937 results about "Octadecane" patented technology

The invention discloses a preparation method of a flexible material with double functions of radiation refrigeration and photothermal conversion storage, and relates to the field of composite phase change materials. The preparation method comprises the following steps: 1) preparing the flexible phase change material matrix by utilizing n-octadecane, SEBS and POE through hot pressing; 2) preparing a BaSO4 solution by using absolute ethyl alcohol, deionized water, a water-based defoaming agent, a water-based dispersing agent and an acrylic resin emulsion; (3) preparing an MXene solution; and 4) spraying the BaSO4 solution on the surface of one side of the flexible composite phase change material matrix by using a spray gun, and spraying the MXene solution on the surface of the other side of the flexible composite phase change material matrix to obtain the flexible composite phase change material. The radiation refrigeration layer can strongly reflect visible light and near-infrared light, has high emissivity in an infrared light area, especially in an atmospheric window wave band, reduces absorbed atmospheric heat radiation, reduces urban heat island effect caused by dense building groups in cities, and can effectively solve the problems of large day and night temperature difference and heat supply and demand in summer and winter.

The invention relates to the technical field of chemical synthesis, and particularly provides a preparation method of a semaglutide side chain, which comprises the following steps: step S1, carrying out reaction on octadecanedioic acid mono-tert-butyl ester and trifluoroacetic acid pentafluorophenyl ester to generate a first intermediate; s2, enabling the first intermediate to react with 1-tert-butyl L-glutamic acid to generate a second intermediate; s3, enabling the second intermediate to react with pentafluorophenyl trifluoroacetate to generate a third intermediate; and S4, carrying out an amidation reaction on the third intermediate and 17-amino-10-oxo-3, 6, 12, 15-tetraoxa-9-aza-heptadecanoic acid, so as to generate a semaglutide side chain, and carrying out an amidation reaction on the third intermediate and 17-amino-10-oxo-3, 6, 12, 15-tetraoxa-9-aza-heptadecanoic acid. According to the preparation method disclosed by the embodiment of the invention, the pentafluorophenyl trifluoroacetate is used as the condensation reagent for two times to activate the carboxylic acid, and the amidation reaction is carried out for two times to construct the amido bond after each activation, so that compared with the traditional carbodiimide and urea positive ion type condensation reagent, the chiral racemization in the condensation process can be effectively avoided, and the yield of the product is improved. The condensation chiral racemization impurity can be lower than 0.3%.

The invention relates to the technical field of plugging agents, and discloses a viscoelastic polymer type self-assembly plugging agent and a preparation method thereof. The preparation method comprises the following steps: adding acrylamide, butyl acrylate, 2-acrylamide-2-methylpropanesulfonic acid, quaternized cyclodextrin, gamma-glycidyl ether oxypropyl trimethoxy silane modified bentonite, Schiff base styrene, a sodium dodecyl benzene sulfonate emulsifier and octadecyl dimethyl allyl ammonium chloride into a reaction kettle; and adding an azodiisobutyronitrile initiator into the deionized water, uniformly mixing, and reacting for 4-5 hours at 50-65 DEG C to obtain the viscoelastic polymer type self-assembled plugging agent after the reaction is finished. The plugging agent disclosed by the invention has a relatively good plugging effect, and effectively solves the problem that the gel strength is weakened or the gelling is not thorough due to the formation shearing effect in a continuous gel migration process.

The invention relates to the technical field of drug analysis and detection, and provides a detection method of moxifloxacin hydrochloride related substances. The related substances of moxifloxacin hydrochloride are detected by adopting a high performance liquid chromatography method, and the detection conditions are as follows: octadecylsilane chemically bonded silica is taken as a filling agent of a chromatographic column; the wavelength of a UV detector is 296 nm; the column temperature is 35-45 DEG C; the flow velocity of the mobile phase is 1.6-1.8 ml / min; the sample injection volume is 10-50 [mu] l; the mobile phase A is phosphate buffer solution-acetonitrile-methanol; the mobile phase B is phosphate buffer solution-acetonitrile-methanol; the elution mode is gradient elution; the diluent is a mobile phase A; according to the method provided by the invention, effective separation between moxifloxacin hydrochloride and various impurities can be realized, the sensitivity is high, the accuracy is good, the reproducibility is relatively good, a good linear relation is shown in a certain range, and qualitative and quantitative determination can be carried out on various impurities in moxifloxacin hydrochloride bulk drugs.

