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543 results about "Magnesium matrix composite" patented technology

Preparation method of in-situ reduced graphene reinforced magnesium-matrix composite

The invention discloses a preparation method of an in-situ reduced graphene reinforced magnesium-matrix composite. The method comprises the following steps: dissolving graphite oxide in an appropriate amount of ethanol solution, and performing ultrasonic treatment for 0.5-2h to obtain a graphene oxide ethanol solution with concentration of less than or equal to 2mg / ml; adding appropriate AZ91 magnesium alloy powder with the particle size of less than or equal to 325 meshes into the mixed solution, and performing ultrasonic treatment and mechanical stirring for 2h to obtain mixed slurry; performing vacuum drying of the mixed slurry, transferring into a mould, and pressing into a composite green under the pressure of 100-600MPa at room temperature; sintering the composite green for 2-4h at 500-600 DEG C in argon protection; and finally performing hot extrusion of the sintered composite at 350-400 DEG C. The preparation method disclosed by the invention is simple in preparation process and safe and reliable; the reduced graphene has good dispersity in magnesium alloy; and the reduction byproduct MgO is good for improving the interface bonding strength so that the reinforcing effect is better and the performance of the composite is excellent. Compared with the method of directly adding graphene into the magnesium matrix, the cost is lower and the dispersity is better; and the preparation method is suitable for industrial preparation of a high-performance graphene reinforced magnesium alloy composite.
Owner:NANCHANG UNIV

Graphene enhanced magnesium-based composite and preparing method thereof

The invention relates to a graphene enhanced magnesium-based composite and a preparing method thereof, and belongs to the technical field of composites. In the inert atmosphere, graphene with a certain lamella size and pure magnesium particles are subjected to ball-milling treatment, and meanwhile peeling of a graphene lamella and mixing between the graphene lamella and the pure magnesium particles are achieved; an ultrasonic dispersing and mechanical stirring technology is adopted, the peeled graphene lamella is further dispersed in a liquid phase, the pure magnesium particles are inserted in the parts among graphene layers in the stirring process, and the solid phase interval and sufficient mixing between the pure magnesium particles and the graphene layers are achieved; the compactness of graphene/pure magnesium particle composite powder is enhanced through a thermal extrusion technology, a magnesium-based precursor containing graphene is obtained, and the graphene enhanced magnesium-based composite is finally obtained through an alloy component blending and stirring casting method. The method technology is simple and convenient to conduct, environment friendliness is achieved, and sufficient dispersing of graphene in a magnesium base body is achieved. The graphene/magnesium-based composite with the enhanced mechanical performance is obtained, and wide application prospects are achieved in the fields such as aerospace, automobiles and electronics.
Owner:BEIJING UNIV OF TECH

Method for preparing carbon nanotube enhanced magnesium-based composite material

InactiveCN103014567AImprove wettabilityGood for mixing and compoundingMagnesium matrix compositeCarbon nanotube
The invention provides a method for preparing a carbon nanotube enhanced magnesium-based composite material comprises the following steps of: mixing carbon nanotubes and metal powder together in the mass ratio of (1:2)-(1:30), putting the mixture in a ball mill for ball milling for 0.5-24 hours, filtering the milled powder through a 40-100-mesh stainless steel sieve, and then covering the mixture with a metal foil and putting the covered mixture in a die for pressing; after completely melting a magnesium base material, refining, degassing and deslagging the melt, and then pressing the carbon nanotube / metal powder precast block into the melt of the magnesium base material by using a bell jar until the percast block is completely melted into the magnesium or magnesium alloy liquid, stirring for 0.5-10 minutes under the conditions of 700-780 DEG C and 100-1500 r / minute, regulating the melt temperature to the casting temperature, and then performing casting to form the billet of the carbon nanotube enhanced magnesium-based composite material, wherein the content of the carbon nanotubes in the carbon nanotube enhanced magnesium-based composite material is 0.1-5wt%. The method provided by the invention is simple in process, convenient in operation and short in flow; the carbon nanotube particles are evenly distributed in the base body; and the method is excellent in performance and low in production cost, thereby being suitable for industrially preparing a high-performance carbon nanotube enhanced magnesium-based composite material.
Owner:NANCHANG UNIV

Silicon carbide particle reinforced magnesium-based composite material and preparation method

