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78 results about "Internal oxidation" patented technology

Internal oxidation, in corrosion of metals, is the process of formation of corrosion products (e.g. a metal oxide) within the metal bulk. In other words, the corrosion products are created away from the metal surface, and they are isolated from the surface.

High-strength plastic copper alloy and preparation method thereof

The invention discloses a high-strength and high-plasticity copper alloy and a preparation method thereof. The high-strength and high-plasticity copper alloy is prepared by mixing Cu-Al pre-alloyed spherical powder and CuO powder according to the mass ratio of (100-150): 1, wherein the Cu-Al pre-alloyed spherical powder and the CuO powder are different in particle size range. The solid solution state Al element part in the high-strength plastic copper alloy is oxidized into Al2O3 through CuO, and the Al2O3 exists in a Cu matrix. The preparation method comprises the following steps: (1) mixing Cu-Al pre-alloyed spherical powder with CuO powder, and drying; (2) cold isostatic pressing treatment; (3) vacuumizing, sintering at a high temperature in a protective atmosphere, and cooling; (4) vacuumizing, reducing in a reducing atmosphere, and cooling; and (5) after preheating, the copper alloy reduction blank is placed in a rotary forging die, rotary forging and air cooling are conducted, and the copper alloy is obtained. The high-strength plastic copper alloy is good in conductivity and mechanical property and high in plasticity. The method is simple in process, environmentally friendly, low in cost and suitable for industrial production.
Owner:CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY

A method for improving tungsten-copper connection interface based on internal oxidation and hydrogen reduction process

The application relates to a method for improving a tungsten-copper connecting interface based on internal oxidation and hydrogen reduction process, and relates to the technical field of tungsten-copper composite material preparation. First, an oxide (Cu2O, CuO) or oxygen is added to the surface of a tungsten block for internal oxidation treatment, a nano-oxide porous structure is generated on the surface, the surface roughness is increased, then hydrogen reduction is performed to remove surface oxide impurities, the surface pores are reserved, finally, the tungsten block with the treated surface is combined with copper powder through discharge plasma sintering to realize effective combination between tungsten and copper. Through the internal oxidation process, the influence of a metal alloy layer formed by a heterogeneous element brazing filler on the tungsten-copper interface compatibility and stability under radiation can be effectively avoided, and through the reduction treatment of high-purity hydrogen, the high-purity of the matrix is maintained, and the combination performance of the porous structure reinforced connecting layer is generated.
Owner:HEFEI UNIV OF TECH +1

High-entropy alloy powder and preparation process thereof

The invention relates to the technical field of alloy powder preparation, discloses high-entropy alloy powder and a preparation process thereof, and aims at solving the problems that Y2O3 particles are easy to agglomerate, the process depends on experience and the batch stability is poor in a traditional ODS high-entropy alloy process, a preparation method combining multi-scale simulation with digital twinning optimization is constructed, critical ball milling impact energy is simulated through molecular dynamics, and the high-entropy alloy powder is obtained. The method comprises the following steps: judging a ball milling end point in real time by adopting an acoustic emission intelligent monitoring system, and performing internal oxidation in an Ar-(3-10)% O2 atmosphere by utilizing defect engineering to generate Y2O3 nano-phase particles of 5-10nm; monitoring an O + / Ar + spectral line intensity ratio through a fiber optic spectrometer in SPS sintering to intelligently trigger pressure loading; constructing a digital twinborn body to realize virtual iterative optimization; the yield strength of the prepared high-entropy alloy powder reaches 1200-1300 MPa, the ductility is larger than or equal to 12%, and the strength is improved by 20-30% compared with that of a traditional process.
Owner:TIANJIN ZHUJIN METAL SURFACE ENG MATERIALTECH DEV

A high-surface-quality 980mpa-grade hot-dip galvanizing dh steel and a preparation method thereof