The invention belongs to the technical field of medicine detection, and particularly relates to a high-sensitivity liquid chromatography method for detecting mutagenic impurities in atomoxetine hydrochloride key starting material 3-chlorobenzene propanol, the method adopts an HPLC (High Performance Liquid Chromatography) analysis method, a chromatographic column adopts octadecylsilane chemically bonded silica as a filler, and the composition of a mobile phase A is a buffer solution; the mobile phase B is methanol or acetonitrile; carrying out gradient elution on the mobile phase; the flow velocity is 0.4 to 0.8 ml / min; the detection wavelength is 230 to 250 nm; by adopting an HPLC analysis method, the content of mutagenic impurities in the key starting material 3-chlorobenzene propanol of atomoxetine hydrochloride can be effectively separated and measured, and the method is high in sensitivity, strong in specificity and good in accuracy and repeatability, and has extremely important significance on quality control of the key starting material 3-chlorobenzene propanol of atomoxetine hydrochloride.

The invention discloses an electrostatic spinning preparation method of a multifunctional composite nanofiber membrane, which comprises the following steps: step 1, sequentially adding PVDF (Polyvinylidene Fluoride) and PLA (Polylactic Acid) into a first mixed solvent, and adding TiO2 while stirring to obtain a shell solution; melting n-octadecane to obtain a core layer solution; step 2, adding PVDF into a second mixed solvent to obtain a PVDF electrospinning solution; 3, the shell layer solution and the core layer solution are subjected to coaxial electrostatic spinning to form core-shell fibers, the PVDF electrospinning solution is subjected to single-shaft electrostatic spinning to form PVDF beads, high voltage is provided, and PVDFamp formed by compounding the core-shell fibers and the PVDF beads is formed on the aluminum foil; the invention relates to a PVDF / PLA / TiO2 (at) Oct composite nanofiber membrane. The material has good anti-ultraviolet, waterproof, breathable, self-cleaning and thermal regulation functions, and has excellent mechanical properties and degradability.

The invention relates to the field of plastic bags, and discloses a biodegradable plastic bag and a preparation method thereof, the biodegradable plastic bag comprises polylactic acid, poly (butylene adipate-co-terephthalate), a functional additive, modified starch, a lubricant and an antioxidant; the functional additive is prepared by grafting hydroxylated modified castor oil and isocyanated montmorillonite loaded titanium dioxide; the hydroxylation modified castor oil is prepared by modifying castor oil with chloroethyl isocyanate, then reacting with N-allylimidazole, and then reacting with 6-mercaptohexyl-1-alcohol; the isocyanated montmorillonite loaded titanium dioxide is prepared by reacting montmorillonite loaded titanium dioxide obtained by a sol-gel method with isophorone diisocyanate; the modified starch is prepared by reacting octadecanoyl chloride and acryloyl chloride with starch, then carrying out graft copolymerization with ethyl acrylate and further introducing glycidyl methacrylate, so that the plastic bag is endowed with excellent mechanical properties, biodegradability and antibacterial property.

