The present invention relates to the technical field of new
biomass materials, and in particular to a preparation process of a novel bio-based
cardanol side chain modified
polyfluorene luminescent material. The process steps are as follows: 2,7-dibromofluorene and 1,3-
dibromopropane are stirred and mixed at 70-80°C to generate 2,7-dibromo-9,9-bis(3-bromopropyl)-9H-
fluorene (1); 2,7-dibromo-9,9-bis(3-bromopropyl)-9H-
fluorene (1) and 2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9,9-di-n-octylfluorene (2) are stirred and mixed at 95-105°C for 48h in a
nitrogen environment to generate 9,9-bis(3-bromopropyl)-7,7'-dimethyl-9'9'-dioctyl-9H,9'H-2,2'-bifluorene (3); finally, 9,9-bis(3-bromopropyl)-7,7'-dimethyl-9'9'-dioctyl-9H,9'H-2,2'-bifluorene is mixed with a novel
polyfluorene luminescent material additive (4) to generate a novel
polyfluorene luminescent material 7,7'-dimethyl-9,9-dioctyl-9'9'-bis(cardanoloxypropyl)-9H,9'H-2,2'-bifluorene (5). The preparation process of the present invention improves the material properties of the novel
fluorene derivative
polymer.