The application discloses a high-surface-quality 980MPa-grade hot-dip galvanizing DH steel and a preparation method thereof. The main chemical component mass content of the hot-dip galvanizing DH steel is as follows: C: 0.17-0.21%, Si: 0.4-0.7%, Mn: 1.8-2.2%, Nb: 0.01-0.02%, Ti: 0.01-0.02%, Cr: 0.4-0.5%, and Als: 0.14-0.9%. The method adopts low-carbon design and high-dew-point annealing process to produce the hot-dip galvanizing steel plate which meets the low-carbon environmental protection requirement and has high surface quality, so as to meet the urgent needs of the market. The high-dew-point annealing process is a new type of annealing technology, the oxygen partial pressure is increased by increasing the dew point, the Si and Mn element internal oxidation is realized, and thus the plating leakage defect is effectively improved, and the surface smoothness and flatness of the steel plate are improved.
Owner:BENGANG STEEL PLATES CO LTD

A method for preparing a multi-stage coating based on RAFM steel / titanium nitride by oxygen-mediated annealing

ActiveCN121852855BRelieve interface stressachieve diffusionVacuum evaporation coatingSputtering coatingSputteringTitanium nitride
The application discloses a preparation method of a multistage coating oxygen-mediated annealing based on RAFM steel / titanium nitride, and belongs to the technical field of coating preparation. The application method comprises the following steps: depositing a TiN coating on the surface of a low-activated ferrite / martensite steel base by using a magnetron sputtering, using a pure titanium target, and setting the nitrogen / argon flow ratio to 1:13-1:18, the base vacuum degree to 4-6*10 ‑5 Pa, and the deposition time to 60-90 min, and not applying additional active heating to the base during the deposition process; packaging the deposited coating sample in a quartz tube, providing a trace oxygen atmosphere in the tube by means of the gas pressure in the tube; and then performing 800-1000 DEG C annealing treatment and keeping the temperature for 90-120 min. Through oxygen-mediated element diffusion and reaction, a multistage composite structure, which comprises, from the base outward, an internal oxidation layer, an Fe internal enrichment layer, a TiN layer, an Fe external enrichment layer and an external oxidation layer, is formed in the TiN coating in situ. The application method is simple in process, does not need to deposit a transition layer additionally, the prepared multistage coating is well combined with the base, has excellent thermal shock resistance, and can withstand more than 30 times of thermal shock cycles.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Alloyed hot-dip galvanized steel sheet

The alloyed hot-dip galvanized steel sheet of the present disclosure has a base steel sheet having a prescribed chemical composition in mass%, and a plated layer, and the existence ratio ER of a specific internal oxide is 40% or less and the interval I of the internal oxide is 300 μm or more when a cross section of the base steel sheet is observed under prescribed conditions. The alloyed hot-dip galvanized steel sheet of the present disclosure is excellent in appearance and the like.
Owner:NIPPON STEEL CORPORATION

Coated steel sheet and its manufacturing method

PendingCN122319271AMetallurgyInternal oxidation
This invention relates to a clad steel sheet and a method for manufacturing the same. The clad steel sheet comprises: a base steel sheet, which, by weight percent, contains: C: 0.10-0.25%, Mn: 1.5-5.0%, Si: 0.5-2.5%, Cr: less than 1.5%, Al: 0.005-0.100%, P: less than 0.10%, S: less than 0.020%, B: less than 0.0050%, with the balance being Fe and other unavoidable impurities; and a coating formed on at least one side of the base steel sheet, wherein, with reference to the direction from the interface between the base steel sheet and the coating toward the thickness center, the depth of the internal oxide layer composed of one or more oxides of Mn, Si, Cr and B is 3-15 μm. More specifically, the invention relates to a clad steel sheet with excellent surface quality and weld LME resistance, and a method for manufacturing the same.
Owner:POHANG IRON & STEEL CO LTD

Fe-based electroplated steel sheet and galvannealed steel sheet, and methods of producing same

To provide an Fe-based electroplated steel sheet that not only has excellent chemical convertibility or excellent coating appearance when subjected to hot-dip galvanizing, but also has excellent resistance to cracking in resistance welding. Disclosed is an Fe-based plated steel sheet including: a cold-rolled steel sheet having a chemical composition containing Si in an amount of 0.1 mass % or more and 3.0 mass % or less; and an Fe-based electroplating layer formed on one or both surfaces of the cold-rolled steel sheet with a coating weight per surface of 1.0 g / m2 or more, in which a thickness of an internal oxidation layer is 2.00 μm or less, and an average value of C concentration in a range of 10 μm to 20 μm in a thickness direction from the surface of the Fe-based electroplating layer is 0.10 mass % or less.
Owner:JFE STEEL CORP