The invention provides a content detection method for a salvia miltiorrhiza medicinal material, a salvia miltiorrhiza clear paste and a musk heart-dredging dropping pill. According to the method, a high performance liquid chromatography method is adopted, octadecylsilane chemically bonded silica is used as a chromatographic column filler, acetonitrile is used as a mobile phase A, 0.02%-0.1% trifluoroacetic acid is used as a mobile phase B, gradient elution is carried out, and rosmarinic acid and salvianolic acid B in the salvia miltiorrhiza medicinal material are synchronously and quantitatively detected. And synchronously and quantitatively detecting tanshinol, protocatechuic aldehyde, caffeic acid, salvianolic acid E, rosmarinic acid, alkannic acid and salvianolic acid B in the salvia miltiorrhiza clear paste, and synchronously and quantitatively detecting tanshinol, protocatechuic aldehyde, caffeic acid, salvianolic acid E, rosmarinic acid, alkannic acid, salvianolic acid B, arenobufagin and bufalin in the musk Tongxin dropping pill. The method is used for monitoring the content of specific components, can also judge the transfer rate in the medicine production process, and facilitates traceability in the production link. In addition, the method is relatively low in equipment requirement and suitable for industrial popularization.

The invention belongs to the technical field of pharmaceutical analysis, and particularly relates to a method for detecting related substances in landiolol hydrochloride for injection. According to the method, an HPLC (High Performance Liquid Chromatography) method is adopted, octadecylsilane chemically bonded silica is taken as a filler, and a mobile phase A (the volume ratio of a monopotassium phosphate solution containing pentafluoropropionic acid to methanol is 58: 42-62: 38) and a mobile phase B (the volume ratio of the monopotassium phosphate solution containing pentafluoropropionic acid to methanol is 28: 72-32: 68) are used for gradient elution to detect the related substances in landiolol hydrochloride for injection. The detection method is high in specificity, high in sensitivity, good in accuracy and convenient to operate, the medicine quality can be effectively controlled, the technical blank of detection of the landiolol hydrochloride related substances for injection is filled, a reference standard is provided for quality control of landiolol hydrochloride for injection, and therefore the safety and reliability of clinical medication are guaranteed.

The invention discloses compression-resistant glass and a preparation method thereof, and relates to the technical field of special glass. When the compression-resistant glass is prepared, an anorthite crystal phase is used as a main material, a wollastonite crystal phase is used as an auxiliary material, and zinc, barium, boron, sodium, antimony and titanium elements are added, so that the compression-resistant glass ceramic is prepared; the preparation method comprises the following steps: mixing tetraethoxysilane, zirconium oxychloride octahydrate and 3-glycidyl ether oxypropyl trimethoxy silane, adding hydrochloric acid, and stirring to obtain modified sol; the preparation method comprises the following steps: mixing hydroxyl-terminated polysiloxane, trimethyl ethyoxyl silane, methyl triethyoxyl silane and octadecyl triethyoxyl silane, adding a hydrochloric acid solution, and reacting to prepare an organosilane modified solution; mixing the modified sol and the organosilane modified solution, coating the surface of the compression-resistant microcrystalline glass with the mixture, and curing to obtain the compression-resistant glass. The compressive glass prepared by the invention has the advantages of high compressive strength, hydrophobicity, wear resistance and high surface hardness.

The invention relates to the technical field of anti-icing coatings, in particular to a preparation method of a soft and hard composite anti-icing coating with low icing adhesion. S1.1, weighing the following raw materials in parts by weight: 75 to 90 parts of modified epoxy resin, 10 to 25 parts of acrylic resin, 6 to 8 parts of vinyl-terminated polydimethylsiloxane, 1 to 3 parts of hydrogen-containing silicone oil, 0.5 to 1 part of platinum catalyst, 0.8 to 1.2 parts of emulsifier, 5 to 10 parts of cocoanut active charcoal and 11 to 13 parts of octadecyltriethoxysilane; the component A is prepared from the following components in parts by weight: 0.4 to 0.8 part of dibutyltin dilaurate, 8 to 12 parts of isophorone diamine, 7 to 9 parts of polydimethylsiloxane and 1 to 3 parts of aliphatic polyisocyanate; the modified epoxy resin is prepared from bisphenol A type epoxy resin, o-trifluoromethyl phenylethylamine and 1-aminobenzotriazole; s1.2, preparation of soft particles; s1.3, preparation of hard particles; s1.4, preparation of a coating layer; and the modified epoxy resin is adopted, so that the anti-icing performance, the wear resistance and the durability of the anti-icing coating are improved.

