asepoxy resin and cement paste can be significantly improved.

Description

technical field [0001] The invention belongs to the technical field of polymer material modification, and in particular relates to a method for modifying the surface of waste rubber powder. Background technique [0002] With the rapid development of the global automobile industry, the number of waste tires is increasing, and waste tires are difficult to decompose in the natural environment for hundreds of years, seriously affecting the safety and beautification of the environment. How to efficiently and rationally utilize waste tires has become an important issue to be solved urgently by countries all over the world. [0003] It is a very promising disposal method to crush waste tires into rubber powder and mix it into concrete to prepare rubber concrete and use it in highway pavement engineering. The existing cement concrete pavement is highly brittle, has weak impact resistance, and is prone to cracks under the action of internal stress (temperature stress and humidity st...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08J11/16C08J11/06C08L19/00
CPCC08J11/06C08J11/16C08J2319/00Y02W30/62
Inventor 舒兴旺李登华刘哲申力涛张影崔东霞林浩
Owner SHANXI PROVINCIAL RES INST OF COMM
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products