Low-deformation ultrahigh-temperature electrothermal alloy and preparation method thereof

The invention belongs to the technical field of alloy manufacturing, and particularly relates to a low-deformation ultrahigh-temperature electrothermal alloy and a preparation method thereof. Compared with a single-powder single-oxygen idea in the prior art, the scheme has the advantages that double powder-double chemical potential gradient is used for driving secondary dispersion precipitation for the first time, the side effect of'shell caused by excessive oxygen 'is converted into an'internal oxygen source', the inherent contradiction between agglomeration of an external addition method and insufficient gradient of an internal oxidation method is overcome, a continuous and controllable causal chain is formed, and the method is suitable for industrial production. And finally, the strength-service life bottleneck of the 1400 DEG C grade FeCrAl electrothermal alloy is solved.
Owner:BEIJING SHOUGANG GITANE NEW MATERIALS

Oxide dispersion strengthened copper alloy stranded wire and preparation method thereof

The invention discloses an oxide dispersion strengthened copper alloy stranded wire and a preparation method thereof, and belongs to the technical field of copper-based composite materials and powder metallurgy, the alloy components comprise, by mass, 0.15%-0.55% of Al, 0.03%-0.15% of Y, 0.01%-0.06% of Ti and the balance Cu, Al2O3 and Y3Al5O12 composite dispersed phases are dispersed and distributed in a matrix, and the composite dispersed phases are dispersed and distributed in the matrix. The preparation method comprises the steps of gas atomization powder preparation, gradient oxygen partial pressure internal oxidation, hydrogen reduction, cold isostatic pressing, hot extrusion, cold drawing, stranding and stable annealing, the tensile strength of the stranded wire is not lower than 500 MPa, the electric conductivity is not lower than 82% IACS, and the strength retention rate is not lower than 90% after heat preservation at 800 DEG C for 100 h.
Owner:XINXIEJI ELECTRONICS (CHANGSHU) CO LTD

Preparation method of high-strength and high-thermal-conductivity copper-based composite material and high-strength and high-thermal-conductivity copper-based composite material

The invention belongs to the technical field of diamond copper composite materials, and particularly relates to a preparation method of a high-strength and high-thermal-conductivity copper-based composite material and the high-strength and high-thermal-conductivity copper-based composite material. The preparation method of the high-strength and high-thermal-conductivity copper-based composite material comprises the following steps that (1) diamond particles and copper-aluminum alloy powder are mixed and then subjected to heat treatment in an inert atmosphere, and diamond-copper mixed powder is obtained; and 2) mixing the diamond-copper mixed powder obtained in the step 1) with an oxygen source, performing compression molding, and performing internal oxidation reduction sintering. Aluminum carbide and Cu-Al-C are generated on the surface of diamond in situ through interface reaction to improve the interface bonding strength of the diamond and a copper matrix, Al2O3 nanoparticles are generated in situ through internal oxidation-reduction-sintering, the interface bonding capacity and the heat conduction performance are further improved, and then preparation of the high-strength and high-heat-conduction copper-based composite material is achieved.
Owner:HENAN UNIV OF SCI & TECH

Method for preparing high-voltage electrical contact of gradient tungsten-copper alloy and dispersion-strengthened copper composite

PendingCN122322472AHeat stabilityHigh voltage
The present application belongs to the field of electrical materials and powder metallurgy, and particularly relates to a preparation method of a high-voltage electric contact with gradient tungsten-copper alloy and dispersion-strengthened copper composite. The W90Cu / W70Cu / W50Cu gradient layer is prepared by adopting gradient porosity pre-preparation and integrated pressing infiltration technology; the ODS-Cu matrix is prepared by adopting accurate internal oxidation-reduction technology; the vacuum hot pressing-brazing composite connection technology is adopted, combined with pressure keeping in the cooling stage, and the high-temperature plastic rheology of the copper matrix is used to actively inhibit the residual thermal stress, so that the W-Cu / ODS-Cu interface shear strength is greater than or equal to 300 MPa. The contradiction between the ablation resistance, electrical conductivity, thermal stability and interface reliability of the contact material is solved, and the service performance and structural reliability of the high-voltage electric appliance are significantly improved.
Owner:WESTERN METAL MATERIAL

Silver tin oxide indium oxide electric contact material and preparation method thereof

