The invention discloses a preparation method of a photo-thermal super-hydrophobic
coating with excellent anti-
icing / deicing performance in a low-temperature and high-relative-
humidity environment, which comprises the following steps of: firstly, growing photo-thermal Cu-MOF (
Metal Organic Framework) nano particles on the surfaces of fibrous clay mineral nano particles with low heat
conductivity coefficient in situ to construct composite photo-thermal particles with a two-stage nano / nano structure; the preparation method comprises the following steps: preparing nano-particles, then carrying out low
surface energy modification on the nano-particles, introducing a low-heat-
conductivity-coefficient binder, inducing the binder to generate phase separation through a non-
solvent to form a micron-scale binder / low-surface-energy nano-particle aggregate, and finally, spraying to construct the photo-thermal super-hydrophobic
coating with a three-level micro / nano / nano structure. The three-level micro / nano / nano structure of the
coating simultaneously endows the coating with excellent photo-thermal performance in a low-temperature and high-relative-
humidity environment and Cassie-Baxter state stability of liquid drops on the surface of the coating, so that the coating has excellent passive anti-
icing / frosting and active deicing /
defrosting performance in the environment. The low heat conduction characteristic of the coating further inhibits heat exchange between the base material and water drops, so that the passive anti-
icing / frosting performance of the coating is further improved. In addition, the invention also has the advantages of simple preparation method, large-area preparation and the like, and lays a
solid foundation for the practical application of the photo-thermal super-hydrophobic anti-icing coating.