The invention relates to the technical field of
negative thermal expansion materials, and discloses a conductive Mg-P co-doped Cu2V2O7-
graphene negative thermal expansion material and a preparation method thereof. The conductive Mg-P co-doped Cu2V2O7-
graphene negative thermal expansion material comprises the following formula raw materials:
graphene oxide, CuO, MgO, V2O5 and NH4H2PO4. According tothe conductive Mg-P co-doped Cu2V2O7-graphene negative
thermal expansion material and the preparation method thereof, Cu2V2O7 has a stable linear negative
thermal expansion coefficient, a centrosymmetric monoclinic phase structure is formed by
doping Cu2V2O7 with Mg, under temperature variation, the Mg-O bond generates a vibration effect, the internal
coupling effect of the Cu2V2O7
crystal is improved, a linear chain-shaped monoclinic phase in the
crystal is destroyed,
oxygen atoms form a new arrangement in the
crystal lattice, local collapse occurs, the Cu2V2O7 is enabled to show a negativethermal expansion phenomenon, P atoms replace part of V atoms, the grain size of Cu2V2O7 is reduced, the
bond energy of P-O bonds is larger than that of V-O bonds, stress in Cu2V2O7 lattices is reduced, lattice
distortion is reduced, the
electron scattering probability and the high-frequency
dielectric constant are reduced, and therefore the
conductivity of Cu2V2O7 is enhanced.