395 results about "Oxygen atom" patented technology

The invention discloses a zinc-bromine flow battery multifunctional negative electrode electrolyte and a preparation method thereof, and belongs to the technical field of electrochemical energy storage, and the method comprises the following steps: uniformly stirring and mixing a solvent, deionized water and a cosolvent, adding an electrolyte, stirring until the electrolyte is completely dissolved, then adding a supporting electrolyte and a negative electrode additive, stirring until the supporting electrolyte and the negative electrode additive are completely dissolved, and obtaining the zinc-bromine flow battery multifunctional negative electrode electrolyte. The multifunctional negative electrode electrolyte of the zinc-bromine flow battery is obtained; the negative electrode cosolvent is dimethylformamide; and the negative electrode additive is at least one of saponin and cinnamyl aldehyde. Saponin molecules are adsorbed on the surface of the zinc electrode, and electronegative carboxyl groups of the saponin molecules form an electrostatic repulsion net in an electric double layer, so that zinc ions are forced to be uniformly dispersed, local ion concentration hot spots are eliminated, and dendritic crystal nucleation is inhibited from the source. In cinnamyl aldehyde, the strong electronegativity of oxygen atoms and the electronegativity of aldehyde oxygen are far higher than those of hydrogen, so that electrons are strongly attracted, adjacent carbon atoms are positively charged, polar adsorption sites are formed, the hydrogen evolution reaction is effectively inhibited, and the stability and the cycle life of the battery are greatly improved.

The invention provides a crystal pulling method for improving the BMD defect density in monocrystalline silicon and a monocrystalline silicon rod, and belongs to the technical field of monocrystalline silicon crystal pulling, and particularly relates to the following steps: stabilizing the oxygen content in a crystal in a relatively high interval by cooperatively regulating and controlling the argon flow, the furnace pressure, the crucible rotating speed, the crystal rod rotating speed and the pulling speed, providing a sufficient oxygen source for generation of BMD defects, and improving the BMD defect density in the monocrystalline silicon on the basis of stabilizing the oxygen content in the crystal in a relatively high interval. In the equal-diameter process, temperature compensation is carried out on a crystal bar through a preset temperature compensation device, diffusion and precipitation of oxygen atoms are effectively promoted to form BMD crystal nucleuses, the BMD body defect density and the axial distribution uniformity are remarkably improved, the specification lower limit of the BMD density is promoted to be improved to 1.0 E + 11 ea / cm < 3 > or above, the internal gettering capacity of a silicon wafer is finally enhanced, and the service life of the silicon wafer is prolonged. And a reliable guarantee is provided for improving the performance and yield of the device.

The utility model discloses a safety type active water molecule electrolysis device which comprises a shell with an air flow channel, a membrane electrode assembly is arranged in the shell, the membrane electrode assembly divides the air flow channel into an air inlet end and an air outlet end, the anode side of the membrane electrode assembly faces the air inlet end, the cathode side of the membrane electrode assembly faces the air outlet end, and the air outlet end faces the air outlet end. The air inlet end is provided with a pure iron foil for air flow to pass through, the pure iron foil absorbs oxygen generated by electrolyzing water molecules on the anode side of the membrane electrode assembly, and the exhaust end is provided with an ePTFE microporous breathable protective film. Through the mode, the safe active water molecule electrolysis device and equipment can absorb oxygen in the equipment, so that the oxygen content is in a lower state, the corrosion damage of oxygen-enriched atoms is avoided, and the spontaneous combustion risk caused by over-high internal oxygen concentration is avoided.