The invention relates to the field of preparation of electric contact materials, and particularly discloses a silver tin oxide indium oxide electric contact material and a preparation method thereof. The method comprises the following steps: mixing Ag, Sn, In and AgMe, and carrying out vacuum induction melting to obtain an alloy solution; after casting the alloy solution, cooling and curing to obtain an alloy particle plant; preheating the alloy particles, and then carrying out an equal-pressure differential-temperature rapid internal oxidation process to obtain a crude product of the electric contact material; and carrying out post-treatment on the crude product of the electric contact material to obtain the electric contact material. According to the preparation method, a one-step granulation method is combined with an equal-pressure differential-temperature rapid internal oxidation process, so that the production period is greatly shortened, the oxidation speed is remarkably increased, the uniformity and compactness of an oxidation film are improved, and the prepared electric contact material has good electrical and mechanical properties.
Owner:SHANGHAI LONGSUN ALLOY CO LTD

Steel sheet and plated steel sheet

The present invention provides a high-strength steel sheet having high platability, LME resistance, and hydrogen embrittlement resistance, and a plated steel sheet. A steel sheet and a plated steel sheet using the same are provided, the steel sheet including C: 0.05 to 0.40%, Si: 0.2 to 3.0%, Mn: 0.1 to 5.0%, and sol. Al: 0.4 to 1.50%, wherein an internal oxidation layer including fine-grained oxides is present in a surface layer of the steel sheet, the number density of the fine-grained oxides in the internal oxidation layer is 4.0 pieces / µm 2 In the above, the surface layer of the steel sheet includes a surface layer deficiency layer, the surface layer deficiency layer consisting of an oxide-free steel at a depth of 1 / 2 of the average depth of the internal oxidation layer calculated from a cross-sectional SEM image of the steel sheet, the oxide-free steel satisfying, in mass%, Si ≤ 0.6% and Al ≥ 0.05%.
Owner:NIPPON STEEL CORPORATION

Galvanized steel sheet

A galvanized steel sheet comprising a steel sheet containing C: 0.05 to 0.30%, Si: 0.01 to 3.00%, Mn: 0.80 to 3.00%, and Al: 0.010 to 2.000% and having a thickness of 0.10 to 0.95 mm, and a galvanized layer on the steel sheet, wherein a tensile strength is 550 to 1500 MPa, and, when defining a thickness of an internal oxide layer per surface of the steel sheet as “A” (μm), a thickness of a decarburized layer per surface of the steel sheet as “B” (μm), and a thickness of the steel sheet as “t” (μm), A / B: 0.01 to 0.50 and B / t: 0.001 to 0.200.
Owner:NIPPON STEEL CORPORATION

High toughness high carbon cold rolled steel sheet having excellent formability, and method for manufacturing same

One embodiment of the present invention provides: a high toughness high carbon cold rolled steel sheet having excellent formability comprising, by weight %, C: 0.80% to 1.25%, Mn: 0.2% to 0.6%, Si: 0.01% to 0.4%, P: 0.005% to 0.02%, S: 0.01% or less, Al: 0.01% to 0.1%, Cr: 0.01% to 1.0%, Sn: 0.05% to 0.5%, the remainder being Fe and other unavoidable impurities, in which a microstructure includes, by area %, retained austenite: 1% to 10%, martensite: 1% to 10%, ferrite: 5% or less (including 0%), the remainder being bainite, and has an average grain size of 3 μm to 20 μm, and an internal oxide layer formed directly below the surface has a thickness of 10 μm or less; and a method for manufacturing same.
Owner:POHANG IRON & STEEL CO LTD

Plated steel sheet

The present invention addresses the problem of providing a plated steel sheet having excellent LME resistance and red rust resistance. This plated steel sheet is provided with a plating layer on one or both surfaces of a steel sheet, and has a tensile strength of 780 MPa or more, the steel sheet having a prescribed chemical composition, the plating layer containing Zn, and the thickness of the plating steel sheet in a GDS measurement in the thickness direction of the plated steel sheet being greater than or equal to 100 [mu] m. A depth at which the luminous intensity Bx at a depth x ([mu] m) and the luminous intensity B150 at a depth 150 [mu] m satisfy Bx / B150 > = 5.0 is 0.5 [mu] m or more from the interface between the steel sheet and the plating layer, the thickness of the oxide formed on the surface of the plating layer is 0.5 [mu] m or less, and an internal oxide layer having a thickness of 1.0 [mu] m or more is present in the thickness direction of the steel sheet from the interface.
Owner:NIPPON STEEL CORPORATION