The invention relates to the field of pharmaceutical analytical chemistry, in particular to a method for determining tandospirone and salt intermediates thereof, high performance liquid chromatography is adopted, and chromatographic conditions include that a chromatographic column with octadecylsilane chemically bonded silica as a filler is adopted, and gradient elution is performed by a mobile phase A and a mobile phase B; wherein the mobile phase A consists of a first water phase and acetonitrile; the mobile phase B is composed of a second water phase and acetonitrile; the first water phase is a water solution containing monopotassium phosphate and sodium hexanesulfonate, and the pH value of the first water phase is 3.0-3.8; the second water phase is an aqueous solution containing monopotassium phosphate and sodium hexanesulfonate, and the pH value of the second water phase is 1.8-2.6. The testing method disclosed by the invention has good specificity, accuracy and repeatability, and can be used for monitoring the quality of the tandospirone raw material medicine.

The invention discloses a detection method for determining N-nitroso-Vonoprasan in Vonoprasan fumarate, and belongs to the technical field of medicine detection.The detection method comprises the steps that a solution is prepared, and detection is conducted; the detection comprises the following steps: determining a test solution and a reference solution by adopting a liquid chromatography-mass spectrometry method, recording a chromatogram, and calculating the content of N-nitroso-Vonorazan according to the chromatogram and an external standard method; according to the method, a triple quadrupole rod liquid phase mass spectrometer is adopted; a chromatographic column adopts octadecyl silane bonded silica gel as a filling agent, the specification of the chromatographic column is Poroshell 120EC-C18, 1.9 mu m, 50 mm * 3.0 mm; a mobile phase is composed of a mobile phase A and a mobile phase B, and gradient elution is adopted; the ultra-high pressure chromatographic column is adopted, the operation time is shorter, the signal-to-noise ratio is higher, the detection sensitivity is higher, the detection cost is lower, and the detection requirement can be met on a low-end triple quadrupole mass spectrum.

The invention belongs to the technical field of insulating oil, and provides a slow-release antioxidant as well as a preparation method and application thereof, the preparation method comprises the following steps: (1) mixing octadecyl trimethyl ammonium bromide, 2, 6-butylated hydroxytoluene, tetraethoxysilane, water and ammonia water, and reacting to obtain the antioxidant; and (2) in a protective atmosphere, mixing the antioxidant, ethanol, water and gamma-mercaptopropyltriethoxysilane, and carrying out a reaction so as to obtain the slow-release antioxidant. The slow-release antioxidant suitable for the synthetic ester insulating oil is prepared through a physical coating means and oleophylic modification, has excellent solubility, can effectively inhibit the increase of the acid value of the synthetic ester insulating oil, delays the oxidation process of the synthetic ester insulating oil, and remarkably prolongs the service life of the insulating oil. Meanwhile, through a slow release mechanism, the antioxidant can prolong the antioxidant effect of the antioxidant, improve the antioxidant stability in long-time operation and meet the higher antioxidant requirement of high-performance equipment such as a transformer for the insulating oil.

The invention discloses a carbon aerogel / reduced graphene oxide double-framework composite phase change material based on shaddock peel as well as a preparation method and application of the carbon aerogel / reduced graphene oxide double-framework composite phase change material. According to the method, the carbon aerogel / reduced graphene oxide double-framework material (CPA-rGO) with a hierarchical pore structure is constructed by taking waste shaddock peel as a raw material through freeze drying, a layer-by-layer self-assembly (LbL) technology and a gas-phase reduction and high-temperature carbonization process. And then, loading n-octacosane in the porous skeleton by a vacuum-assisted impregnation method to form the composite phase change material (OCPA-rGO) with a stable shape. The material has excellent leakproof performance (the leakage rate at 70 DEG C is only 4%), high thermal conductivity (0.366 W / (m.K)), remarkable photothermal conversion efficiency (91.6%) and electrothermal response characteristic, has a temperature sensitive resistance function, and can be applied to building energy-saving temperature control and intelligent household high-temperature early warning systems. According to the invention, high-value utilization of agricultural wastes is realized, and a new thought is provided for design of efficient and multifunctional phase change energy storage materials.