The invention discloses a method for improving the oxidation resistance of nickel-based superalloy, and belongs to the technical field of metal material surface modification. Based on the high-energy transient effect of laser shock waves, the method mainly comprises the key steps of alloy surface pretreatment, laser shock peening process implementation, post-treatment and the like. Specifically, firstly, the surface of the nickel-based single crystal alloy is subjected to pretreatment such as polishing and cleaning, surface defects and pollutants are removed, and the treatment quality is guaranteed; then, according to the material characteristics and performance requirements of the nickel-based single crystal alloy, laser parameters such as laser energy, pulse width and light spot diameter are accurately set, and proper restraint layer and absorption layer materials are selected; then, high-energy pulse laser is utilized to irradiate the absorption layer, high-temperature and high-pressure plasma is induced to be generated, the plasma expands and explodes to generate strong shock waves, the shock waves act on the alloy surface, the surface material is subjected to severe plastic deformation, a residual compressive stress layer with the depth capable of reaching hundreds of micrometers is formed, meanwhile, surface grains are refined, and the microstructure is optimized; and after the strengthening treatment is completed, simple cleaning and performance detection post-treatment are carried out. Through laser shock strengthening, a special organization structure with high density and low defect density is formed on the surface of the nickel-based single crystal alloy, diffusion and invasion of oxygen atoms are effectively hindered, and the oxidation resistance of the alloy is remarkably improved. According to the method, the controllability of technological parameters is high, the strengthening effect can be accurately regulated and controlled, the treatment process is free of pollution and high in efficiency, the obtained strengthened nickel-based single crystal alloy can be widely applied to the fields such as aerospace engine hot end parts and nuclear energy equipment which have strict requirements for high-temperature oxidation resistance, the reliability of related parts is greatly improved, and the service life of the related parts is greatly prolonged.

A negative electrode material for secondary battery use includes silicon-containing particles and coating layers covering at least part of the surfaces of the silicon-containing particles. The silicon-containing particles each include an ion conductive phase and silicon phases dispersed in the ion conductive phase. The coating layers contain at least one phosphate compound selected from the group consisting of a phosphate compound, a polyphosphate compound, and a metaphosphate compound, each of which contains an anion represented by general formula (1):In general formula (1), A represents an organic group or an oxygen atom.

The invention discloses a compound and a preparation method thereof and an electronic device, the molecular structure general formula of the compound is shown in the specification, R is selected from one of the following structures, X1-X2 are respectively and independently selected from one of oxygen atoms, sulfur atoms, selenium atoms and nitrogen atoms, and X is a positive integer. X < 3 > to X < 4 > are respectively and independently selected from one of the following structures; and X < 5 > to X < 6 > are respectively and independently selected from any one of alkyl groups. According to the compound provided by the invention, the electron pushing and pulling capability in the compound is adjusted by changing the structures of a donor and an acceptor, so that the purpose of regulating and controlling molecular electron cloud distribution and energy level is achieved, and key physical properties such as emission wavelength, radiative transition rate (kr) and backlash crossing rate (kRISC) of a material are systematically regulated and controlled. The compound as a guest material of a luminescent layer has good comprehensive performance when being applied to organic electroluminescent devices for solution processing and vacuum evaporation.

The invention discloses a silicon spiro compound as well as a preparation method and application thereof. The silicon spiro compound has the following structural formula, the X group and the Y group are respectively and independently selected from any one of an oxygen atom, a carbonyl group, a sulfinyl group, a sulfuryl group, a substituted or unsubstituted C1-C6 alkylene group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C2-C10 cyano group and an aryl group; the silicon spiro compound provided by the invention is suitable for being used as an additive of a lithium ion battery electrolyte, the stability and cycle life of a lithium ion battery can be obviously improved, the reaction condition is mild, and the product purity and yield are high.

The invention relates to the technical field of batteries, and particularly discloses a composite current collector and a preparation method and application thereof. The composite current collector comprises a thin film substrate, and a phosphorus-containing monomer is introduced into the surface of the thin film substrate through plasma treatment; an aluminum conductive layer disposed on at least one side surface of the film substrate; the surface functional layer is arranged on the surface of one side, far away from the thin film substrate, of the aluminum conducting layer, and the surface functional layer comprises a fluorine-containing polymer layer and a nanotube composite layer which are sequentially arranged from inside to outside. Phosphorus-containing monomers (phosphoric acid groups and ester derivatives thereof) are introduced to a film substrate, oxygen atoms or hydroxyl groups in key functional groups of the phosphoric acid groups and the ester derivatives thereof interact with metal ions strongly to form coordinate bonds to enhance the interface bonding force between an aluminum conductive layer and a PET film, and a surface functional layer is combined to block electrolyte permeation, so that the film has a good anti-corrosion effect. And the nanotubes in the surface functional layer form a three-dimensional conductive network, so that the contact resistance is reduced, and the conductivity is enhanced.