The invention discloses a silicon carbide particle reinforced magnesium-based composite material and a preparation method thereof, and belongs to the field of a metal-based composite material. The silicon carbide particle reinforced magnesium-based composite material is characterized in that the silicon carbide particle reinforced magnesium-based composite material is prepared by taking pure Mg powder, Al powder and SiC particle micro-powder as raw materials through powder metallurgy and a multi-directional forging method. Through two forming methods: powder metallurgy and multi-directional forging method, an excellent wettability and an excellent combining property are guaranteed between a magnesium alloy substrate and the SiC particles, and residual pores in the material in the powder metallurgy forming process are eliminated, so that the prepared magnesium-based composite material is uniform in distribution of the SiC particles and fine in magnesium alloy substrate grains, and the composite material has an excellent mechanical performance. In comparison with other particle-reinforced magnesium-based composite material preparation methods, the preparation method disclosed by the invention, by a solid forming process, is simple in process, low in cost, easy to industrially produce, and is capable of preparing the SiC particle reinforced magnesium-based composite material which is excellent in mechanical performance.
Owner:TAIYUAN UNIV OF TECH

SiC particle-containing magnesium alloy high in elastic modulus and preparation method of magnesium alloy

The invention provides a SiC particle-containing magnesium-based composite material high in elastic modulus. The SiC particle-containing magnesium-based composite material comprises the following components in percentage by weight: 1.0-10.0% of aluminum and/or zinc, 1.0-15.0% of SiC and the balance of magnesium, wherein the sum of percentages by weight of the components is 100%; the alloy element comprises aluminum and/or zinc. A preparation method of the SiC particle-containing magnesium-based composite material comprises the following steps: punching holes in a pure magnesium ingot, adding SiC particles subjected to surface modification and drying into the holes, heating and melting pure magnesium under the protective atmosphere, stirring and then quickly raising the temperature again, adding intermediate alloys of the other components and stirring, controlling the time for fully melting the intermediate alloys till the casting time is shorter than or equal to 3 minutes, refining and slagging, casting to obtain a cast ingot. The SiC particle-containing magnesium-based composite material is reasonable in ratio of components, easy to process and manufacture and low in cost; the prepared magnesium-based composite material is high in room temperature strength and elastic modulus and good in plasticity; the comprehensive performance of the magnesium-based composite material is apparently higher than that of the existing ordinary magnesium alloy; the magnesium-based composite material is suitable for industrialized production.
Owner:BAIC MOTOR CORP LTD

Method for reinforcing magnesium matrix composite by using magnesium oxide-coated graphene

The invention provides a method for reinforcing a magnesium matrix composite by using magnesium oxide-coated graphene. The method comprises the following steps: mixing 0.1 to 5 g of magnesium oxide-coated graphene with no less than 250 ml of an ethanol solution and carrying out ultrasonic treatment for 1 to 2 h so as to obtain a magnesium oxide-coated graphene ethanol mixed liquor; adding magnesium alloy powder with mass of no less than 95 g and granularity of no more than 325 meshes into the mixed liquor and carrying out ultrasonic treatment and mechanical stirring for 1 to 3 h so as to obtain mixed slurry; carrying out filtering and vacuum drying on the mixed slurry, then transferring the obtained substance to a die and carrying out cold pressing at room temperature under a pressure of 100 to 600 MPa; sintering a cold-pressed composite at 500 to 600 DEG C under the protection of argon for 2 to 4 h; carrying out hot extrusion on the sintered composite at 350 to 400 DEG C; and subjecting the extruded composite to T6 heat treatment. The method has the advantages of low process cost, safety, reliability and simple operation; the magnesium oxide-coated graphene is uniformly distributed in magnesium alloy and has high bonding strength with a matrix interface, obvious grain refinement effect is obtained, and the composite has excellent performance; and the method can realize industrial preparation of the high-performance graphene-reinforced magnesium alloy composite.
Owner:NANCHANG UNIV

Amorphous particle reinforced magnesium-base composite material and manufacture process