The invention provides a temperature-resistant and salt-resistant wall-fixing agent for a water-based drilling fluid for a myriameter deep well as well as a preparation method and application of the wall-fixing agent, and belongs to the technical field of drilling. The preparation method of the wall fixing agent comprises the following steps: adding acrylic acid into deionized water, adjusting the pH value of a system to 7.0, then sequentially adding N-hydroxymethyl acrylamide, N-[2-(3, 4-dihydroxyphenyl) ethyl]-2-acrylamide, an emulsifier, octadecyl vinyl ether and a complexing agent into the system, and shearing to obtain a monomer solution; adding an initiator into the monomer solution, and reacting; and after the reaction is completed, washing, drying and crushing to obtain the wall fixing agent. The wall fixing agent can resist the temperature of 200 DEG C, can resist the salt to be saturated, has strong adsorbability and high cohesion, and can effectively adsorb, block and bond micropores and micro cracks of rocks, so that the rocks are solidified, the well wall stability is effectively enhanced, drilling fluid leakage is prevented, and a technical guarantee is provided for safe and efficient drilling of deep wells.

The application belongs to the technical field of oil and gas field development, and provides a phase permeability improver, a fracturing fluid system containing the same, and respective preparation methods and applications. The phase permeability improver is obtained by copolymerization and hydrolysis of acrylamide AM, a functional monomer 2-acrylamido-2-methylpropanesulfonic acid AMPS, and cationic hydrophobic monomers A and B; the cationic hydrophobic monomer A is at least one of tetradecyl dimethyl allyl ammonium chloride, hexadecyl dimethyl allyl ammonium chloride, and octadecyl dimethyl allyl ammonium chloride; the cationic hydrophobic monomer B is at least one of methacryloyloxyethyl trimethyl ammonium chloride, acryloyloxyethyl trimethyl ammonium chloride, and acryloyloxyethyldimethyl benzyl ammonium chloride; the phase permeability improver and the fracturing fluid system containing the same can significantly reduce the water phase permeability after fracturing operation, while having a smaller influence on the oil phase permeability, and have a significant effect of stabilizing oil and controlling water, and can significantly improve the stable production effect of fracturing operation in a low-permeability oil reservoir.

The application provides a temperature-resistant and salt-resistant wall stabilizer for a ten-thousand-meter deep well water-based drilling fluid and a preparation method and application thereof, and belongs to the technical field of drilling. The preparation method of the wall stabilizer comprises the following steps: acrylic acid is added into deionized water, the pH of the system is adjusted to 7.0, then N-hydroxymethyl acrylamide, N-[2-(3,4-dihydroxyphenyl)ethyl]-2-acrylamide, an emulsifier, octadecyl vinyl ether and a complexing agent are sequentially added into the system, shearing is performed, a monomer solution is obtained, an initiator is added into the monomer solution, and reaction is performed; after the reaction is completed, washing, drying and crushing are performed, and the wall stabilizer is obtained. The wall stabilizer has a temperature resistance of 200 DEG C and a salt resistance of saturation, has strong adsorption and high cohesion, can effectively adsorb, plug and cement micro-pores and micro-cracks of rocks, thereby consolidating the rocks, effectively enhancing the well wall stability, preventing drilling fluid leakage and providing technical support for safe and efficient drilling of deep wells.