As a charge-transporting varnish for forming a charge-transporting thin film with excellent hole transport properties, a charge-transporting varnish is provided, comprising copper halide (I) or pseudo-copper halide (I), one of an amine selected from formulas (1) to (3), SiO2 nanoparticles, and a solvent. (where R...) 1 ~R 4 Each can independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. L represents an alkylene group having 3 to 8 carbon atoms, and oxygen atoms may be present between the carbon atoms in the aforementioned alkylene groups. However, there must be at least 3 carbon atoms between H₂N⁻ and -OH. R 5 ~R 6 Each of these can independently represent an alkyl group having 1 to 6 carbon atoms that can be replaced by a hydroxyl group, and oxygen atoms may be present between the carbon atoms of these alkyl groups. However, R 5 and R 6 (At least one alkyl group is substituted with a hydroxyl group, or an oxygen atom is present between carbon atoms.)

The application discloses a treatment method for reducing carbon content of REBCO powder, and relates to the technical field of superconducting material preparation. The treatment method is that the REBCO powder is placed in an ozone-containing atmosphere for heat treatment. The core principle of the treatment method is that the strong oxidizing property of ozone and active oxygen atoms generated by the decomposition of ozone are used to directly oxidize carbon impurities in the REBCO powder into CO2 gas at a lower temperature, and meanwhile, the superconducting phase is avoided from being damaged. It is verified by a carbon analyzer that the carbon reduction efficiency of the powder after ozone heat treatment is several times higher than that of the powder after traditional oxygen atmosphere treatment.

The present disclosure is characterized by being represented by general formula G1. In general formula G1, ring C is an aromatic hydrocarbon ring or a heteroaromatic ring. A11-A15 and A21-A25 are each independently selected from the group consisting of CRA and a nitrogen atom. RA represents a hydrogen atom or a substituent of various types. When RA exists in a quantity of more than one, the plurality of RAs may be the same or different from each other. X1 and X2 are each independently selected from the group consisting of an oxygen atom, a sulfur atom, a tellurium atom, a selenium atom, and NRB. RB represents a hydrogen atom or a substituent of various types. When RB exists in a quantity of more than one, the plurality of RBs may be the same or different from each other. RAs adjacent to each other or RA and RB adjacent to each other are optionally bonded to form a ring.

A gas production apparatus includes: a separator configured to separate and capture a separated gas including carbon dioxide as a main component from an exhaust gas of exhaust gas equipment; reactors which are downstream of the separator, each of the reactors: (i) containing a reductant configured to contact the separated gas to produce carbon monoxide through a reduction reaction of carbon dioxide; (ii) being configured to separate at least some oxygen atoms split off from carbon dioxide in the reduction reaction; and (iii) having a reducing agent containing a metal oxide configured to reduce carbon dioxide as the reductant; a reducer configured to supply a reducing gas containing a reducing substance configured to reduce the reducing agent oxidized by contact with carbon dioxide; a pressure regulator configured to regulate a pressure of the separated gas; and a flow regulator configured to regulate a flow rate of the separated gas.

A two-dimensional particle that includes: one or plural layers that comprise a layer body represented by: MmXn, wherein Mis at least one metal of Group 3, 4, 5, 6, or 7; X is a carbon atom, a nitrogen atom, or a combination thereof; n is 1 to 4; and m is more than n but not more than 5, a modifier or terminal T exists on a surface of the layer body, wherein T is at least one selected from a hydroxyl group, a fluorine atom, a chlorine atom, an iodine atom, an oxygen atom, a chlorine atom, a phosphorus atom, and a hydrogen atom; and a hydrocarbon compound exists on the one or plural layers.

