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Method for preparing nano fiber reinforcement toughening resin base composite material

A technology of nanofibers and composite materials, applied in fiber processing, filament/thread forming, textiles and papermaking, etc., can solve the problems of poor interfacial compatibility of nanofiber-reinforced resin-based composite materials, and achieve easy popularization and application and improve electrical conductivity and heat conduction, the effect of improving the interface performance

Active Publication Date: 2009-04-01
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology describes how we use an electric spinning process for creation of fibers made from plastics called poly(methyl methacrylate) (PMMA). By choosing various factors like type of monomers involved during manufacturing, size weight ratio, and concentration of certain chemical agents within each component, this technique allows us to produce very strong and durable products at competitive prices compared to traditional methods. Additionally, these techniques allow for precise control over the final product's physical characteristics, which makes them useful in applications where they were previously unknown. Overall, our technical results include enhancing the quality and efficiency of producing highly functional and stronger thermoplastic/resorfined composite materials while maintaining their overall benefits.

Problems solved by technology

Technological Problem: Nanoplasma particles that form strong connections within matrices such as thermostructural plastics require careful control during manufacturing processes because they may affect other components like metal foils. These interactions lead to weakened areas called cracks where damage occurs when pressure acts upon the composition. To prevent crackings caused by these forces, various techniques involving specialized equipment were developed including chemical vapor deposition (CVD), physical blowfishing, ultrasonic fusion, electric spinning, etc., each method being studied separately.

Method used

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  • Method for preparing nano fiber reinforcement toughening resin base composite material
  • Method for preparing nano fiber reinforcement toughening resin base composite material
  • Method for preparing nano fiber reinforcement toughening resin base composite material

Examples

Experimental program
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Effect test

Embodiment 1

[0027] Example 1: Polymethyl methacrylate (PMMA) and polyacrylonitrile (PAN) were selected to prepare shell-core structure PMMA / PAN nanofibers. PMMA is Korean Atofina V020 (molecular weight 50000g / mol), and PAN is selected from British Courtaulds Ltd company (molecular weight 100000g / mol). 1.2g PAN is dissolved in dimethylformamide (DMF) of 10ml, and the viscosity is 598.4mPa. s, 1.2g PMMA is dissolved in 10ml of DMF, the viscosity is 100mPa.s. The two solutions are fully stirred and mixed. The viscosity of the mixed solution is 306.5mPa.s. It is used for electrospinning, and the spun silk is a shell-core structure nanofiber. PAN is located in the core structure, and PMMA is located in the shell structure, such as figure 2 shown.

Embodiment 2

[0028] Example 2: The raw materials are the same as in Example 1, 1.6g PAN is dissolved in 10ml of DMF with a viscosity of 718.4mPa.s, 0.8gPMMA is dissolved in 10ml of DMF with a viscosity of 48.6mPa.s. The two solutions are fully stirred and mixed. The viscosity of the mixed solution is 356.5mPa.s. It is used for electrospinning, and the spun silk is a shell-core structure nanofiber. PAN is located in the core structure and PMMA is located in the shell structure.

Embodiment 3

[0029] Example 3: The raw materials are the same as in Example 1, 1.8g PAN is dissolved in 10ml of DMF with a viscosity of 816.4mPa.s, 0.6gPMMA is dissolved in 10ml of DMF with a viscosity of 35.6mPa.s. The two solutions are fully stirred and mixed. The viscosity of the mixed solution is 412.5mPa.s. It is used for electrospinning, and the spun silk is a shell-core structure nanofiber. PAN is located in the core structure and PMMA is located in the shell structure.

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Abstract

The invention relates to a method for reinforcing toughening a resin matrix composite material by nano-fiber, which belongs to the composite material field. The invention is characterized in that polymers of different molecular weight with the designed solubility parameter ratio ranging from 0.8 to 1.2 and the molecular weight above 2:1 are selected as core and shell structure high polymers; by using traditional electrostatic spinning, namely the uniaxial method, shell-core structure nano-fiber is prepared; then the shell-core structure nano-fiber is composited and cured with the resin matrix by the layer paving or mixing process so as to prepare a composite material; the polymers of the shell structure part can be dissolved or mutually reacted with the molecular part of the resin matrix; and finally the three-dimensional network chain of the cured composite material can be mutually entangled or reacted with the molecular chain of the shell structure polymer, thereby greatly improving the interfacial property of the composite material. Compared with traditional nano-fiber composite materials, the interfacial bonding of the nano-fiber and the resin matrix is good; and mechanical property of the resin matrix composite material can be significantly enhanced under smaller content of nano-fiber.

Description

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Claims

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Application Information

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Owner BEIJING UNIV OF CHEM TECH
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