Graphene and aluminum oxide synergistically reinforced copper-based composite material and preparation method thereof

The invention discloses a graphene and aluminum oxide synergistically reinforced copper-based composite material and a preparation method thereof, and belongs to the technical field of metal-based composite material preparation. According to the method, dispersed nano-particles are formed in a copper matrix through internal oxidation-reduction, the surface is removed through selective pickling, a pure copper surface layer is exposed, then the surface of powder is coated with high-quality graphene through a CVD technology, and then the high-performance composite material is obtained through cold isostatic pressing, protective atmosphere sintering and hot extrusion densification. According to the composite material, 10-50 nm particles are distributed in a dispersed mode, graphene is of a 1-5-layer structure, the density is larger than or equal to 99.2%, the tensile strength ranges from 365 MPa to 485 MPa, the conductivity ranges from 78% to 92% IACS, and collaborative optimization of the strength and the conductivity is achieved. The preparation method is suitable for large-scale production and can be widely applied to the fields of electric power, electronics, rail transit and the like.
Owner:HARBIN DONG DA HIGH-TECH MATERIALS CO LTD

Resistance spot welding method and method for manufacturing welded member

The purpose of the present invention is to provide a resistance spot welding method and a method for manufacturing a welded member. The present invention is a resistance spot welding method in which a plate group in which two or more steel plates are stacked is sandwiched by a pair of welding electrodes and energized while being pressurized to join the steel plates to each other, the resistance spot welding method comprising a holding step in which the welding electrodes are held after the energization is completed, the pressure holding time is controlled so as to be within a prescribed time range defined by a specific relational expression using the C content, Si content, and Mn content of the steel sheet, and the decarburized layer thickness and internal oxidation amount of the surface layer of the steel sheet.
Owner:JFE STEEL CORP

A method for producing a low-cost high-surface-quality galvanized hot-formed steel sheet

PendingCN122279450ALaminar coolingHigh surface
This invention belongs to the field of metallurgical technology, and particularly relates to a low-cost, high-surface-quality galvanized hot-formed steel sheet production method. It includes the following steps: S1, using hot-rolled steel strip as raw material, controlling the coiling temperature of the hot-rolled steel strip to ≤550℃ through segmented laminar flow cooling; S2, pickling the hot-rolled steel strip using a composite pickling solution; S3, continuously galvanizing the pickled hot-rolled steel strip, wherein the heating temperature before galvanizing is ≤600℃. This invention eliminates the cold rolling and high-temperature annealing processes, fundamentally avoiding the internal oxidation defects of high-alloy hot-formed steel. The resulting steel sheet has a smooth surface without pitting or incomplete coating, and the interface between the coating and the substrate is clear and uniform. Simultaneously, the composite pickling solution improves pickling efficiency and reduces HCl volatilization. This invention has advantages such as low cost, high surface quality, and strong alloy adaptability.
Owner:RIZHAO STEEL HLDG GROUP

A pre-sanding process for large particles

The present application relates to a kind of pre-sand grinding processes of large particles, specifically including the following steps: step one: by using crusher, large oxide particles are broken;Step two: by water injection device, the oxide particles are dispersed with water;Step three: the oxide particles after being dispersed with water are transported to pre-sand grinding device and broken to specified size, then output;Step four: the oxide particles meeting the specified size are put into sand mill and ground into oxide powder;After two driving rollers pass through the two corners of the crushing box, the crushing box moves downward due to gravity, collides with the support plate to generate vibration, changes the position and angle of the oxide particles in the crushing box, and by controlling the reciprocating extension of the extension end of the hydraulic cylinder, the oxide particles in the crushing box are crushed multiple times, so that the particle size of the internal oxide particles meets the requirements, and the crushing efficiency of the oxide particles is improved.
Owner:PIONEER FILM MATERIALS (ANHUI) CO LTD

A method for preparing a graphene-reinforced aluminum oxide dispersion copper composite