To provide a photoresponsive material that solves at least one of the problems of conventional technology. [Solution] The material has a crystalline structure formed by crosslinking at least one lanthanide with an organic group having 1 to 3 carbon atoms, wherein the organic group contains at least carbon atoms which may be partially or entirely substituted with other nonmetallic carbon group elements, and oxygen atoms which may be partially or entirely substituted with other nonmetallic oxygen group elements. A photoresponsive material having a peak component in the range of 533 eV to 534 eV in the O1s spectrum obtained by hard X-ray photoelectron spectroscopy.

The invention relates to the technical field of all-solid-state lithium batteries, and discloses a high-ionic-conductivity inorganic nanoparticle dispersed polyether composite solid electrolyte composition, which is prepared from the following components in percentage by weight: 35 to 65 percent of inorganic solid electrolyte nanoparticles, 15 to 45 percent of polyether polymer matrix precursor, 2 to 8 percent of cross-linking agent, 10 to 20 percent of lithium salt and initiator, wherein the molar ratio of lithium salt to ether oxygen atoms is 1 / 20, a three-dimensional cross-linked network is constructed through an in-situ ultraviolet polymerization reaction, high-content inorganic nanoparticles are physically locked in a polymer grid, and a continuous ion transmission channel is constructed at room temperature through a percolation effect while particle aggregation is inhibited, so that the high-content inorganic nanoparticles can be prepared. The composition has excellent ionic conductivity and mechanical flexibility, effectively solves the problems of high brittleness and low conductivity of the traditional composite electrolyte, only needs wet coating in the preparation process, and is suitable for large-area film production.

The invention relates to the technical field of gas production materials, and discloses preparation and application of a high-nitrogen energetic gas production material, triazole has high-energy and multi-nitrogen characteristics, nitryl compounds have high energy, and the combination of triazole and nitryl compounds enables the gas production material to have the characteristics of large gas production rate, low-temperature combustion, less harmful gas and the like; the molecular structure contains a large number of N-N, C-N and C = N bonds and has high enthalpy of formation, meanwhile, the content of C and H in the molecule is low, the density of the energetic material can be improved, the electronegativity of nitrogen and oxygen atoms in the structure is high, and the energetic material is a painful energetic material and has high safety in the using process; compared with similar gas production materials, the prepared gas production material has the advantages that the gas production rate is greatly increased, the amount of solid residues is greatly reduced, the added adhesive has no corrosivity, the prepared gas production material is good in fluidity, the external additive can play a role in slagging, and the residues are not prone to being sprayed out.

The invention discloses an oxygen-doped carbon nanofiber bifunctional electrocatalytic oxidation film and a preparation method and application thereof. The atomic ratio of nitrogen atoms to oxygen atoms in the oxygen-doped carbon nanofiber bifunctional electrocatalytic oxidation film is 11: (6-15). The catalytic performance of the electrocatalytic oxidation film can be improved by controlling the atomic ratio of nitrogen atoms to oxygen atoms in the oxygen-doped carbon nanofiber bifunctional electrocatalytic oxidation film, and then the catalytic efficiency of the electrocatalytic oxidation film is improved.

A system and method of making hydrogen from water. A reaction vessel is provided with an outer shell, a central shaft, and concentric inner tubes separated by annular spaces. Water is delivered to the annular spaces by a water pump through an inlet defined in the reaction vessel. The water courses along a tortuous flow path. That path begins at an inner annular space around a central shaft. It ends at an outer annular space. The water emerges from the reaction vessel through an outlet associated with a manifold. A vibratory stimulus is applied to the reaction vessel and water. Water molecules are dissociated into hydrogen molecules and oxygen atoms. These reaction products are delivered through the manifold along an effluent flow path to a receiving pressure vessel before deployment to a sub-assembly for harnessing clean energy.