The present invention provides a kind of detection method of thirteen kinds of related substance contents in vonoprazan fumarate, and high performance liquid chromatography is used for detection, and the chromatographic conditions are: the test solution and the reference solution are injected into the high performance liquid chromatograph, and the chromatographic conditions are: the chromatographic column adopts octadecyl bonded silica gel column; the ultraviolet detector is used, and the detection wavelength is 260nm; the injection volume: 10μl; the column temperature: 30℃‑40℃; the flow rate: 0.8ml / min‑1.0ml / min; the gradient elution method is used, and the mobile phase A: the solution of 0.02mol / L potassium dihydrogen phosphate solution adjusted to pH 8.0 with potassium hydroxide solution and isopropanol mixed with a volume ratio of 95:5; the mobile phase B: the mixed solution of acetonitrile and isopropanol with a volume ratio of 95:5. The method can be used to detect the contents of 13 kinds of related substances in vonoprazan fumarate, and high performance liquid chromatography is used for detection, and the method has high detection sensitivity, and the verification results show that the system applicability and specificity of this method meet the requirements, and the needs of drug production quality monitoring can be met.

The invention discloses immobilized lipase based on bifunctional silicon dioxide as well as a preparation method and application of the immobilized lipase. Hydrophobic modification and covalent modification are performed on the surface of mesoporous silicon dioxide to obtain a bifunctional silicon dioxide carrier; the hydrophobic modification is any one of methylation modification, octylation modification, octadecyl alkylation modification, esterification modification and bromopropylation modification. The dual-functionalized silicon dioxide carrier is used for immobilization of lipase, and the prepared immobilized lipase can be used for production of biodiesel. The immobilized lipase provided by the invention is mild in enzyme reaction condition, good in biocompatibility, relatively high in enzyme activity, and excellent in stability and repeatability. In addition, by changing the ratio of the covalent modifier to the hydrophobic modifier, the catalytic activity and stability of the immobilized enzyme and the biodiesel yield are remarkably improved.

The invention discloses a high performance liquid detection method for letemovir content, and belongs to the technical field of pharmaceutical chemicals. The method comprises the following steps: (1) preparing a sample; (2) detection: carrying out isocratic elution by adopting a chromatographic column taking octadecyl bonded silica gel as a filler, taking an ammonium dihydrogen phosphate solution with the concentration of 20mmol / L as a mobile phase A and taking acetonitrile-methanol (80: 20) as a mobile phase B; and (3) analysis: recording a chromatogram, and calculating the content of the letemovir component by a peak area according to an external standard method. According to the method, an isocratic elution detection method is selected, a base line is smooth, the requirement on an instrument is low, the detection time is short, the detection efficiency can be improved, and consumables and reagents are saved.

The invention relates to the field of plasma separation and detection, in particular to a composition for separating plasma and a using method thereof. The composition comprises: a phase change component, which is selected from n-alkanes, which are selected from at least one of n-tetradecane, n-pentadecane, n-hexadecane, n-heptadecane, n-octadecane, n-nonadecane, n-eicosane, n-heneicosane or n-docosane; a liquid phase carrier component, wherein the liquid phase carrier component is selected from silicone oil; the structural framework and rheology regulation and control component comprises fumed silica, and the structural framework and rheology regulation and control component comprises fumed silica; the dispersion and stabilization auxiliary agent component is selected from at least one of TiO2 and BaSO4, the density adjusting filler component is selected from at least one of TiO2 and BaSO4, and the dispersion and stabilization auxiliary agent component comprises a silane coupling agent. According to the device, plasma and blood cells can be reliably, rapidly and effectively separated only through one-time low-temperature centrifugation, and remixing caused by transportation jolting can be avoided.