The application belongs to the technical field of metal matrix composite material preparation, and particularly relates to a preparation method of graphene reinforced aluminum oxide dispersed copper composite material. The method comprises the following steps: taking copper aluminum and cuprous oxide as raw materials, ball-milling and mixing to obtain a mixture, carrying out internal oxidation treatment on the mixture under a vacuum atmosphere, and crushing to obtain aluminum oxide reinforced dispersed copper; mixing the aluminum oxide reinforced dispersed copper and a nano-oxidized graphene dispersion solution, carrying out stirring and ultrasonic treatment, and freeze-drying to obtain aluminum oxide dispersed copper-nano-oxidized graphene powder; and carrying out forming, hydrogen reduction sintering and hot extrusion deformation on the aluminum oxide dispersed copper-nano-oxidized graphene powder to obtain the graphene reinforced aluminum oxide dispersed copper composite material. The application can effectively introduce graphene into the aluminum oxide dispersed copper uniformly, can increase the electrical conductivity of the material while improving the strength, has high controllability, low production cost, simple equipment, a more simplified process flow, is environment-friendly in the process, and is suitable for industrial production.
Owner:WESTERN METAL MATERIAL

Silver copper oxide electrical contact material applied to new energy charging pile and preparation method of silver copper oxide electrical contact material

The invention discloses a silver copper oxide electrical contact material applied to a new energy charging pile and a preparation method thereof.The preparation method comprises the following steps that S1, silver ingots, copper ingots, cerium ingots and indium ingots are subjected to vacuum melting and cooled through a crystallizer to obtain silver alloy continuous casting wires, the diameter of the silver alloy continuous casting wires is 8-10 mm, and the silver alloy continuous casting wires comprise 6-10 wt% of Cu, 0.3-0.8 wt% of In, 0.1-0.4 wt% of Ce and the balance Ag; s2, after the silver alloy continuous casting wire obtained in the step S1 is subjected to wire drawing through multi-pass cold drawing, particles are obtained through ultrasonic vibration pelletizing; s3, performing step-by-step internal oxidation on the particles obtained in the step S2 to obtain oxidized particles; the preparation method is low in energy consumption and high in processing efficiency, and the prepared electrical contact material is uniformly oxidized.
Owner:WENZHOU JUXING ELECTRIC CONTACT TECH

A silver tin oxide internal oxidation production process

PendingCN122168939ACompression moldingWire rod
The application discloses a silver tin oxide production process by internal oxidation, which comprises the following steps: vacuum continuous casting of raw materials to obtain silver alloy wire rods; wire drawing, annealing and shearing of the silver alloy wire rods to obtain silver alloy wire particles; internal oxidation, pickling and compression molding of the silver alloy wire particles to obtain silver alloy ingots; and extrusion sintering, annealing and wire drawing of the silver alloy ingots to obtain silver tin oxide finished products. The application has the advantages of reducing processing procedures and improving the electrical properties of silver tin oxide.
Owner:FOSHAN TONGBAO ELECTRICAL PRECISION ALLOY CO LTD

A particulate dispersion-strengthened copper-based composite material and a method for producing the same

The application discloses a kind of granular dispersion distribution copper-based composite material and preparation method thereof, the copper-based composite material includes Al2O3, Cr2O3, WC, Bi2O3, TeO2 and balance Cu according to mass percentage.The preparation method includes: Al, Cr and Cu are smelted and gas atomized to obtain copper aluminum chromium alloy powder, which is mixed with Cu2O powder and then subjected to heating oxidation treatment, and then subjected to crushing and reduction to obtain internal oxidation powder, then WC, Bi2O3 and TeO2 are mixed and sequentially subjected to hot isostatic pressing, hot extrusion, cold rolling, stamping and post-processing to obtain the copper-based composite material.The particles in the material are uniformly distributed, and the material is suitable for high-voltage direct-current relays, vacuum circuit breakers, load switches, industrial contactors and high-power electric vacuum tubes and other electric contact devices.
Owner:ZHEJIANG UNIV OF TECH +1

Preparation method of dispersion copper with high density and low free oxygen content