The embodiment of the present application provides a solar cell and a forming method thereof. The forming method of the solar cell comprises the following steps: providing a substrate; performing boron diffusion treatment on the substrate to form a boron-doped layer and a borosilicate glass layer which are sequentially stacked on the surface of the substrate, and the borosilicate glass layer has interstitial oxygen atoms; the boron diffusion treatment comprises a deposition stage and a pushing stage, the substrate is provided with a boron source and an oxygen source in the deposition stage; the temperature of a reaction chamber in the deposition stage is greater than that in the pushing stage; after the boron diffusion treatment, a passivation stage is performed, a passivation source is provided to the borosilicate glass layer, and the passivation source and the interstitial oxygen atoms react to form an oxygen-containing compound. The embodiment of the present application is beneficial to improving the performance of the solar cell.

A preparation method of an oxygen solute gradient amorphous high-entropy alloy oxidation coating comprises the following steps that after a high-entropy alloy coating is deposited on the surface of a base body in a magnetron sputtering mode, the high-entropy alloy coating is cooled to the room temperature; and putting the substrate containing the high-entropy alloy coating into an oxidizing furnace, carrying out thermal oxidation in an air atmosphere, and cooling to room temperature along with the furnace to obtain the AlCrYTiZrO high-entropy oxidation coating. In the invention, the AlCrYTiZrO high-entropy oxidation coating can generate excellent corrosion resistance through characteristic complementation of a single element, a multi-element synergistic effect and a unique cocktail effect of high entropy due to a large number of components, large mixed entropy, low Gibbs free energy and a stable system; thermal oxidation is carried out under the air atmosphere, small-radius oxygen atoms can be introduced into the coating, the atomic size mismatching degree is increased, an amorphous structure with the oxygen solute gradient is formed, the corrosion resistance is further improved, meanwhile, AlCrYTiZr alloy elements and matrix elements are mutually diffused at the interface of the coating and a matrix, a diffusion layer is formed, and the corrosion resistance of the coating is improved. And the binding force between the coating and the substrate can be enhanced.

The invention provides a compound additive for an electrolyte. A <-> is selected from one of boron-containing inorganic anions or nitrogen-containing organic anions; r1-R4 and X are respectively and independently selected from one of a hydrogen atom, a halogen atom, a C1-C7 alkyl chain or a C1-C7 alkyl chain with a substituent group, a C1-C7 alkoxy chain or a C1-C7 alkoxy chain with a substituent group, a C2-C7 olefin chain or a C2-C7 olefin chain with a substituent group; y is selected from a sulfur atom or an oxygen atom, and A-in the formula 1 and X in the formula 2 respectively contain at least one halogen atom. The electrolyte additive shows high ionic conductivity and good interface mechanical performance, and interface charge transfer impedance is remarkably reduced; meanwhile, the dendritic crystal growth puncture problem at the interface is effectively inhibited, and the cycle life and the safety performance of the battery are improved.

Aspects of the present disclosure provide a method of fabricating a resistive random access memory (RRAM). For example, the method can include providing a substrate, forming a first electrode on the substrate, and forming a first metal oxide layer on the first electrode. The first metal oxide layer can act as a sink or reservoir of oxygen atoms that interact with a current conducting filament. The method can further include forming a second metal oxide layer on the first metal oxide layer. The second metal oxide layer can be configured to form conduction paths. The method can further include forming a second electrode on the second metal oxide layer. In an embodiment, the first metal oxide layer can be formed on a portion of the first electrode.

The invention provides a negative electrode material and a preparation method thereof, and a battery, the negative electrode material comprises an active substance, the active substance comprises silicon, a silicon oxide and a compound of a metal element M, the compound of the metal element M comprises a silicate of the metal element M and / or an oxide of the metal element M; the negative electrode material is measured through electron paramagnetic resonance, the g factor value of an electron spin resonance signal of oxygen atoms is X, and X is larger than or equal to 2.00601 and smaller than or equal to 2.00699; the oxygen vacancy intensity is Y, and Y is more than or equal to 10G and less than or equal to 400G. The negative electrode material provided by the invention has proper oxygen vacancies, a stable lithium ion channel exists in the battery cycle process, the expansion effect of the negative electrode material can be improved, and the cycle stability can be improved.