The invention discloses an amorphous reinforced magnesium-based compound material and a preparation technique thereof. The material includes an amorphous grain NixMyTz and a magnesium-based alloy MgaAlbQcRd; wherein, x is equal to or more than 30 or equal to or less than 70; y is equal to or more than 3 or equal to or less than 50; z is equal to or more than 0, or equal to or less than 35; a is equal to or more than 80, or equal to or less than 100; b is equal to or more than 0, or equal to or less than 18; c is or is equal to or more than 0, or equal to or less than and d is equal to or more than 0, or equal to or less than 3. Simultaneously, the invention also provides the preparation technique of the amorphous reinforced magnesium-based compound material: the grains of a magnesium alloy and the grains of an amorphous alloy are uniformly mixed and pressed in a cold pressing way with a cold pressing pressure of 30 to 250MPa; then the grains of the magnesium alloy and the grains of the amorphous alloy are sintered in a hot pressing sinter boiler with a hot pressing pressure of 5 to 60MPa; the sintering temperature is arranged between 500 and 700 DEG C; the sintering time lasts 30 to 180 minutes. An amorphous metal reinforcement adopted by the amorphous reinforced magnesium-based compound material has typical metal characteristics and can be better combined with the interface between magnesium and a magnesium alloy matrix, thereby better facilitating to improving the reliability of the material during the using process; simultaneously the preparation technique of the amorphous reinforced magnesium-based compound material is more simplified, thus being suitable for industrial production.
Owner:上海市机械制造工艺研究所有限公司

Preparation method of enhanced magnesium-based composite material of carbon nanotubes

The invention relates to a preparation method of an enhanced magnesium-based composite material of carbon nanotubes, relates to a preparation method of a nanometer composite material, and mainly solves the technical problems that the carbon nanotubes are difficultly scattered uniformly in a magnesium alloy matrix and the tensile strength of the enhanced magnesium-based composite material is low. The preparation method comprises the following steps of: firstly, carrying out mixing and ball milling on Zn powder and the carbon nanotubes to obtain composite powder; secondly, pressing the composite powder and magnesium powder into precast blocks after uniformly mixing the composite powder and the magnesium powder; and finally, adding the precast blocks into the molten magnesium powder, heating until obtaining metal solution, and transferring the metal solution into a die to be pressed, thus obtaining the enhanced magnesium-based composite material of the carbon nanotubes, wherein the tensile strength of the enhanced magnesium-based composite material is 195-210 MPa, and the elongation rate of the enhanced magnesium-based composite material is 13-15%. According to the preparation method of the enhanced magnesium-based composite material of the carbon nanotubes, the tensile strength is high, the dispersity is good, and the enhanced magnesium-based composite material of the carbon nanotubes can be applied to the fields of aerospace, automobiles and sports equipments.
Owner:HARBIN INST OF TECH

Electromagnetic/ultrasonic preparation method of in-situ particle reinforced magnesium-based composite material

An electromagnetic/ultrasonic preparation method of an in-situ particle reinforced magnesium-based composite material belongs to the technical field of metallurgy. The invention discloses a method for preparing the magnesium-based composite material with an electromagnetic continuous casting method, which is characterized by comprising the following steps of: melting a magnesium-based melt added with micro-alloying elements of Ca, rare earth Y, rare earth Ce; selecting an Al-Ti-C or Al-Ti-B reinforced system, adopting a self-propagating high-temperature synthesis method to synthesize a magnesium-based composite material melt containing reinforced particles in situ, and implementing electromagnetic/ultrasonic combined stirring to the magnesium-based composite material melt; and finally adopting a continuous casting process to form the magnesium-based composite material by continuous casting, and applying an electromagnetic field and an ultrasonic field within the range of a crystallizer so as to obtain a multi-phase reinforced magnesium-based composite material continuous-casting billet. The electromagnetic/ultrasonic preparation method has the effects and advantages of organically combining the self-propagating reaction method with the electromagnetic continuous casting technology and the ultrasonic technology, obtaining the magnesium-based composite material continuous-casting billet with smooth surface, uniform distribution of particle reinforcement phases in the basal body and good combination of the reinforced bodies and the basal body, and having simple preparation process.
Owner:DALIAN UNIV OF TECH

Preparation method of carbon nanotube-alumina composite reinforced magnesium-based composite material

The invention discloses a preparation method of a carbon nanotube-alumina composite reinforced magnesium-based composite material, which relates to the manufacture of magnesium-based alloy by using a casting method. The preparation method comprises the steps of: step 1, calcining and reducing raw materials of ferric nitrate nonahydrate and alumina in the ratio of (0.07-1.00):1 to obtain an iron / alumina composite catalyst, and finally, performing catalytic pyrolysis reaction by using the mixed gas of nitrogen gas and ethylene in the volume ratio of (6-12):1 for uniformly dispersing carbon nanotubes on the surface of the alumina, so as to prepare a carbon nanotube-alumina composite reinforced phase; and step 2, adding the carbon nanotube-alumina composite reinforced phase to a molten magnesium base material, and stirring and casting to prepare the carbon nanotube-alumina composite reinforced magnesium-based composite material, wherein the added carbon nanotube-alumina composite reinforced phase accounts for 1-15% of the molten magnesium base material by mass percentage. According to the invention, the defect of a magnesium-based alloy texture in the magnesium-based composite material produced in the prior art is overcome, the excellent enhancing effect of the carbon nanotubes in a magnesium matrix can be brought into full play, and the comprehensive performance of the magnesium-based composite material is ensured to be enhanced.
Owner:HEBEI UNIV OF TECH +1

