High Conductivity Magnesium Alloy

a high-conductivity, magnesium alloy technology, applied in the direction of material nanotechnology, transportation and packaging, foundation engineering, etc., can solve the problems of limited strength, increased brittleness of alloys, poor reliability, etc., to enhance mechanical properties of magnesium-based composites such as ductility and/or tensile strength, and improve thermal, physical and mechanical properties. , the effect of improving the mechanical properties

Inactive Publication Date: 2017-09-21
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0016]The present invention is directed to a cast or wrought magnesium-based composite incorporating insoluble nanoparticles and optional insoluble micron-sized particles, and method for manufacture of such magnesium-based composite. The magnesium-based composite has improved thermal, physical, and mechanical properties as compared to prior art magnesium alloys. The nanoparticles and optional micron-sized particles can be selected and used in quantities so that the grain boundaries of the magnesium-based composite contain a desired composition and morphology to achieve the desired physical and chemical properties of the composite and to optionally obtain a specific galvanic corrosion rate in the entire composite or along the grain boundaries o...

Problems solved by technology

While these systems have enjoyed modest success in reducing well completion costs, their consistency and ability to specifically control dissolution rates in specific solutions, as well as other drawbacks such as limited strength and poor reliability, have impacted their widespread adoption.
While the addition of a large volume percent of high thermal conductivity phases, such as SiC and graphite or carbon materials, to certain alloys has been shown to increase thermal conductivity in select alloys, such additions have typically resulted in increased brittleness of the alloy and the inability to cast or otherwise form the alloy.
As such, these types of alloys have been economically unattractive to use.
Attempts to improve mechanica...

Method used

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  • High Conductivity Magnesium Alloy
  • High Conductivity Magnesium Alloy
  • High Conductivity Magnesium Alloy

Examples

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example 1

[0152]An AZ91D magnesium alloy having 9 wt. % aluminum, 1 wt. % zinc and 90 wt. % magnesium was melted to above 700° C. About 2 vol. % nano iron particles and about 2 vol. % nano graphite particles were added to the AZ91D magnesium alloy using ultrasonic mixing. The melt was cast into steel molds. The iron particles and graphite particles did not fully melt during the mixing and casting processes. The material dissolved at a rate of 2 mg / cm2−min in a 3% KCl solution at 20° C. The material dissolved at a rate of 20 mg / cm2−hr in a 3% KCl solution at 65° C. The material dissolved at a rate of 100 mg / cm2−hr in a 3% KCl solution at 90° C. The dissolving rate of magnesium-based composite for each these test was generally constant.

example 2

[0153]Carbon nanotubes and / or finely divided copper nanoparticle powder were added to pure magnesium and an AZ91 magnesium alloy (having 9 wt. % aluminum, 1 wt. % zinc and 90 wt. % magnesium) when in molten form. The AZ91 magnesium alloy was melted to above 700° C. Insoluble nanoparticles in the form of carbon nanotubes (multiwall, high thermal conductivity) were added to the molten AZ91 magnesium alloy. The insoluble carbon nanotubes were added by consolidating the carbon nanotubes into a magnesium rod by mechanically blending the carbon nanotubes with magnesium powder and then cold pressing the mixture of carbon nanotubes and magnesium powder into a rod. The rod containing the carbon nanotubes was fed / inserted into the molten AZ91 magnesium alloy. The insoluble carbon nanotubes were dispersed in the molten AZ91 magnesium alloy by ultrasonic mixing wherein the rod was directed into the ultrasonic sweet spot to melt the rod at a melt temperature of 700° C. The carbon nanotubes const...

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Abstract

A castable, moldable, or extrudable magnesium-based alloy that includes one or more insoluble additives. The insoluble additives can be used to enhance the mechanical properties of the structure, such as ductility and/or tensile strength. The final structure can be enhanced by heat treatment, as well as deformation processing such as extrusion, forging, or rolling, to further improve the strength of the final structure as compared to the non-enhanced structure. The magnesium-based composite has improved thermal and mechanical properties by the modification of grain boundary properties through the addition of insoluble nanoparticles to the magnesium alloys. The magnesium-based composite can have a thermal conductivity that is greater than 180 W/m−K, and/or ductility exceeding 15-20% elongation to failure.

Description

[0001]This invention claims priority on U.S. Provisional Patent Application Ser. No. 62 / 340,074 filed May 23, 2016, which is incorporated herein. The present invention is also a continuation-in-part of U.S. patent application Ser. No. 14 / 627,236 filed Feb. 20, 2015, which in turn claims priority on U.S. Provisional Application Ser. No. 61 / 942,879 filed Feb. 21, 2014, which is incorporated herein by reference.[0002]The present invention relates to composites and methods for manufacture of a high conductivity magnesium composite, particularly to a magnesium-based composite and methods for manufacture of such composite wherein the composite has improved thermal and mechanical properties, more particularly to a magnesium-based composite and method for manufacture of such composite wherein the composite has improved thermal and mechanical properties by the modification of grain boundary thermal resistance through the addition of insoluble nanoparticles that are generally high conductivit...

Claims

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Application Information

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IPC IPC(8): C22F1/06E02D27/38C22C1/10B82Y30/00C22C23/00C21D10/00B22F1/062
CPCC22F1/06C22C23/00E02D27/38C22C1/1036B82Y30/00C21D10/00B22D19/14B22D21/007B22D21/04B22D23/06B22D25/06B22D27/00B22D27/02B22D27/08B22D27/11C22C1/03C22C1/0408C22C23/02C22C23/06C22C26/00C22C47/08C22C49/02C22C49/04B22F2998/10B22F2999/00C22C2026/002B22F1/062C22C1/1047B22F2202/01B22F1/0551B22F1/0547B22F1/054
Inventor SHERMAN, ANDREW J.FARKAS, NICHOLAS
Owner TERVES
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