The invention belongs to the technical field of electromagnetic wave absorbing materials, and particularly relates to a hollow spherical mixed-phase
molybdenum disulfide-coated Ti3C2Tx
composite material and a preparation method and application thereof.The preparation method comprises the following steps that Ti3AlC2 is added into a
hydrochloric acid solution of
lithium fluoride, after
etching, supernate is removed through
centrifugation, precipitates are washed with water till the pH ranges from 6 to 7, the precipitates are dispersed in water again, ultrasonic treatment is conducted, and the hollow spherical mixed-phase
molybdenum disulfide-coated Ti3C2Tx
composite material is obtained. A supernatant is collected, such that a Ti3C2Tx suspension liquid is obtained; the preparation method comprises the following steps: adding
melamine into a
formaldehyde aqueous solution, heating and stirring for a set time, then adding acid into the
formaldehyde aqueous solution, heating and stirring to react under a weak acid condition, and centrifuging after the reaction is finished to obtain
melamine formaldehyde resin microspheres MF; the preparation method comprises the following steps: ultrasonically dispersing melamino-formaldehyde resin microspheres in water, then adding a Ti3C2Tx suspension into the water, and carrying out self-
assembly on MF and Ti3C2Tx to obtain Ti3C2Tx (at) MF; the preparation method comprises the following steps: dispersing Ti3C2Tx (at) MF in water, adding a
molybdenum source and a
sulfur source, and then carrying out
hydrothermal reaction on a
mixed solution to obtain the hollow spherical mixed-phase
molybdenum disulfide (at) Ti3C2Tx
composite material. The problems of poor
impedance matching and poor
electromagnetic wave absorption performance of the Ti3C2Tx-based material can be solved.