The invention provides a composite multifunctional health paint mate and a preparation method thereof, which relate to a paint mate and a preparation method thereof. According to the invention, the problems of complicated preparation process, single function and no environment protection of the traditional paint. The product comprises environment friendly functional material negative ion element, nano-zinc compound, nano-titanium dioxide, nano-silver solution, nanometer calcium carbonate and substrate emulsion paint. The method comprises the following steps of: 1) weighing raw materials; 2) mixing and stirring the nano-zinc compound, nano-titanium dioxide, nano-silver solution and nanometer calcium carbonate, and then adding the environment friendly functional material negative ion element to the mixed material, and continuing to stir the mixture so as to obtain a slurry; and 3) adding the substrate emulsion paint to the slurry and stirring the mixture so as to obtain the composite multifunctional health paint mate. The composite multifunctional health paint mate and the preparation method thereof, provided by the invention, have the advantages of simplicity and convenience in operation, multiple product functions, environment friendliness, health, capability of resisting disoperations from atmosphere and ultraviolet rays, durability, scrub resistance, alkali resistance, mildew resistance and good air permeability; and negative ions are continuously released into the air so that the paint mate can be mixed with the emulsion paint to improve the painting texture of the common emulsion paint and stop the penetrations of water and salt.