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42results about How to "Take full advantage of enhancements" patented technology

Preparation method of hydroxylation titanium oxide/graphene visible light catalysis material

The invention relates to a preparation method of a surface hydroxylation titanium oxide/graphene visible light catalysis material. According to the method, butyl titanate, graphene and nitrate serve as raw materials, organic electrolyte serves as surfactant, and the surface hydroxylation graphene/TiO<2> catalysis material is obtained through the steps of sol application, thermostatic water bath, ultraviolet irradiation, microwave irradiation, washing, drying and the like. The preparation method has the greatest advantage that ultraviolet pre-oxidation and microwave irradiation are utilized for achieving surface hydroxylation, the preparation process is simple, the energy consumption is low, rapid synthesis can be achieved, and large-scale production is easy to achieve; meanwhile, more defects such as oxygen vacancy and Ti<3+> are caused to a composite by surface hydroxylation, surface activity is increased, forbidden bandwidth of the composite is decreased, the spectral response range is widened, the obtained graphene/TiO<2> catalysis material is great in absorption performance and high in activity, durability and antibacterial performance, and the preparation method has a wide application prospect in fields such as sewage treatment, photocatalytic water splitting, air purification, solar cells, antibacterial materials and the like.
Owner:CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY

Method for preparing montmorillonite/graphene oxide aerogel/epoxy resin composite material

The invention provides a method for preparing a montmorillonite/graphene oxide aerogel/epoxy resin composite material and relates to a study on single-aspect performance of a double-phase composite material or epoxy resin. The method for preparing the montmorillonite/graphene oxide aerogel/epoxy resin composite material comprises the following steps: after adding expanded graphite to a container under a condition of ice-water bath, adding a mixed solution of concentrated sulfuric acid and concentrated nitric acid to the container; adding potassium permanganate to the container; stirring and heating an obtained mixture; after adding hydrogen peroxide to the mixture till a solution becomes luminous yellow, adjusting the PH value of the solution to 7; centrifuging the solution; freezing and drying the solution to obtain graphene oxide aerogel; taking the graphene oxide aerogel and adding the graphene oxide aerogel to acetone solution; carrying out ultrasonic treatment on an obtained mixture to obtain modified graphene oxide under the nitrogen protection; adding acetone to the modified graphene oxide and modified montmorillonite mixture; adding pre-heated epoxy resin to the modified graphene oxide and modified montmorillonite mixture in advance; and ultrasonically stirring, vacuumizing, heating, curing and cooling an obtained mixture to obtain a three-phase composite material. Themethod for preparing the montmorillonite/graphene oxide aerogel/epoxy resin composite material is used for preparing the montmorillonite/graphene oxide aerogel/epoxy resin composite material.
Owner:HARBIN UNIV OF SCI & TECH

Polylactic acid nanometer complex concurrently having toughness and strength, and preparation method thereof

The present invention discloses a polylactic acid nanometer complex concurrently having toughness and strength, and a preparation method thereof, and belongs to the field of polymer materials, wherein the complex comprises a polylactic acid matrix resin, a toughening agent and a reinforcing agent. The preparation method comprises: adding natural latex and deionized water to a reactor, and adding potassium hydroxide and sodium lauryl sulfate; introducing protective gas, adding isopropyl alcohol, uniformly mixing, adding glycidyl methacrylate, heating, and adding an initiator and a catalyst; carrying out a reaction, drying, carrying out immersion washing, drying, extracting, and drying to obtain NR-g-GMA; adding polyethylene glycol, elemental sodium wire and toluene to the reactor, carrying out a reflux reaction, cooling, adding epibromohydrin, carrying out a reaction, filtering, adding the filtrate to ether, precipitating, washing, and drying to obtain PEG-EP; adding a NaOH solution to a cellulose nano-crystal aqueous solution, uniformly mixing, adding the PEG-EP, carrying out a reaction, carrying out dialysis, and drying to obtain CNC-g-PEG; and carrying out melt blending on the dried polylactic acid matrix resin, the NR-g-GMA and the CNC-g-PEG so as to obtain the complex.
Owner:贵州黔城黔测检测技术有限公司

Powder metallurgy preparation method of graphene reinforced aluminum-based composite material

The invention provides a powder metallurgy preparation method of a graphene reinforced aluminum-based composite material, which comprises the following steps: preparing graphene-aluminum composite powder by long-time low-energy ball milling in advance, annealing, and carrying out short-time high-energy ball milling, densification processing and heat treatment to finally obtain the composite material. Uniform compounding of matrix powder and graphene is achieved through long-time low-energy ball milling, meanwhile, interface reaction can be avoided, and the structural integrity of graphene is protected; the annealed composite powder can improve the plastic deformation capacity of the composite powder while improving the quality of the graphene; short-time high-energy ball milling is performed, so that composite powder is welded into particles, and the quality of graphene is not damaged; and in addition, for the composite material of a aluminum alloy matrix, the uniformly dispersed graphene promotes the precipitation of fine dispersed precipitated phases in the matrix, and the mechanical properties of the composite material are further improved. The method is beneficial to protecting the integrity of the graphene structure to the maximum extent, exerts the graphene strengthening potential, saves energy and time, and is suitable for batch preparation and production.
Owner:SHANGHAI JIAO TONG UNIV