The invention relates to the technical field of copper alloy preparation, in particular to a preparation method of high-density low-free-oxygen-content dispersed copper, which comprises the following steps: preparing copper-aluminum powder through atomization powder preparation, carrying out internal oxidation and reduction by using the oxidized powder of the copper-aluminum powder as an oxygen source to obtain aluminum oxide / copper powder, filling the aluminum oxide / copper powder into a steel ladle sleeve, vacuumizing, introducing hydrogen, and carrying out high-density low-free-oxygen-content dispersed copper. Aluminum oxide / copper powder is subjected to on-line reduction at a high temperature, a powder ingot with low free oxygen is obtained after high-temperature hot degassing, and then hot isostatic pressing and hot extrusion are performed to obtain the dispersion copper with high density and low free oxygen content. The relative density of the obtained dispersion copper is larger than or equal to 98%, and the free oxygen content is smaller than or equal to 20 ppm. According to the method, a solid reducing agent is not introduced, external elements are not introduced, the high-density and low-free-oxygen-content dispersed copper is obtained through hydrogen online reduction, and the use requirement of a divertor is met.
Owner:CHINA SHIPBUILDING INDUSTRY CORPORATION NO725 RESEARCH INSTITUTE

Preparation method of metal wear self-repairing material for wind turbine generator bearings

The invention discloses a preparation method of a metal wear self-repairing material for a wind turbine generator bearing, and relates to the technical field of metal wear self-repairing materials. Mineral substance hydroxyl magnesium silicate is adopted as a main component, Mg [SiO] [OH] is adopted, and the particle size ranges from 0.3 micrometer to 3.0 micrometers. In addition, graphene with the particle size of 15-60 nm is added, a self-repairing material is brought into the surface of a friction pair through a lubricating grease carrier, under the heavy-load or high-speed working condition, the friction flash temperature of 800-1200 DEG C can be generated on the surface, internal oxidation and sintering of the abraded surface are induced, and a super-hard, super-smooth and super-wear-resistant ceramic coating within 10 micrometers is automatically formed. According to the method, in-situ repair is triggered by utilizing friction flash temperature through the characteristics of the synergistic mineral substance and the graphene nano material, a superhard and super-smooth metal ceramic coating is formed on a worn surface, and automatic repair of micro-damage such as electric corrosion and pitting corrosion is realized.
Owner:ZHONGJI SQUIRREL LOW CARBON TECHNOLOGY (SHANGHAI) CO LTD

Smelting method of high-purity silver-magnesium-nickel alloy

PendingCN121737497AIngotNickel alloy
The invention provides a smelting method of a high-purity silver-magnesium-nickel alloy, and relates to the field of functional alloy smelting, and the smelting method of the high-purity silver-magnesium-nickel alloy comprises raw material selection of the high-purity silver-magnesium-nickel alloy, a vacuum smelting method, a cast ingot pure area selection method and the like. According to the method, the high-purity silver-magnesium-nickel alloy with extremely low inclusion content can be prepared, after the high-purity silver-magnesium-nickel alloy is rolled into a sheet subsequently, the defect of surface blistering in an internal oxidation process can be effectively avoided, and the production qualification rate of the silver-magnesium-nickel reed is remarkably increased.
Owner:BEIJING YAHANG TIANJI IND&TRADE

High-strength if steel hot-dip galvanized steel sheet and method for manufacturing the same

This invention discloses a high-strength IF steel hot-dip galvanized sheet and its preparation method, belonging to the field of steel manufacturing technology. The mass percentage content of each component of the steel sheet includes: C: 0.003%~0.012%; Mn: 0.3%~1.0%; Si: ≤0.05%; P: ≤0.03%; S: ≤0.005%; Als: 0.02%-0.07%; N: ≤0.003%; B: 0.0003%~0.0008%; Ti: 0.02%~0.09%; wherein [Ti]-4*[C]-3.43*[N]≥0.01%, [P] / [B]≤90, and the balance is Fe. This invention also discloses a production method for the hot-dip galvanized steel sheet. By controlling the hot rolling, cold rolling, and continuous hot-dip galvanizing annealing processes, and by adding Ti and C microalloying elements to form TiC, fine grain strengthening and precipitation strengthening are achieved to obtain the mechanical properties of high-strength IF steel. The reduction of P and Si content and the reasonable P / B ratio improve the secondary processing embrittlement performance. At the same time, by controlling the dew point, the Mn element is changed from external oxidation to internal oxidation, which improves the surface quality of the coating. As a result, the high-strength IF steel hot-dip galvanized steel sheet has excellent mechanical properties, secondary processing embrittlement, and surface quality.
Owner:SHOUGANG GROUP CO LTD