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Preparation method for graphene aerogel

The invention discloses a preparation method for graphene aerogel. The method comprises the following steps: preparing an aqueous polyvinyl alcohol solution containing graphene oxide so as to obtain a graphene oxide dispersion liquid with a concentration of 1 to 10 mg / cm<3>; subjecting the graphene oxide dispersion liquid to freezing in the condition of no higher than minus 196 DEG C so as to obtain a frozen sample; subjecting the frozen sample to freezing and drying so as to obtain a frozen-dried sample; and subjecting the frozen-dried sample in an argon-hydrogen mixed gas environment to high-temperature reduction so as to obtain the required graphene aerogel, wherein the high-temperature reduction comprises the steps of burning at 350 to 450 DEG C for 2 to 3 hours and burning again at 900 to 1100 DEG C for 2 to 3 hours. The preparation method for the graphene aerogel provided by the invention adopts a liquid nitrogen freezing manner to obtain a graphene oxide aerogel precursor, the subsequent segmented high-temperature reduction process is combined, the frozen-dried sample undergoes high-temperature burning at different temperatures, polyvinyl alcohol is removed and graphene oxide is reduced at high temperature, so the graphene aerogel is finally obtained; meanwhile, the graphene aerogel obtained by using the method in the invention has stable structure, good homogeneity and stable material performance.
Owner:BEIJING BORGWARD AUTOMOBILE CO LTD
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