Preparation method of high-strength and high-toughness graphene reinforced aluminum matrix composite

The invention provides a preparation method of a high-strength and high-toughness graphene reinforced aluminum matrix composite, and relates to a preparation method of an aluminum matrix composite. The preparation method aims to solve the problems that graphene is not uniformly dispersed in an aluminum matrix during preparation of the aluminum matrix composite, and the strength and toughness of the prepared composite are inverted. The preparation method comprises the steps that graphene micro-sheets and aluminum metal powder are used for preparing the graphene micro-sheet reinforced aluminum matrix composite with the thickness being 2-2.5 times of the thickness of a product, the graphene micro-sheet reinforced aluminum matrix composite and an aluminum alloy plate are stacked for accumulative composite rolling deformation treatment, and heat treatment is carried out. According to the preparation method, the multi-pass accumulative composite rolling technology is utilized for enabling sheet layers of the graphene micro-sheets to be gradually opened, material grains are greatly refined, a composite interface is formed, the toughness of the obtained composite is not reduced while the strength of the composite is increased, and the problem that the strength and toughness of the graphene reinforced aluminum matrix composite are inverted is solved. The preparation method is suitable for preparing the graphene reinforced aluminum matrix composite.
Owner:HARBIN INST OF TECH

3D concrete material for printing

The invention discloses a 3D concrete material for printing, which is prepared from the following components in percentage by weight: 20 to 30 percent of Portland cement, 12 to 16 percent of sulphoaluminate cement, 6 to 8 percent of compound fiber, 10 to 20 percent of mineral admixture, 20 to 40 percent of compound fine aggregate, 0.5 to 1 percent of water reducing agent, 0 to 1 percent of accelerator, 1 to 2 percent of cellulose ether and 10 to 12 percent of water. According to the 3D printing concrete material disclosed by the invention, the formula of the cementing material is adjusted, and the Portland cement and the sulphoaluminate cement with the early strength characteristic are jointly used as the cementing material, so that the early hydration speed and the early strength of concrete can be adjusted, and a rapid hardening effect is achieved; the recycled fine aggregate is used for partially replacing traditional fine aggregate such as natural river sand, smooth pumping of materials in the 3D printing process is facilitated, and recycling of waste resources can be achieved; the steel fibers and the basalt fibers are used together, so that the investment cost can be reduced, the composite material is more suitable for being used in various environments, and the fiber reinforcement effect can be fully exerted.
Owner:南京绿色增材智造研究院有限公司

3D printing method of continuous fiber self-enhancement composite material

The invention discloses a 3D printing method of continuous fiber self-enhancement composite material. The 3D printing method comprises the following steps: at first, establishing a three-dimensional model of a self-enhancement composite material workpiece, and deriving the three-dimensional model as an stl formatted file; determining a printing temperature interval, wherein the self-enhancement composite material is thermoplastic high polymer material with different physical forms and is provided with a reinforced phase and a matrix base, the reinforced phase and the matrix base have the samechemical construction and different melting points, the reinforced phase is continuous fiber, and the matrix phase is resin; the printing temperature scope is higher than the melting point of the matrix phase and is lower than the melting point of the reinforced phase; preparing the self-enhancement composite material through 3D printing, finally, recycling the self-enhancement composite material,physically crushing the self-enhancement composite material, heating the crushed self-enhancement composite material to above the melting point to completely melt the self-enhancement composite material, and recycling the self-enhancement composite material as the raw material. On one hand, the 3D printing method solves the problems that the interfacial properties are poor and recycling is difficult when 3D printing is carried out on the composite material, and on the other hand, low-cost rapid manufacturing of the continuous fiber self-enhancement composite material is realized.
Owner:XI AN JIAOTONG UNIV

Method for preparing metal-based gradient coating with enhanced laser-cladding ceramic nano-particles

A method for preparing a metal-based gradient coating with enhanced laser-cladding ceramic nano-particles includes the steps that a plurality of groups of mixed powder of micron metal powder and ceramic nano-particles in a certain proportion are prepared into coated composite powder with uniformly dispersed nano-particles by means of mechanical composite, wherein the content of the ceramic nano-particles in the groups of mixed powder of the micron metal powder and the ceramic nano-particles in a certain proportion is gradually increased; laser-cladding sheets are pressed by means of compression molding; and the metal-based gradient coating with the nano-particles gradually is increased along the thickness direction by means of multilayer laser-cladding. The method has the advantages that the nano-particles can have excellent toughness by the aid of a dispersion strengthening mechanism for the nano-particles, the problem of easiness in cracking of a clad layer can be hopefully solved by the aid of a stress relieving mechanism for the gradient coating, excellent performances can be achieved by the aid of reinforcement of the nano-particles and the gradient coating, and accordingly the metal-based gradient coating can be applied to the surfaces of key parts such as aviation turbine engine blades and the like.
Owner:TONGLING UNIV
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