The invention discloses a method for detecting an intermediate acetylglucose of tetraacetyl by an HPLC-CAD (High Performance Liquid Chromatography-Computer Aided Design) method. The method comprises the following steps: (1) preparing a reference substance solution, namely dissolving acetylglucose by adding a diluent, and diluting to prepare the reference substance solution; (2) preparation of a test solution: taking tetraacetyl, adding a diluent solvent, and diluting to prepare the test solution; and (3) detecting the content of acetyl glucose in the test sample by adopting an HPLC-CAD (High Performance Liquid Chromatography-Computer Aided Design) method, and taking octadecylsilane chemically bonded silica as a filler in an adopted chromatographic column. According to the method disclosed by the invention, the intermediate acetyl glucose of the tetraacetyl substance is detected based on an HPLC-CAD (High Performance Liquid Chromatography-Computer Aided Design) method, and CAD parameters, a chromatographic column, a mobile phase, a diluent and a sample concentration are selected, so that the aims of effectively separating and accurately detecting the acetyl glucose in the sample can be fulfilled; the method has the advantages of simplicity, sensitivity, high accuracy, high repeatability, high specificity, good durability, high precision and the like, and has certain guiding significance on carbohydrate compound detection.

The invention provides a method for simultaneously detecting at least two of cysteine, acetylcysteine and cystine or salts of amino acids in an amino acid composition. High performance liquid chromatography is adopted for detection, and chromatographic conditions comprise that octadecylsilane chemically bonded silica is adopted as a chromatographic column of a filler, and a mobile phase A and a mobile phase B are adopted for gradient elution; wherein the mobile phase A is a mixed solution of an ammonium sulfate solution and an ion pair reagent. According to the method disclosed by the invention, cysteine, acetylcysteine, cystine or salts of the amino acids in the amino acid composition can be separated from one another and can be effectively separated from other amino acid components or impurities, and the separation degree is high; cysteine, cystine and acetylcysteine in the reference substance and amino acid composition are stable in retention time and good in peak shape. The method provided by the invention has the advantages of strong specificity, good stability, high accuracy, accurate, reliable and effective detection result, good repeatability and high precision.

According to the all-organic nonlinear insulating material based on the electron-donating group and the preparation method, polyolefin is used as a matrix of the material, and an organic small molecule filler containing the electron-donating group is introduced to form a uniformly dispersed composite structure, so that the nonlinear conductivity of the material is remarkably improved. The small organic molecules can be ethylene glycol diphenyl ether, nonylphenol polyoxyethylene ether, allyloxy polyoxyethylene ether or octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate, and the mass fraction of the filler is 0.1-3 wt%. The preparation method comprises the following steps: melting the polyolefin matrix at 110-120 DEG C, adding the small organic molecule filler, and blending for 10-30 minutes at the rotating speed of 50-70 r / min. The material has excellent electric field homogenization capability in a high electric field, avoids the problem of inorganic filler agglomeration, has relatively low filler content and excellent processability, can be widely applied to the field of high-voltage electrical equipment such as transformers, switch equipment and mutual inductors, and effectively improves the insulating property and prolongs the service life of the equipment.

The invention relates to the technical field of heat energy storage materials, and particularly provides a silicon dioxide aerogel composite phase change heat storage material and a preparation method thereof. The method comprises the following steps: mixing an organic silicon source, absolute ethyl alcohol and deionized water according to a specific ratio, fully stirring to obtain a mixed solution, and dropwise adding an acid catalyst into the mixed solution at room temperature for hydrolysis reaction to obtain a hydrolysate; sequentially adding a drying control agent and an alkali catalyst, and standing for gelation reaction to obtain gel; adding an organic solvent to carry out aging reaction, and then adopting the organic solvent to carry out replacement for multiple times to obtain alcogel; replacing the alcohol gel with an organic solvent for multiple times to obtain wet gel, soaking the wet gel in an excessive molten phase change material, and carrying out normal-pressure solvent replacement and drying at 40 DEG C to obtain the phase change material, the loading capacity of octadecane in the obtained CPCM is about 83%, the phase change enthalpy reaches up to 192J / g, the heat conductivity is as low as 0.0812 W / m.K, and no obvious leakage occurs after 200 times of circulation.