Preparation method for graphene reinforced magnesium matrix composite material

The invention discloses a preparation method for a graphene reinforced magnesium matrix composite material. The preparation method comprises the following steps that magnesium powder is dissolved in ethanol, mechanical stirring and ultrasonic dispersion are conducted, and a magnesium alloy solution is obtained; graphene is added into the ethanol, ultrasonic mixing is conducted, and a graphene dispersion solution is obtained; the graphene dispersion solution is added into the magnesium alloy solution drop by drop, ultrasonic dispersion and mechanical stirring are conducted, and a graphene magnesium alloy dispersion solution is obtained; the graphene magnesium alloy dispersion solution is placed in a low-temperature water bath kettle to be heated; after the solution evaporates to be liquid seal pulp, heating is stopped, the pulp is taken out to be subjected to vacuum ball milling, vacuum pumping is conducted after standing, then high-purity argon is pumped in, and ball milling is conducted; a ball-milled mixture is taken out, subjected to vacuum drying and put into a vacuum glove box to be subjected to manual dispersion grinding; and composite powder is put into a sintering furnace to be sintered. The technological process is simple, practicability is wide, and the graphene reinforced magnesium matrix composite material has wide military and aviation application prospects.
Owner:HARBIN UNIV OF SCI & TECH

Graphene and reaction in-situ nano magnesium oxide particle composite enhanced magnesium-based composite material and preparing method thereof

The invention discloses a graphene and reaction in-situ nano magnesium oxide particle composite enhanced magnesium-based composite material and a preparing method thereof, relates to a graphene enhanced magnesium-based composite material and a preparing method thereof, and aims at solving the problems that in existing composite materials, graphene and magnesium matrix wettability is poor, graphenedispersibility is poor, and the interface bonding strength is low. The composite material is prepared through three raw materials including oxide, graphene and a magnesium matrix. The method comprises the steps that firstly, stirring casting or powder metallurgy is conducted; and secondly, heat deformation is conducted, and a cast-state composite material or a sintered-state composite material issubjected to hot extrusion or rolling deformation. The interface position of the composite material prepared through the method is free of holes and impure phases, graphene and matrix wettability isgood, and the interface interaction between graphene and a matrix is high. The graphene and reaction in-situ nano magnesium oxide particle composite enhanced magnesium-based composite material and thepreparing method thereof are used in the magnesium-based composite material field.
Owner:HARBIN INST OF TECH

Preparation method of carbon-nanotube-enhanced magnesium-based composite material

ActiveCN102747240AImprove performanceAvoid melting temperatureMagnesium matrix compositeModified carbon
The invention relates to a preparation method of a carbon-nanotube-enhanced magnesium-based composite material. The method comprises the steps that: carbon nanotubes are subjected to surface modification, such that a uniform and compact Ni-P alloy layer is formed on the surface of the carbon nanotubes; the modified carbon nanotubes are mixed with powders of elements such as magnesium, aluminum, and zinc, such that a mixed raw material is obtained; the mixed raw material is mixed with ceramic balls, such that mixed powder is obtained; the mixed powder is placed in a mold, and is subjected to bidirectional cold-pressing under room temperature; the composite material obtained by cold-pressing is subjected to vacuum sintering with the mold; and the composite material obtained by vacuum sintering is subjected to hot extrusion. With the method provided by the invention, the carbon-nanotube-enhanced magnesium-based composite material with high performance, light weight, and high strength can be prepared. The combination of the enhancing phase and the substrate is good. The material is advantaged in relatively high specific strength, high specific rigidity, high thermal conductivity, excellent machining performance, and the like. The composite material has good application prospect in industrial fields such as aeronautics and astronautics, automotives, 3C industries, sports and entertainments, and the like.
Owner:NORTHEASTERN UNIV
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