Provided is a compound represented by general formula (I). In general formula (I), X1 to X8 each independently represent a hydrogen atom or a substituent (which is not a halogen atom), X1 and X2, X3 and X4, X5 and X6, and X7 and X8 each may independently be bonded to each other via a substituent to form a benzene ring, Y represents an oxygen atom or a sulfur atom, and R1 to R8 each independently represent an organic group, with the proviso that when Y is an oxygen atom, not all of R1 to R8 are phenyl groups.

A method of controlling nitrogen and oxygen content of synthetic air is disclosed. The method may include decomposing nitrous in a decomposition system by expanding liquid nitrous into gaseous nitrous in a decomposition chamber. A gaseous mixture of oxygen gas (O2), transient oxygen atoms (O), nitrogen gas (N2), and / or transient nitrogen atoms (N) may be obtained from the decomposition. The gaseous mixture may be provided to a test chamber that is at least initially devoid of receiving an additional nitrogen gas (N2) from either an N2 supply or a reservoir of air and / or at least initially devoid of receiving additional oxygen gas (O2) from the reservoir of air. The test material may be exposed to the gaseous mixture in the test chamber. A response of the test material to the gaseous mixture may be determined.

The invention relates to the technical field of lithium ion batteries, in particular to a modified lithium-rich manganese-based positive electrode material and a preparation method thereof. The modified lithium-rich manganese-based positive electrode material comprises a lithium-rich manganese-based base material and a coating layer, and the coating layer comprises a lithium pyrophosphate coating layer and / or a lithium manganese pyrophosphate coating layer. The surface of the lithium-rich manganese-based substrate is coated with the lithium pyrophosphate and / or the lithium manganese pyrophosphate, lattice oxygen atoms are anchored through 'P = O' bonds in pyrophosphate groups of the lithium pyrophosphate and the lithium manganese pyrophosphate, and oxygen escape under high voltage is reduced; the tetrahedral structure of pyrophosphate can occupy the gap position of a transition metal layer, and Mn / Ni ions are physically prevented from being migrated to a lithium layer; and the two are combined, so that a lithium ion diffusion channel is guaranteed, and the modified lithium-rich manganese-based positive electrode material has relatively high capacity retention ratio, voltage retention ratio and rate capability in a charge-discharge long-cycle process.

The present invention relates to: a copolymer a monomer unit comprising a heterocyclic structure of 2 to 6 carbon atoms containing at least one oxygen atom in an amount of 1% to 40% by weight, based on 100% by weight of the total weight of the copolymer; and core-shell particles, a slurry composition, a separator, and a secondary battery comprising same.

The application belongs to the method for improving the energy conversion efficiency and stability of organic-inorganic hybrid perovskite solar cells, and the main content is that ethyl benzene sulfonyl lactam (PSAD) containing sulfonamide functional group is combined with-NH2 and Pb 2+ in perovskite material respectively through hydrogen bond and coordination effect to passivate the crystal defects caused by the two kinds of functional groups and cations in perovskite crystal grains. The oxygen atom of the sulfoxide group in PSAD can not only fix the organic amine ion in perovskite through hydrogen bond, but also can form Pb 2+ …O coordination bond with Pb to passivate the defects caused by Pb. The method passivates the grain boundary, reduces the non-radiation recombination of carriers, enhances the charge transport of perovskite thin film, and significantly improves the energy conversion efficiency and stability of perovskite solar cells. The additive PSAD is cheap and easy to obtain, which provides the possibility for industrialization.

This fluorine-containing ether compound is represented by R1-R2-Y-(CH2)z-O-CH2-R3[-CH2-R4-CH2-R3]x-CH2-O-(CH2)z-Y-R5-R6 (x is 0-1; z is an integer of 2-10; Y is any of O, NH, or S; R3 is a perfluoropolyether chain; R4 is a divalent linking group having 1-3 hydroxyl groups and having oxygen atoms at both ends; R2 is formula (2-1) or (2-2); R5 is formula (2-3) or (2-4); and R1 and R6 are end groups.).