The invention discloses a collecting agent capable of being used for quartz direct and reverse flotation and a preparation method and application of the collecting agent. The collecting agent consists of the following components in parts by weight: 1-5 parts of a cation collecting agent, 7-30 parts of an anion collecting agent and 10-25 parts of an emulsifier, the cation collecting agent is at least one of lauryl amine, coconut oil alkyl primary amine, octadecyl succinamide and daminozide; the anion collecting agent is at least one of oleic acid, oxidized paraffin soap, naphthenic acid soap, cottonseed oil soap, rosin soap and sodium dodecyl sulfate; the emulsifying agent is at least one of glycerol, Tween 80, isooctanol polyoxyethylene polyoxypropylene ether and tributyl phosphate. Based on the synergistic effect of all the components, the collecting agent can effectively modify the surface of quartz under the strong alkaline condition, hydrophobization of the surface of quartz ore is promoted, and therefore flotation separation of feldspar and quartz is achieved; the feldspar surface can be effectively modified under the strong acid condition, and whitening and purification of quartz concentrate are achieved.

The invention relates to the technical field of chemical fiber manufacturing, in particular to a preparation process of graphene reinforced porous hollow polyester fibers. The problems that existing polyester fibers are insufficient in mechanical property and poor in moisture absorption and air permeability are solved. The preparation method comprises the following steps: modifying a PET sheet by using 2, 2-dimethylolpropionic acid and hydroxyl-terminated polydimethylsiloxane to obtain modified PET; the preparation method comprises the following steps: taking chitosan modified graphene as a carrier, and loading metal ions to obtain loaded graphene; polyethylene glycol and sodium bicarbonate are used as pore-foaming agents; modifying octadecyl dimethyl allyl ammonium chloride to obtain an antibacterial toughening agent; all the components are mixed, and the polyester fiber is prepared through melt spinning, stretching, heat treatment and alkali treatment. The mechanical property of the fiber is improved through the introduction of graphene and the modification treatment of the PET sheet; by utilizing the composite pore-foaming agent and adjusting the process, the moisture absorption and air permeability of the fiber are improved, and the service life of the fiber is prolonged.

The invention provides a specific chromatogram construction method and application of polygonum-folium isatidis formula granules. The specific chromatogram construction method comprises the following steps: acquiring a specific chromatogram of a to-be-detected substance by adopting a high performance liquid chromatography; the specific chromatographic conditions of the high performance liquid chromatography are provided, octadecylsilane chemically bonded silica is used as a chromatographic column of a filler, the detection wavelength is 305-315 nm, acetonitrile is used as a mobile phase A, a 0.04%-0.06% phosphoric acid aqueous solution is used as a mobile phase B, and elution is carried out according to a specific gradient program. The specificity of the material information corresponding to the characteristic peak in the characteristic spectrum obtained by the construction method is stronger, the related information in the characteristic spectrum represented by the method is more comprehensive, and the overall quality control of the polygonum-folium isatidis can be better realized.

The invention relates to a phase change energy storage fiber with ultraviolet shielding and heat regulation and control functions and a preparation method of the phase change energy storage fiber. The preparation method comprises the following steps: dissolving thermoplastic polyurethane in N, N-dimethylformamide to form a spinning mother solution; the preparation method comprises the following steps: firstly, adding nano titanium dioxide and uniformly dispersing, then adding a silicon dioxide shell layer-octadecane core layer phase change microcapsule, and stirring and ultrasonically defoaming to obtain a uniform composite spinning solution; extruding the spinning solution into a coagulating bath consisting of isopropanol and deionized water through an injection pump, and coagulating and forming to obtain nascent fibers; finally, washing, solvent replacement, tension setting and drying treatment are conducted, and compared with the prior art, the obtained fiber has efficient ultraviolet shielding performance and remarkable phase change energy storage capacity and has wide application prospects in the fields of intelligent temperature adjusting textiles, outdoor protective garments, building heat management and the like.